The whole of Volume 22 is devoted to the kinetics and mechanisms of
the decomposition and interaction of inorganic solids, extended to
include metal carboxylates. After an introductory chapter on the
characteristic features of reactions in the solid phase,
experimental methods of investigation of solid reactions and the
measurement of reaction rates are reviewed in Chapter 2 and the
theory of solid state kinetics in Chapter 3. The reactions of
single substances, loosely grouped on the basis of a common anion
since it is this constituent which most frequently undergoes
breakdown, are discussed in Chapter 4, the sequence being
effectively that of increasing anion complexity. Chapter 5 covers
reactions between solids, and includes catalytic processes where
one solid component remains unchanged, double compound formation
and rate processes involving the interactions of more than three
crystalline phases. The final chapter summarises the general
conclusions drawn in the text of Chapter 2-5.
General
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