As we transition into the 21st century, it is apparent that this is an exciting time for environmental engineers and scientists studying remediation technologies. There has been a rapid development of new ways to clean-up polluted groundwater. Research activities of the past and next 10 years will have a dramatic impact on the quality of the subsurface environment for the next century. In 20, or even 10 years from now, our approach to subsurface remediation will probably be vastly different than it is today. Many of the emerging technologies presented in this book will form the basis of standard remediation practices of the future. Physicochemical Groundwater Remediation presents detailed information on multiple emerging technologies for the remediation of the contaminated subsurface environment. All of these technologies apply our knowledge of physical and chemical processes to clean up ground water and the unsaturated zone, and many (if not all) of these emerging technologies will help define standard practices in the future. These technologies include in situ sorptive and reactive treatment walls, surfactant-enhanced aquifer remediation, optimization analyses for remediation system design, chemical, electrochemical, and biochemical remediation processes, and monitored natural attenuation. You will learn how palladium catalyzes the dehalogenation of chlorinated solvents. You will find out how barometric pumping can naturally remove significant quantities of volatile organic pollutants from shallow ground water and the unsaturated zone. You can learn about mobilizing non-aqueous phase liquids (NAPLs) without risking significant downward migration of the NAPL. You can find out how processes such as electroosmosis and electromigration can be exploited for groundwater remediation purposes and how zero-valent iron and zeolite treatment walls can be used in situ to treat and control contaminant plume migration. Contributors to this book are experts in groundwater remediation processes, and they represent industry, consulting, academia, and government. If your work involves the clean up of contaminated soil and groundwater, this book is an essential reference to keep you up to date on the most promising new developments in remediation research.

A growing proportion of the world's population is dependent on Seawater Desalination as a source of fresh water for both potable and civil use. One of the main drawbacks of conventional desalination technologies is the substantial energy requirement, which is facing cost increases in the global energy market. "Seawater Desalination" presents an overview of conventional and non-conventional technologies, with a particular focus on the coupling of renewable energies with desalination processes.

The first section of this book presents, in a technical but reader-friendly way, an overview of currently-used desalination processes, from thermal to membrane processes, highlighting the relevant technical features, advantages and disadvantages, and development potential. It also gives a rapid insight into the economic aspects of fresh water production from seawater.

The second section of the book presents novel processes which use Renewable Energies for fresh water production. From the first solar still evaporators, which artificially reproduced the natural cycle of water, technology has progressed to develop complex systems to harness energy from the sun, wind, tides, waves, etc. and then to use this energy to power conventional or novel desalination processes. Most of these processes are still at a preliminary stage of development, but some are already being cited as examples in remote areas, where they are proving to be valuable in solving the problems of water scarcity.

A rapid growth in these technologies is foreseen in the coming years. This book provides a unique foundation, within the context of present and future sustainability, for professionals, technicians, managers, and private and public institutions operating in the area of fresh water supply.

This book aims at stimulating discussion between researchers working on state of the art approaches for operational control and design of transport of water on the one hand and researchers working on state of the art approaches for transport over water on the other hand. The main contribution of the book as a whole is to present novel perspectives ultimately leading to the management of an envisioned unified management framework taking the recent advances from both worlds as a baseline. The book is intended to be a reference for control-oriented engineers who manage water systems with either or both purposes in mind (transport of water, transport of goods over water). It highlights the possible twofold nature of water projects, where water either acts as primary object of study or as a means. The book is dedicated to comparing and relating to one another different strategies for (operational) management and control of different but strongly related systems in the framework of the water. In that sense, the book presents different approaches treating both the transport of water and transport over water. It compares the different approaches within the same field, highlighting their distinguishing features and advantages according to selected qualitative indices, and demonstrates the interaction and cross-relations between both fields. It will also help to determine the gaps and common points for both fields towards the design of such a unifying framework, which is lacking in the literature. Additionally, the book looks at case studies where the design of modeling/control strategies of either transport of water or transport over water have been proposed, discussed or simulated.

This study presents a unique way to utilize the existing literature to explain the success of treaties in managing hydrologic stress. Literature-derived core concepts are summarized as seven treaty mechanisms categories (specificity, uncertainty management, enforcement, communications, flexibility, integrativeness, and scale) and are hypothesized as important for shaping the institutional resiliency of a treaty. Treaty design is shown to have a relevant and important role in shaping basin management so that nations may better achieve their goals in a changing climate.

