Books > Science & Mathematics > Chemistry > Inorganic chemistry
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Synthesis, Characterization & Application Of Mn(III) Complex Compound (Paperback)
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Synthesis, Characterization & Application Of Mn(III) Complex Compound (Paperback)
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Manganese has variable oxidation states and appears as Mn(III) with
redox function. It plays an important role in numerous biological
processes associated with utilization or generation of hydrogen
peroxide or dioxygen. The functions of these type are known viz
manganese superoxide dismutase, manganese catalase, manganese
peroxidase, manganese ribonucleotide reductase and oxygen involving
complex in photo system-II. This has prompted to under take the
coordination of Mn(III) ions with ligands. The oxygen donar ligands
used for the coordination are -diketones since -diketones anions
are powerful chelating species and they give stable Mn(III) complex
which can further be used for preparing other Mn(III) species that
can be used as catalysts. The tris ( -diketonate) Mn(III) complex
gives substitution as well as addition reactions with other
ligands. Here nitrogen donar ligands used are ethylenediamine,
propylenediamine and hexamethylenediamine. The nitrogen donar atom
ligands ultimately result in the mixed ligand complexes for Mn(III)
which are more stable in this oxidation state of manganese. In this
way the aim of preparing stable Mn(III) complexes is achieved by
the oxygen donor"
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