Self-assembly based on range of non-covalent interactions is a
recent tool in the chemistry tool-kit. An important factor in the
process of assembling are the complementary binding motifs on the
components and these could be simple organic molecules to metals to
complex amino acids. Recent years have witnessed a few
breakthroughs in the field of catalyst designing via self-assembly,
but there is immense need of new approaches. This book outlines
strategies to prepare metal complexes with chelating,
template-centered bis-phosphine ligands by self-assembly of simple
hard and soft metal complex precursors with bi-functional
phosphine-catecholate ligands in a single synthetic step. The
choice of template of different size and coordination number
permits to adjust the bite angle of the chelating bis-phosphine
unit in a predictable manner. Chirality in chelate complexes has
been demonstrated in simple and excellent manner. This book aims at
an audience of advanced students, experts and scientists working in
catalysis via self-assembly, bimetallic complexes, hard-soft
acid-base complexes and ligand designing.
General
Imprint: |
VDM Verlag Dr. Mueller E.K.
|
Country of origin: |
Germany |
Release date: |
September 2008 |
First published: |
September 2008 |
Authors: |
Samir Chikkali
|
Dimensions: |
229 x 152 x 11mm (L x W x T) |
Format: |
Paperback - Trade
|
Pages: |
200 |
ISBN-13: |
978-3-639-07138-2 |
Categories: |
Books >
Science & Mathematics >
Chemistry >
General
|
LSN: |
3-639-07138-7 |
Barcode: |
9783639071382 |
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