This volume captures the impact of women's research on the public health and environmental engineering profession. The volume is written as a scholarly text to demonstrate that women compete successfully in the field, dating back to 1873. Each authors' chapter includes a section on her contribution to the field and a biography written for a general audience. This volume also includes a significant representation of early women's contributions, highlighting their rich history in the profession. The book covers topics such as drinking water and health, biologically-active compounds, wastewater management, and biofilms. This volume should be of interest to academics, researchers, consulting engineering offices, and engineering societies while also inspiring young women to persist in STEM studies and aspire to academic careers. Features a blend of innovations and contributions made by women in water quality engineering, as well as their path to success, including challenges in their journeys Presents an opportunity to learn about the breadth and depth of the field of water quality Includes a history of women in water quality engineering as well as research in current issues such as urban water quality, biologically-active compounds, and biofilms

This volume provides a comprehensive overview of environmental aspects of the Sava River, which is the greatest tributary to the Danube River and the major drainage river system of South Eastern Europe. Hydroelectric power plants, river traffic, intensive agricultural activities, heavy industry and floods have considerable influence on the environment and biota in the basin. Summarizing the results that were gathered in the course of EU, bilateral and national projects, the book highlights the most important stressors and helps readers to better understand the impact of anthropogenic activities on the function of river basins. Topics include: transboundary water cooperation between the riparian countries; climate change projection, including its impact on flood hazards; evaluation of anthropogenic pollution sources; pollution of sediments, metal bioavailability and ecotoxicological and microbiological characterization of the river. The biological part also addresses quality aspects related to wildlife in river aquatic ecosystems (algae, macrophytes, zooplankton, macroinvertebrates and fish) and riparian ecosystems (amphibians, reptiles, birds and mammals). The general state of biodiversity and pressures caused by invasive aquatic species are also discussed.

TheI&ECSYMPOSIUMfromwhichthisvolumewasderivedfeatured519presen- tationsat88technicalsessionsduringathree-daymeetingonSeptember17-20, 1996in Birmingham,Alabamawith580registrants. Thefinalselectionsforthechaptersincluded hereinwerebasedonpeerreview,scientificmerit,theeditors'perceptionsoflastingvalue orinnovativefeatures, andthegeneralapplicabilityofeitherthetechnologyitselforthe scientificmethodsandscholarlydetailsprovidedbytheauthors. Thevolume isacontinuationofathemeinitiatedin 1990. Itspredecessors,Emerg- ing Technologies in Hazardous Waste Management, ACS Symposium Series No. 422 (1990), EmergingTechnologiesinHazardous WasteManagementII,ACSSymposiumSe- ries No. 468 (1991), Emerging Technologies in Hazardous WasteManagement III, ACS SymposiumSeriesNo. 518(1993), EmergingTechnologiesinHazardous WasteManage- mentIV, ACSSymposium Series No. 554 (1994),Emerging Technologies in Hazardous WasteManagement V. ACSSymposiumSeriesNo. 607(1995), andEmergingTechnolo- gies in Hazardous Waste Management VI, American AcademyofEnvironmental Engi- neersPublication (1996), arerelatedcontributionsonhazardouswastemanagement,but eachvolumeisessentiallydifferent. Byinspection,thereadermayquicklyrecognizethis diversity,andalsoconcludethatnosinglevolumecandojusticetothebreadthanddepth oftechnologiesbeingdevelopedandappliedinpractice. Thecontributionspresented in thisvolumearedivided intofourseparatebutcom- plementary sections, including: (1) Chemical and Thermal Treatment; (2) Biochemical Treatment;(3)SeparationTechnologies;and(4)RadioactiveWasteTreatment. D. WilliamTedder FrederickG. Pohland GeorgiaInstituteofTechnology UniversityofPittsburgh Atlanta, Georgia30332-0100 Pittsburgh,Pennsylvania15261-2294 v ACKNOWLEDGMENTS The Industrial & Engineering Chemistry (I&EC) Division ofACS organized and sponsored the symposium. ACS Corporate Associates was a majorfinancial cosponsor; theAmericanInstituteofChemicalEngineers(AIChE)EnvironmentalSciencesDivision, theAIChECenterforWasteReductionTechnologies,theAmericanAcademyofEnviron- mental Engineers,andtheJointAssociationfor theAdvancementsofSupercriticalFluid Technologywerenominalcosponsors;andEnviroExpocositedanexhibition. Thisgener- osity was essential to the overall successofthe symposium and is gratefully acknow- ledged. vii CONTENTS I. EmergingTechnologiesinHazardousWasteManagementVII:AnOverview...FrederickG. PohlandandD. WilliamTedder ChemicalandThermalMethods 2. GranularIronOxideasaCatalystinChemicalOxidationofOrganic Contaminants...9 MiratD. Gurol,Shu-SungLin,andNileshBhat 3. AnElectronBeamGeneratedPlasmaReactorforDecompositionof HalogenatedVOCs 23 S. A. Vitale, K. Hadidi,D. R. Cohn, L. Bromberg,andP. Falkos 4. IncinerationandThermalTreatmentofChemicalAgentsandChemicalWeapons 33 F. C. GouldinandE. M. Fisher 5. PredictingStabilityConstantsofVariousChelatingAgentsUsingQSAR Technology 49 R. W. Okey,S. Lin,andP. K. A. Hong 6. MineralizationofHazardousChemicalsbyHemeReaction ...69 GuyoungKang,JimoJung,KapsongPark,andDavidK. Stevens BiochemicalTreatment 7. AnaerobicTransformationsofCarbonTetrachloride:CombinedBacterialand AbioticProcesses 81 FlynnW. Picardal,SanggooKim,AnnaRadue,andDeberaBackhus 8. BiorecoveryofMetalsfromAcidMineDrainage...91 RakeshGovind,UmaKumar,RamaPuligadda,JimmyAntia,and HenryTabak ix x Contents 9. BiotreatmentofMinewater-ContainingCyanidesbyUsingImmobilizedCell Technology 103 Onguri K. Vijaya,G. R. V. Babu,JackAdams,JamesH. Wolfram,and KiritD. Chapatwala 10. Augmentationofin-SituSubsoilRemediationUsingColloidalGasDispersions 113 P. G. Chaphalkar,K. T. Valsaraj,D. Roy, W. D. Constant,andP. Lee 11. EffectofSorptionontheMicrobialReductiveDechlorinationofSoil-Bound Chloroalkenes 127 SpyrosG. PavlostathisandPingZhuang SeparationTechnologies 12. TheRemovalofVOCsfromExhaustAirandVapourCondensatesby MembraneProcesses ...

