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Aggregation of Luminophores in Supramolecular Systems - From Mechanisms to Applications (Hardcover)
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Aggregation of Luminophores in Supramolecular Systems - From Mechanisms to Applications (Hardcover)
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Supramolecular aggregation-driven by weak non-covalent
interactions, such as van der Waals, - interactions, hydrogen
bonding, and electrostatic-has been utilized to build sensing
platforms with improved selectivity and sensitivity. Supramolecular
aggregates, owing to cooperative interactions, higher sensitivity
and selectivity, relatively weak and dynamic non-covalent
interactions, and environmental adaptation, have achieved better
sensing performance than that of molecular sensory systems that
rely on sensors with delicate structures. Aggregation of
Luminophores in Supramolecular System: From Mechanisms to
Applications describes recent advances in supramolecular chemistry,
in which the luminophores are almost non-luminescent in the
molecular state, but become highly emissive in the aggregate state.
These advances bring new opportunities and challenges for the
development of supramolecular chemistry. The intermolecular
non-covalent interactions have been considered to be the main
driving forces for fabricating supramolecular systems with
aggregating luminophores and have an important influence on the
luminescence properties of the probes. Based on these unique
properties, luminescent supramolecular aggregates have greatly
promoted the development of novel materials for applications as
sensors, bio-imaging agents, organic electronic devices, and in the
field of drug delivery. Features: Discussion of fundamental and
interdisciplinary aspects of the aggregation in supramolecular
systems. Narration of intermolecular interactions and the
photophysical phenomenon of aggregation in supramolecular systems.
Comparative discussion on recent developments in
aggregation-induced quenching (AIQ) and aggregation-induced
emission (AIE), and drawbacks of AIQ. Description of the
technological applications of aggregation as biological sensors,
chemical sensors, organic electronic materials, and in the field of
drug delivery. A convenient format for checking formulas and
definitions. This book surveys highlights of the progress made in
the field of the aggregation of luminophores in supramolecular
chemistry. It is hoped that the work will form a foundation (and
indeed a motivation) for new workers in the area, as well as also
being useful to experienced supramolecular chemists. It may also
aid workers in the biological area to see Nature's aggregation in a
new light. Further, the approach employed has been designed to
provide readable background material for use with graduates, senior
undergraduates, research professionals, and industries.
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