Volume 79 in the venerable Organic Reactions series contains two
chapters. The first addresses cross-coupling reactions of
organotrifluoroborate salts, useful in the development of natural
products, materials, and pharmacologically active substances. It is
an excellent companion to two previous chapters on tin-based and
silicon-based cross-couplings contained in Volumes 50 and 75,
respectively. The second chapter addresses asymmetric
transformations by deprotonation using chiral lithium amides,
useful in target-oriented synthesis, and representing one of the
most powerful workhorse reactions in organic synthesis.
General
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