Over the last several years, there has been much discussion on the interrelation of CO2 emissions with the global warming phenomenon. This in turn has increased pressure to develop and produce more fuel efficient engines and vehicles. This is the central topic of this book. It covers the underlying processes which cause pollutant emissions and the possibilities of reducing them, as well as the fuel consumption of gasoline and diesel engines, including direct injection diesel engines. As well as the engine-related causes of pollution, which is found in the raw exhaust, there is also a description of systems and methods for exhaust post treatment. The significant influence of fuels and lubricants (both conventional and alternative fuels) on emission behavior is also covered. In addition to the conventional gasoline and diesel engines, lean-burn and direct injection gasoline engines and two-stroke gasoline and diesel engines are included. The potential for reducing fuel consumption and pollution is described as well as the related reduction of CO2 emissions. Finally, a detailed summary of the most important laws and regulations pertaining to pollutant emissions and consumption limits is presented. This book is intended for practising engineers involved in research and applied sciences as well as for interested engineering students.

Air pollution related to the release of industrial toxic gases, represents one of the main
concerns of our modern world owing to its detrimental effect on the environment. To tackle this growing issue, efficient ways to reduce/control the release of pollutants are required. Adsorption of gases on porous materials appears as a potential solution. However, the physisorption of small molecules of gases such as ammonia is limited at ambient conditions. For their removal, adsorbents providing strong adsorption forces must be used/developed.
In this study, new carbon-based materials are prepared and tested for ammonia adsorption at ambient conditions. Characterization of the adsorbents texture and surface chemistry is performed before and after exposure to ammonia to identify the features responsible for high adsorption capacity and for controlling the mechanisms of retention. The characterization techniques include: nitrogen adsorption, thermal analysis, potentiometric titration, FT-IR spectroscopy, X-ray diffraction, Energy Dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy and Electron Microscopy. The results obtained indicate that ammonia removal is governed by the adsorbent s surface chemistry. On the contrary, porosity (and thus physisorption) plays a secondary role in this process, unless strong dispersive forces are provided by the adsorbent. The surface chemistry features responsible for the enhanced ammonia adsorption include the presence of oxygen-(carboxyl, hydroxyl, epoxy) and sulfur- (sulfonic) containing groups. Metallic species improve the breakthrough capacity as well as they lead to the formation of Lewis acid-base interactions, hydrogen-bonding or complexation. In addition to the latter three mechanisms, ammonia is retained on the adsorbent surface via Bronsted acid-base interactions or via specific reactions with the adsorbent s functionalities leading to the incorporation of ammonia into the adsorbent s matrix. Another mechanism involves dissolution of ammonia in water when moisture is present in the system. Even though this process increases the breakthrough capacity of a material, it provides rather weak retention forces since ammonia dissolved in water is easily desorbed from the adsorbent s surface."

The enduring changes in the aquatic environment and the increasing influx of contaminants call for novel conceptual and methodological approaches to relating chemical pollution and ecological alterations in ecosystems. This volume highlights the latest advances concerning the sampling, analyses, occurrence, bioavailability, and effects of emerging and priority pollutants in European rivers, the current status of the River Management Plans in Europe, and the applicability of the newly developed techniques for water monitoring purposes. The topics are discussed in the context of the EU Water Framework Directive, evaluating their shortcomings and providing a basis for doing away with them. Linking scientific research and river management practices, this book is an invaluable source of information for environmental chemists, aquatic scientists, ecologists and water managers.

Due to the threat of a possible global climate change and the greenhouse effect caused by constituents of anthropogenic origin in the atmosphere, air quality has become a major environmental issue. As a consequence, emissions into the atmosphere need to be monitored and controlled. Measurement of Atmospheric Emissions presents technologies for emission control and analysis from industrial and energy plants. The author explains the physical and chemical basis before proceeding to the practical performance. This publication provides the reader with the knowledge necessary to critically analyze and investigate emission measurement techniques. It will be of great interest to researchers and engineers in the fields of environmental technology and air pollution control. It will assist in the choice of the most appropriate instruments for various purposes and circumstances.

This short, practical book offers advice on the safe storage, handling and transportation of liquid natural gas (LNG), liquid petroleum gas (LPG) and other cryogenic fluid mixtures. It begins with a review of the physical properties of LNG and LPG, and a brief overview of basic handling and storage methods. The chapters that follow address more in-depth topics such as heat flows in LNG and LPG storage systems, insulation techniques and surface evaporation phenomena. Two chapters are then devoted to the specific sequence of problems caused by stratification and rollover, and the techniques used to manage and alleviate these issues. The book then considers the use of vacuum insulated tanks for the storage of pressurised LNG, and the effective transfer of liquids avoiding 2-phase flow. It concludes with a summary of safe storage and handling protocols, and addresses the specific health issues encountered when dealing with cryogenic liquid mixtures. Throughout the book the author presents real-life case studies to illustrate the situation being discussed. Written in a practical style, it will prove an invaluable companion to anyone working with LNG, LPG or other cryogenic liquid mixtures.

