Books > Science & Mathematics > Physics > States of matter
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Molecular Networks (Paperback, 2009 ed.)
Loot Price: R8,443
Discovery Miles 84 430
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Molecular Networks (Paperback, 2009 ed.)
Series: Structure and Bonding, 132
Expected to ship within 10 - 15 working days
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In the future, many modern materials will be increasingly based on
the assembly of preformed molecular entities. Their structural
characteristics and functional prop- ties will be programmed at the
molecular level and their formation as a completed entity will be
achieved by self-assembly processes. This in essence is a bottom-up
approach and its success will require a deep understanding not only
of the chemistry of intermolecular interactions and associations
but also of self-assembly processes in the condensed phase. Among
various interesting innovations brought about by the development of
supramolecular chemistry, supramolecular synthesis is a part-
ularly powerful approach for the design and generation of molecular
architectures displaying both structural and functional complexity.
The combination of mol- ular synthesis (which allows chemists to
design and prepare extremely sophis- cated biotic and abiotic
molecules through the interconnection of atoms or group of atoms by
strong covalent bonds) and supramolecular synthesis (which orch-
trates the association of molecules by recognition processes
through the use of weak and reversible interactions) opens up
endless structural and functional possibilities. Following the
perceptive observation by Dunitz that "A crystal is, in a sense,
the supramolecule par excellence", molecular crystals may be seen
as in?nite periodic architectures resulting from the
interconnection of building blocks or tectons ca- ble of
self-assembling through speci?c recognising events.
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