There is not an extensive literature on street sweeping. Much of the research that has been completed exists in the "gray" area of technical reports and government documents. Furthermore, a great deal of this research is locally based, and has not been widely published. Indeed, our review of the scientific literature, revealed that, while storm water quality has received a lot of attention, few academicians have been involved in street sweeping research per se. Thus, throughout our research into street we sweeper effectiveness, sweeping protocols, and sweeping practices, wished that there had been a book summarizing some of the important issues associated with street sweeping. As our frustration grew, we realized that we were uniquely poised to write such a book as our research had encompassed a variety of different projects including sweeper testing, waste management, and related storm water quality. Also, early on in this exercise, we recognized that there was a growing demand for information about street sweeping policies and management, especially for studies focusing on the effectiveness of different sweeping schedules, on waste management operations, and on non-point, pollution reduction practices associated with storm water runoff. It was abundantly clear that there was a profound lack of research on street sweeping that could assist with developing local, regional, or national policies. There was, in effect, little guidance for city managers on these issues.

The concern over the entry of agrochemicals and other xenobiotics into drinking water resources and over the general quality of drinking water is increasing. The topic of water quality and water supply will continue to be of great interest during the next two decades in developed as well as in developing countries. The new volume discusses in an authoritative way the key issues of drinking water and its often necessary treatment.

Heavy metals always pose serious ecological risks when released into the environment due to their elemental non-degradable nature, regardless of their chemical form. This calls for the development of efficient and low-cost effluent treatment and metal recuperation technologies for contaminated waste water, not only because regulatory limits need to be met but also because the waste itself can be a resource for certain precious metals.

Biosorption is a general property of living and dead biomass to rapidly bind and abiotically concentrate inorganic or organic compounds from even very diluted aqueous solutions. As a specific term, biosorption is a method that utilizes materials of biological origin - biosorbents formulated from non-living biomass - for the removal of target substances from aqueous solutions. Recent research on biosorption provides a solid understanding of the mechanism underlying microbial biosorption of heavy metals and related elements.

This book gathers review articles analyzing current views on the mechanism and (bio)chemistry of biosorption, the performance of bacterial, fungal and algal biomass, and the practical aspects of biosorbent preparation and engineering. It also reviews the physico-chemical evaluations of biosorbents and modelling of the process as well as the importance of biosorption during heavy metal removal using living cells. It is a reference work for scientists, environmental safety engineers and R&D specialists who wish to further promote biosorption research and use the accumulated knowledge to develop and build industrial applications of biosorption in heavy metal separation technologies.