Based on detailed research funded across two continents and involving universities in Argentina, Spain and the UK, this book sets out an innovative, multidisciplinary approach to assessing both environmental and social risks in a given territorial area. Using data from a number of Ibero-American nations, the study combines environmental, socio-economic and geographic factors to construct a set of spatial and technical indicators that measure the social vulnerability and industrial hazardousness of a defined area. Aggregating these indicators in a geographic information system (GIS) allows researchers to assess the potential risk to which a certain area and its population are subject as a result of the environmental deterioration caused by co-located industrial activity.

Although fossil fuels remain the primary global energy source, developing and expanding economies are creating an ever-widening gap between supply and demand. Efficient energy management offers a cost-effective opportunity for both industrialized and developing nations to limit the enormous financial and environmental costs associated with burning fossil fuels. The implication of photovoltaic systems in particular presents the potential for clean and sustainable electrical energy to be generated from an unrestricted source. Energy Management in Buildings Using Photovoltaics demonstrates how adopting 'best practices' for energy management and harvesting can reduce the need to construct new generating facilities. Illustrated with figures, tables and photos, Energy Management in Buildings Using Photovoltaics provides an introduction and step by step instructions on designing and planning photovoltaic systems and energy policies for both residential and industrial buildings. With particular focus on the example of provided by European industry, the creation of energy efficient systems is explored including chapters on: Zero Energy Buildings, Photovoltaics Technology, and Connection of the Network By presenting this topic from basic introduction to highly technical analysis, Energy Management in Buildings Using Photovoltaics acts a study guide for postgraduate students as well as a key point of reference for researchers and technical consultants in the field of photovoltaic systems.

Written by outstanding experts in the fields of marine engineering, atmospheric physics and chemistry, fluid dynamics and applied mathematics, the contributions in this book cover a wide range of subjects, from pure mathematics to real-world applications in the oil spill engineering business. Offering a truly interdisciplinary approach, the authors present both mathematical models and state-of-the-art numerical methods for adequately solving the partial differential equations involved, as well as highly practical experiments involving actual cases of ocean oil pollution. It is indispensable that different disciplines of mathematics, like analysis and numerics, together with physics, biology, fluid dynamics, environmental engineering and marine science, join forces to solve today's oil pollution problems. The book will be of great interest to researchers and graduate students in the environmental sciences, mathematics and physics, showing the broad range of techniques needed in order to solve these pollution problems; and to practitioners working in the oil spill pollution industry, offering them a professional reference resource.

The book contains an analysis of theoretical dependences, bottlenecks and limiting factors of a new technology used in both Consteel and shaft furnaces operating with flat bath. Performances obtained and potentialities of these furnaces are examined. Based on this analysis, a steel melting aggregate of the new type - fuel arc furnace FAF has been developed and offered. In comparison with the best modern electric arc furnaces of identical capacity the productivity of FAF is higher by 36% and electrical energy consumption is lower by a factor of 1.8. Environment characteristics are considerably improved.

Heavy-metal contamination is one of the world's major environmental problems, posing significant risks to agro-ecosystems. Conventional technologies employed for heavy-metal remediation have often been expensive and disruptive.

This book provides comprehensive, state-of-the-art coverage of the natural, sustainable alternatives that use a wide range of biological materials in the removal/detoxification of heavy metals, consequently leading to the improvement of crops in these soils. Novel, environmentally friendly and inexpensive solutions are presented based on a sound understanding of metal contamination and the roles of plants and microbes in the management of these toxic soils.

Written by worldwide experts, the book provides not only the necessary scientific background but also addresses the challenging questions that require special attention in order to better understand metal toxicity in soils and its management through bioremediation.

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Recent developments in air pollution modeling and its application are explored here in contributions by researchers at the forefront of their field. The book is focused on local, urban, regional and intercontinental modeling; data assimilation and air quality forecasting; model assessment and evaluation; aerosol transformation; the relationship between air quality and human health and the interaction between climate change and air quality. The work will provide useful reference material for students and professors interested in air pollution modeling at the graduate level as well as researchers and professionals involved in developing and utilizing air pollution models.

