S Sulfur-Nitrogen Compounds - Compounds with Sulfur of Oxidation Number IV (Paperback, 8th ed. 1991. Softcover reprint of the original 8th ed. 1991)

PF3, (CH3)3SiCl -> (CH3)3SiF, and RC(O)Cl -> RC(O)F. Others include the conversion of (C6H5)3P into (C6H5)3PF2 and of (R3NC(S)S)2 into R2NCF3, R=alkyl. In organic chemistry, fluorides are easily accessible from alcohols, geminal fluorides RR'CF2 from the respective aldehydes or ketones, and acyl fluorides RC(O)F from carboxylic acides by using DAST. Because DAST is easy to handle and gives clean reactions in syntheses, this Gmelin volume devotes much space to the description of the chemical and physical properties od DAST.

General

Imprint:	Springer-Verlag
Country of origin:	Germany
Series:	S. Schwefel. Sulfur (System-Nr. 9), S / S-N / 8
Release date:	October 2013
First published:	1991
Authors:	Norbert Baumann
Assisted by:	U. Hettwer
Editors-in-chief:	Alfons Kubny
Editors:	Norbert Baumann
Authors:	Hans-Jurgen Fachmann
Editors:	Hans-Jurgen Fachmann
Assisted by:	R. Bohrer
Authors:	Brigitte Heibel
Assisted by:	U. Nohl
Editors:	Brigitte Heibel
Dimensions:	254 x 178 x 27mm (L x W x T)
Format:	Paperback
Pages:	487
Edition:	8th ed. 1991. Softcover reprint of the original 8th ed. 1991
ISBN-13:	978-3-662-06365-1
Categories:	Books > Science & Mathematics > Chemistry > General
LSN:	3-662-06365-4
Barcode:	9783662063651

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