Of related interest...

LASER IONIZATION MASS ANALYSIS

Edited by Akos Vertes, Renaat Gijbels, and Fred Adams

Edited by three of the field's leading authorities and featuring contributions from thirteen chemists, this book offers a comprehensive look at the new hardware and investigative possibilities of this form of analysis. The book clearly links theory with applications as well as hardware with hard science. Among topics covered are lasers in mass spectrometry, including instrumentation basic to ion generation for mass analysis; methods of using low and medium laser irradiance; high laser irradiance regime; exotic applications of laser ionization mass spectrometry in space research. 1993 (0-471-53673-3) 584 pp.

STATISTICAL METHODS IN ANALYTICAL CHEMISTRY —Peter C. Meier and Richard E. Zünd

Designed to address the practical day-to-day needs of lab chemists, this practical guide demonstrates the ways in which statistics can be used effectively in analytical work. Chapters 1 and 2 present classical statistical techniques, illustrating them in the context of simple situations. Chapter 3 expands the discussion into ancillary techniques, such as exploratory data analysis, made possible with computing. Chapter 4 presents a number of complex examples that might confront the analyst, while emphasizing the conflicting demands imposed on a possible solution. Chapter 5 presents core sections of programs which complement the equations. Complete with a floppy disk of ready-made programs and data files, here is a clear, real-world introduction to maximizing statistical tools in the lab. 1993 (0-471-58454-1) 352 pp.

PHOTOCHEMICAL VAPOR DEPOSITION—J. G. Eden

Here is an extremely useful overview of photochemical vapor deposition, both its characteristics and potential. The book focuses on the properties of films that have been created by this versatile method and the conditions under which they are grown. The author works from the position that while photochemical vapor deposition (photo-CVD) is not the solution to all low-temperature deposition methodologies, it does provide an added dimension of flexibility to and control over the growth process and has proven to be valuable for those materials and growth steps in device fabrication that are sensitive to the processing temperature. Whenever applicable, the properties of electronic devices incorporating photo-CVD films are presented and numerous tables detail the deposition parameters as well as electrical and structural properties of the films of specific materials. 1992 (0-471-55083-3) 208 pp.

Research and development of solid state gas sensor devices began in the 1950s with several uncoordinated independent efforts. The number and pace of these investigations later accelerated in response to increasing pressure placed on the environment and public health by industrial activities. Since 1970, several thousand articles have been written on the subject, and laboratories around the globe have introduced novel methodologies and devices to address needs associated with particular technological developments. Despite the rapid development of this important new technology, very little has been done to review and coordinate data related to sensor science and technology itself.

Physics, Chemistry and Technology of Solid State Gas Sensor Devices focuses on the underlying principles of solid state sensor operation and reveals the rich fabric of interdisciplinary science that governs modern sensing devices. Beginning with some historical and scientific background, the text proceeds to a study of the interactions of gases with surfaces. Subsequent chapters present detailed information on the fabrication, performance, and application of a variety of sensors.

Types of sensor devices discussed include:

• Gas-sensitive solid state semiconductor sensors
• Photonic and photoacoustic gas sensors
• Fiber optic sensors
• Piezoelectric quartz crystal microbalance sensors
• Surface acoustic wave sensors
• Pyroelectric and thermal sensors

For analytical chemists using solid state sensors in environment-related analysis, and for electrical engineers working with solid state sensors, this book will expand and unify their understanding of these devices, both in theory and practice.

This book presents a systematic description of the electronic and physico-chemical properties of transition-metal carbides and nitrides. This is the first book devoted to the theoretical modelling of refractory carbides and nitrides and alloys based on them. It makes use of computational methods to calculate their spectroscopic, electric, magnetic, superconducting, thermodynamical and mechanical properties. Calculated results on the electronic band structure of ideal binary transition metal carbides and nitrides are presented, and the influence of crystal lattice defects, vacancies and impurities are studied in detail. Data available on chemical bonding and the properties of multi-component carbide- and nitride-based alloys, as well as their surface electronic structure, are described and compared with those of bulk crystals.