Mathematical models are the effective tool to solve different tasks predicting pollutant movement. The finite difference method is the oldest, but still remains widely used in hydrogeological practice. However, this method is not very useful to construct the new transport models because it cannot approximate the shape of remediation elements exactly. Therefore the book is concerned with the FEM (Finite Element Method) and BEM (Boundary Element Method), and also with the comparison of advantages of these methods in groundwater hydrology. The combination of the BEM and the random-walk particle tracking method, which seems to be a very useful tool to model the spread of pollution in groundwater, are also presented. The computer programmes have been developed on the basis of the theoretical backgrounds of these methods. They use the Visual C++ programming language for Windows 95/NT platform and will be included in the book.

This book provides a comprehensive overview of remediation and rehabilitation techniques and strategies for contaminated and anthropogenically disturbed land. Rehabilitation approaches in the urban environment, such as brownfield redevelopment and urban mining, are discussed. In relation to contaminated land, techniques for soil containment and decontamination of soil, soil vapour and groundwater are comprehensively and systematically presented. Complicated treatment techniques are schematically depicted and can be readily understood. Agricultural, silvicultural and environmentally sustainable rehabilitation strategies for reclaiming disturbed land/terrain in former mining or natural-resource extraction areas, such as open-cast mines, quarries, harvested peatlands, and subsided mining terrain (sinkholes), are introduced. This book will be a useful tool for students, researchers, private consultants and public authorities engaged in the treatment of contaminated or disturbed land.

Environmental Chemistry is a relatively young science. Interest in this subject, however, is growing very rapidly and, although no agreement has been reached as yet about the exact content and limits of this interdisciplinary discipline, there appears to be increasing interest in seeing environmental topics which are based on chemistry embodied in this subject. One of the first objectives of Environmental Chemistry must be the study of the environment and of natural chemical processes which occur in the environment. A major purpose of this series on Environmental Chemistry, therefore, is to present a reasonably uniform view of various aspects of the chemistry of the environment and chemical reactions occurring in the environment. The industrial activities of man have given a new dimension to Environmental Chemistry. We have now synthesized and described over five million chemical compounds and chemical industry produces about hundred and fifty million tons of synthetic chemicals annually. We ship billions of tons of oil per year and through mining operations and other geophysical modifications, large quantities of inorganic and organic materials are released from their natural deposits. Cities and metropolitan areas of up to 15 million inhabitants produce large quantities of waste in relatively small and confined areas. Much of the chemical products and waste products of modern society are released into the environment either during production, storage, transport, use or ultimate disposal. These released materials participate in natural cycles and reactions and frequently lead to interference and disturbance of natural systems.

Properties, sources of formation, reactions, and detection of oxygen species form the first part of this volume.
Biochemical, toxicological and environmental aspects are dealt with in detail in the following chapters. This information provides the basis for a state-of-the-art understanding of the role of oxygen species in environmental pollution and as a health hazard.

An important purpose of The Handbook of Environmental Chemistry is to aid the understanding of distribution and chemical reaction processes which occur in the environment. Volume 4, Part B of this series is dedicated to Air Pollution Control Equipment, Materials Damage, Peroxyacyl Nitrates, Semivolatile Compounds in the Atmosphere, and Arctic Haze.

This book is the result of a conference held biannually at the Goodwin-Niering Center for Conservation Biology and Environmental Studies at Connecticut College. It uses an interdisciplinary approach to focus on important ecological impacts of acid deposition. The book combines research findings and the policy analyses of experts from different academic disciplines with the positions advanced by representatives of various nongovernmental organizations.

Does a connection exist between environmental degradation, resource scarcity and violent conflicts? Global environmental changes, such as climate change and sea level rise, shortage of fresh water and rapid soil degradation increasingly highlight the dimensions of environmental change in foreign and security policy. To reverse these negative environmental consequences over the long term, comprehensive and preventive policy approaches are urgently required.
This state-of-the-art book contains numerous articles by renown German-speaking experts from different scientific disciplines as well as international and European political advisors and diplomats. Together they discuss the complex causes of environmentally induced conflicts and the political and societal mechanisms for conflict prevention.

Originally published in 1993, this volume describes a complementary selection of tests to those described in the companion volume Basic Mutagenicity Tests (Cambridge University Press, 1990). These supplementary tests were used to assess risks of in vitro mutagenicity in those instances where the basic tests were inconclusive. As such, these tests had an important role in the assessment of the safety of compounds, drugs and chemicals. These supplementary test and guidelines, originally drawn up by the United Kingdom Environmental Mutagen Society (UKEMS) were fully revised in this publication to take full account of different regulatory guidelines and scientific advances. This volume will be of value to anyone with aninterest in regulatory affairs, mutagenicity testing and the registration of chemical products in the UK and Europe.