"

The proposed book deals with the role of changing groundwater base level on the adjacent hydrological systems. It summarizes, compiles and compares results of current and paleo base levels, using examples from all over the world. A classification is given for marine or continental groundwater base levels with special attention to those below sea level. The factors controlling base level changes and the methods for their determination are elaborated. Holocene and future changes are discussed with their effect on salinization and flushing mechanisms of groundwater. All topics described in the book are accompanied by examples and references from all over the world.

Irrigated agriculture produces about 40% of all food and fibre on about 16% of all cropped land. As such, irrigated agriculture is a productive user of resources; both in terms of yield per cropped area and in yield per volume of water consumed. Many irrigation projects, however, use (divert or withdraw) much more water than consumed by the crop. The non-consumed fraction of the water may cause a variety of undesirable effects ranging from water-logging and salinity within the irrigated area to downstram water pollution.

This book discusses all components of the water balance of an irrigated area; evapotranspiration (Ch.2), effective precipitation (Ch.3) and capillary rise from the groundwater table (Ch.4). Chapter 5 then combines all components into a water management strategy that balances actual evapotranspiration (and thus crop yield) with the groundwater balance of the irrigated area (for a substainable environment). Chapter 6 presents CRIWAR 3.0, a simulation program that combines all water balance components into a single simulation procedure. The chapter describes the use of the CRIWAR software for developing water requirement tables and other useful information based on the selected water management strategy. This version greatly expands upon the capabilities of previously published programs.

This book addresses questions of relevance to governments and industry in many countries around the world, in particular concerning the link between contaminated-land-management programs and the protection of drinking water resources and the potential effects of climate changes on the availability of these same resources. On the "problem" side, it reports and analyzes methodologies and experiences in monitoring and characterization of drinking water resources (at basin, country and continental scales), pollution prevention, assessment of background quality and of impacts on safety and public health from land and water contamination and impacts of climate change. On the "solution" side, the book presents results from national cleanup programs, recent advances in research into groundwater and soil remediation techniques, treatment technologies, research needs and information sources, land and wastewater management approaches aimed at the protection of drinking water. "

For the first time, here is a book that focuses on in vitro approaches to the study of the toxicology of polluting agents (including heavy metals, radionuclides, micro-organics, estrogenic compounds, and complex mixtures) in the aquatic environment. The importance of in vitro methods is that they allow standardised techniques to be developed and validated for substance and species specific experiments in a controlled way. Also, they allow mechanistic studies without the problems of individual variation between animals and environmental stress.

Biotechnology for Waste Management and Site Restoration covers: waste management - solid, gaseous, liquid; site restoration - radioactivity, organics, toxic metals; educational, economic, social and business aspects; and international collaboration. International collaboration is growing apace and many concrete projects have been started. The body of knowledge is growing. Over the long term, it is envisaged that this international collaboration will result in a long-term scientific and technological strategy, new technologies and alternative solutions, and practical implementations of biotechnology for the nuclear and industrial sectors of the economy.

This book discusses different drinking water treatment technologies and what contaminants each treatment method can remove, and at what costs. The production of drinking water requires adequate management. This book attempts to fill the existing knowlegde gap about (a) water treatment technologies and their costs, (b) risk assessment methods, (c) adverse health effects of chemical contaminants, (d) management protocols, and varying regulatory practices in different jurisdictions, and what successes are possible even with small financial outlays. Addressing water consulting engineers, politicians, water managers, ecosystem and environmental activists, and water policy researchers, and being clearly structured through a division in four parts, this book considers theoretical aspects, technologies, chemical contaminants and their possible elimination, and illustrates all aspects in selected international case studies.Source-water protection, water treatment technology, and the water distribution network are critically reviewed and discussed. The book suggests improvements for the management of risks and financial viability of the treatment infrastructure, as well as ways toward an optimal management of the distribution network through the risk-based management of all infrastructure assets.

This book covers the fundamental requirements for air, soil and water pollution control in oil and gas refineries, chemical plants, oil terminals, petrochemical plants, and related facilities. In this concise volume, Dr. Bahadori elucidates design and operational considerations relevant to critical systems such as the waste water treatment units, solid waste disposal, and waste water sewer treatment as well as engineering/technological methods related to soil and air pollutions control. Engineers and technical managers in a range of industries will benefit from detail on a diverse list of topics."

