This book summarizes recent progresses in inorganic fluorine
chemistry. Highlights include new aspects of inorganic fluorine
chemistry, such as new synthetic methods, structures of new
fluorides and oxide fluorides, their physical and chemical
properties, fluoride catalysts, surface modifications of inorganic
materials by fluorination process, new energy conversion materials
and industrial applications.
Fluorine has quite unique properties (highest electronegativity;
very small polarizability). In fact, fluorine is so reactive that
it forms fluorides with all elements except with the lightest noble
gases helium, neon and argon. Originally, due to its high
reactivity, fluoride chemistry faced many technical difficulties
and remained undeveloped for many years. Now, however, a large
number of fluorine-containing materials are currently produced for
practical uses on an industrial scale and their applications are
rapidly extending to many fields.
Syntheses and structure analyses of thermodynamically unstable
high-oxidation-state fluorides have greatly contributed to
inorganic chemistry in this decade. Fluoride catalysts and surface
modifications using fluorine are developing a new field of fluorine
chemistry and will enable new syntheses of various compounds. The
research on inorganic fluorides is now contributing to many
chemical energy conversion processes such as lithium batteries.
Furthermore, new theoretical approaches to determining the
electronic structures of fluorine compounds are also progressing.
On the industrial front, the use of inorganic fluorine compounds is
constantly increasing, for example, in semi-conductor industry.
"Advanced Inorganic Fluorides: Synthesis, Characterization and
Applications" focuses on these new features in inorganic fluorine
chemistry and its industrial applications. The authors are
outstanding experts in their fields, and the contents of the book
should prove to be of valuable assistance to all chemists,
graduates, students and researchers in the field of fluorine
chemistry.
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