Environmental chemistry is a fast developing science aimed at deciphering fundamental mechanisms ruling the behaviour of pollutants in ecosystems. Applying this knowledge to current environmental issues leads to the remediation of environmental media, and to new, low energy, low emission, sustainable processes. Chapters review analysis and remediation of pollutants such as greenhouse gases, chiral pharmaceuticals, dyes, chlorinated organics, arsenic, toxic metals and pathogen in air, water, plant and soil. Several highlights include the overlooked impact of air pollutants from buildings for health risk, innovative remediation techniques such as bioreactors for gas treatment, electrochemical cleaning of pharmaceuticals, sequestration on Fe-Mn nodules, phytoremediation and photocatalytical inactivation of microbial pathogens.

This book will be a valuable source of information for engineers and students developing novel applied techniques to monitor and clean pollutants in air, wastewater, soils and sediments.

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Nuclear sites become contaminated with radionuclides due to accidents and activities carried out without due consideration for the environment. Naturally-occurring radioactive materials (NORM) released by industrial processes such as coal power production and fertilizer manufacture may also require clean-up. Environmental remediation and restoration aim to reduce exposure to radiation from contaminated soil or groundwater. This book provides a comprehensive overview of this area. Part 1 provides an introduction to the different types of contaminated site and their characteristics. Part 2 addresses environmental restoration frameworks and processes. Part 3 then reviews different remediation techniques and methods of waste disposal.

The disturbance and recovery of arctic terrestrial ecosystems was the subject of a NATO Advanced Workshop held at the Arctic Centr, University of Lapland, Rovaniemi, Finland, in September 1995. The object of the meeting was to bring together researchers on arctic vegetation who share a concern for the preservation of arctic ecosystems. A particular aim of the meeting was to involve as many Russian colleagues as possible and to encourage younger scientists currently active in the Russian Arctic to come to Rovaniemi and make first-hand contact with colleagues from other countries with a view to planning further collaboration. This volume of papers therefore contains papers both from many younger researchers as well as from those who have been active in arctic plant ecology for many years. Disturbance is no new feature in the arctic environment. The factors that create the arctic habitat include marked climatic oscillations, physical disturbance and fluctuations in herbivore populations. The combination of environmental stress and disturbance from habitat instability and the possibility of periods of intense grazing imposes a particularly testing blend of adverse conditions for plant survival. The physical nature of the terrain with constant soil movement through cryoperturbation and solifluction contributes to the fragility of arctic habitats. To this scenario we must add disturbance by man in the unending quest for yet more natural resources, whether they be animal, vegetable or mineral or merely the concept of environmental experience, as in tourism.

In situ remediation techniques have experienced a boom over the last few years, thereby producing a wide range of valuable experiences. Their results have demonstrated that in situ techniques are a mature alternative to conventional remediation techniques. Irrespective of future policy developments, it is impossible to imagine future remediation practice without the use of in situ techniques. The book presents an overview of recent developments in the field of in situ soil remediation. The book is unique in that it is not a compilation of unrelated case studies. A conceptual approach has been chosen; remediation models described in this book are illustrated from a practical point of view. The authors present the Dutch way of treating contaminated land; The Netherlands is renowned for being at the forefront of remediation techniques as a result of the country's progressiveness and experience in this area.

Facing the challenges of globalization and ecology, the standards for economic, social and environmental performance of companies are becoming more demanding. This book shows what sustainable development means for the business community and presents best practice approaches in environmental management from Japan, the USA, Brazil and seven European countries. The book stresses that international competitiveness depends on the effective use of innovative management tools and has to be supported by an intelligent system of environmental regulation, that is, promoting innovation and eco-efficiency. Experts with many years of practical experience share their know-how on how to achieve excellency in environmental performance and present concrete steps towards a sustainable company.

Preface When you write a book like this after ten years' working as an environmental specialist, you end up with something that reflects your career. Of course, when I started working at the Ministry of the Environment in the Netherlands, I could not foresee that I would now be at TNO, nor that I would have performed research into chlorine, PVC, waste, etc. , that would come to form the basis for this book. But step by step, with some coincidence and with the support of several people - who were probably unaware of the crucial role that, with hindsight, they played - I arrived at a position where I could start to consider this enterprise. At this point I shall try something dangerous - thanking a few of those people who gave that support. At the same time, it is obvious that I cannot mention them all. I hope that those whom I do not mention will forgive me. A first, crucial moment in this sequence of events came quite soon after I joined TNO in 1990. Just a few weeks later, all the senior staff in my section decided to leave in order to set up their own company. I decided to stay at TNO. As a consequence, I had to manage it on my own.