This book presents a Two-Stage Anaerobic Digestion (TSAD) technique for producing hydrogen and methane, following a step-by-step approach in order to guide readers through the experimental verification of the related hypothesis. In the first stage of AD, the reaction conditions are optimized to obtain the maximum amount of hydrogen, while in the second the liquid residue from the first phase is used as a substrate to produce fuel-methane. AD has traditionally been used to reduce the organic content of waste; this results in a biogas that is primarily constituted of CH4 and CO2. Over the last few decades, the conversion of organic matter into hydrogen by means of AD and selecting Hydrogen Producing Bacteria (HPB) has matured into a viable and sustainable technology among the pallet of H2 generation technologies. The combined bio-production of hydrogen and methane from Organic Waste Materials (OWM) is considered to be an ideal way of utilizing waste, and can increase energy efficiency (the substrate Heat Value converted into H2 and CH4 fuel) to roughly 80%, since the energy efficiency of H2-production alone (15%) is not energetically competitive. The two gas streams can be used either separately or in combination (Hytane (R)), be supplied as civilian gas or used for transportation purposes. All the aspects of this sustainable technology are taken into account, from the basic biochemical implications to engineering aspects, establishing the design criteria and the scale-up procedures for full-scale application. The sustainability of the TSAD method is assessed by applying EROI (Energy Return On Investment) and EPT (Energy Payback Time) criteria, and both the general approach and application to the field of Anaerobic Digestion are illustrated.

The present work reflects a multi-disciplinary effort to address the topic of confined hydrosystems developed with a cross-fertilization panel of physics, chemists, biologists, soil and earth scientists. Confined hydrosystems include all situations in natural settings wherein the extent of the liquid phase is limited so that the solid-liquid and/or liquid-air interfaces may be critical to the properties of the whole system. Primarily, this so-called "residual" solution is occluded in pores/channels in such a way that decreases its tendency to evaporation, and makes it long-lasting in arid (Earth deserts) and hyper-arid (Mars soils) areas. The associated physics is available from domains like capillarity, adsorption and wetting, and surface forces. However, many processes are still to understand due to the close relationship between local structure and matter properties, the subtle interplay between the host and the guest, the complex intermingling among static reactivity and migration pathway. Expert contributors from Israel, Russia, Europe and US discuss the behaviour of water and aqueous solutes at different scale, from the nanometric range of carbon nanotubes and nanofluidics to the regional scale of aquifers reactive flow in sedimentary basins. This scientific scope allowed the group of participants with very different background to tackle the confinement topic at different scales. The book is organized according to four sections that include: i) flow, from nano- to mega-scale; ii) ions, hydration and transport; iii) in-pores/channels cavitation; iv) crystallization under confinement. Most of contributions relates to experimental works at different resolution, interpreted through classic thermodynamics and intermolecular forces. Simulation techniques are used to explore the atomic scale of interfaces and the migration in the thinnest angstrom-wide channels.

In this essential new volume, Volume 13: Membrane and Desalination Technologies, a panel of expert researchers provide a wealth of information on membrane and desalination technologies. An advanced chemical and environmental engineering textbook as well as a comprehensive reference book, this volume is of high value to advanced graduate and undergraduate students, researchers, scientists, and designers of water and wastewater treatment systems. This is an essential part of the Handbook of Environmental Engineering series, an incredible collection of methodologies that study the effects of pollution and waste in their three basic forms: gas, solid, and liquid. Chapters adopt the series format, employing methods of practical design and calculation illustrated by numerical examples, including pertinent cost data whenever possible, and exploring in great detail the fundamental principles of the field. Volume 13: Membrane and Desalination Technologies is an essential guide for researchers, highlighting the latest developments in principles of membrane technology, membrane systems planning and design, industrial and municipal waste treatments, desalination requirements, wastewater reclamation, biofiltration, and more.

Gilbert S. Omenn Dean, School of Public Health and Community Medicine University of Washington Seattle, Washington 98195 On behalf of the University of Washington, the City of Seattle, the Steering Committee, and the sponsoring agencies, corporations, and organ izations, I welcome you. \Ve all expect this Conference to stimulate further what is becoming an important application of biotechnology in an area in which our society experiences considerable frustration and gloom: the management of hazardous wastes. It is an all-too-frequent refrain that technology has its benefits and its risks. To many--in the lay pUblic, at least--the damaging notion has taken hold that we are capable of creating problems but are less capable of finding solutions. Chemical streams from industry, agriculture, municipal operations, and household operations have contaminated groundwater, drinking water, and soils, and have undermined the productivity of agri culture and the quality of life. In the meantime, however, we have im proved our quality of life in immeasurable ways through some related developments. The challenge is to continue the enhancements while modifying or preventing the damage."