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Understanding Voltammetry (Hardcover)
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Understanding Voltammetry (Hardcover)
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New Edition: Understanding Voltammetry (3rd Edition)The power of
electrochemical measurements in respect of thermodynamics, kinetics
and analysis is widely recognized but the subject can be
unpredictable to the novice even if they have a strong physical and
chemical background, especially if they wish to pursue quantitative
measurements. Accordingly, some significant experiments are perhaps
wisely never attempted while the literature is sadly replete with
flawed attempts at rigorous voltammetry.This textbook considers how
to go about designing, explaining and interpreting experiments
centered around various forms of voltammetry (cyclic,
microelectrode, hydrodynamic, and so on). The reader is assumed to
have a knowledge to Masters level of physical chemistry but no
exposure to electrochemistry in general, or voltammetry in
particular. While the book is designed to 'stand alone', references
to important research papers are given to provide an entry into the
literature.The book gives clear introductions to the theories of
electron transfer and of diffusion in its early chapters. These are
developed to interpret voltammetric experiments at macro-electrodes
before considering microelectrode behavior. A subsequent chapter
introduces convection and describes hydrodynamic electrodes. Later
chapters describe the voltammetric measurement of homogeneous
kinetics, the study of adsorption on electrodes and the use of
voltammetry for electroanalysis.
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