This book presents a computational scheme for calculating the electronic properties of crystalline systems at an ab-ini tio Hartree-Fock level of approximation. The first chapter is devoted to discussing in general terms the limits and capabilities of this approximation in solid state studies, and to examining the various options that are open for its implementation. The second chapter illustrates in detail the algorithms adopted in one specific computer program, CRYSTAL, to be submitted to QCPE. Special care is given to illustrating the role and in: fluence of computational parameters, because a delicate compromise must always be reached between accuracy and costs. The third chapter describes a number of applications, in order to clarify the possible use of this kind of programs in solid state physics and chemistry. Appendices A, B, and C contain various standard expressions, formulae, and definitions that may be useful for reference purposes; appendix D is intended to facilitate the interpretations of symbols, conventions, and acronyms that occur in the book. Thanks are due to all those who have contributed to the implementation and test of the CRYSTAL program, especially to V.R. Saunders and M. Causal, and to F. Ricca, E. Ferrero, R. Or lando, E. Ermondi, G. Angonoa, P. Dellarole, G. Baracco

The second edition of a modern introduction to the chemistry and physics of solids. This textbook takes a unique integrated approach designed to appeal to both science and engineering students.

"Review of 1st edition"

"an extremely wide-ranging, useful book that is accessible to anyone with a firm grasp of high school science...this is an outstanding and affordable resource for the lifelong learner or current student." Choice, 2005

The book provides an introduction to the chemistry and physics of solids that acts as a foundation to courses in materials science, engineering, chemistry, and physics. It is equally accessible to both engineers and scientists, through its more scientific approach, whilst still covering the material essential to engineers.

This edition contains new sections on the use of computing methods to solve materials problems and has been thoroughly updated to include the many developments and advances made in the past 10 years, e.g. batteries, solar cells, lighting technology, lasers, graphene and graphene electronics, carbon nanotubes, and the Fukashima nuclear disaster.

The book is carefully structured into self-contained bite-sized chapters to enhance student understanding and questions have been designed to reinforce the concepts presented.

The supplementary website includes Powerpoint slides and a host of additional problems and solutions.

"Introduction to Solid State NMR Spectroscopy" is written for undergraduate and graduate students of chemistry, either taking a course in advanced or solid-state nuclear magnetic resonance spectroscopy or undertaking research projects where solid-state NMR is likely to be a major investigative technique. It will also serve as a practical introduction in industry, where the techniques can provide new or complementary information to supplement other investigative techniques.

By covering solid-state NMR spectroscopy in a clear, straightforward and approachable way with detailed descriptions of the major solid-state NMR experiments focussing on what the experiments do and what they tell the researcher, this book will serve as an ideal introduction to the subject. These descriptions are backed up by separate mathematical explanations for those who wish to gain a more sophisticated quantitative understanding of the phenomena. With additional coverage of the practical implementation of solid-state NMR experiments integrated into the discussion, this book will be essential reading for all those using, or about to use, solid-state NMR spectroscopy.

Dr Melinda Duer is a senior lecturer in the Department of Chemistry at the University of Cambridge, Cambridge, UK.

This comprehensive textbook provides a modern, self-contained treatment for upper undergraduate and graduate level students. It emphasizes the links between structure, defects, bonding, and properties throughout, and provides an integrated treatment of a wide range of materials, including crystalline, amorphous, organic and nano- materials. Boxes on synthesis methods, characterization tools, and technological applications distil specific examples and support student understanding of materials and their design. The first six chapters cover the fundamentals of extended solids, while later chapters explore a specific property or class of material, building a coherent framework for students to master core concepts with confidence, and for instructors to easily tailor the coverage to fit their own single semester course. With mathematical details given only where they strengthen understanding, 400 original figures and over 330 problems for hands-on learning, this accessible textbook is ideal for courses in chemistry and materials science.

Used in materials science, physical chemistry and physics, density functional methods provide a unifying description of electronic properties applicable to all materials while also giving specific information on the system under study. A large number of very different materials and systems (atoms, molecules, macromolecules, clusters, bulk solids, surfaces and interfaces) are presently being studied with methods based on density functional formalism. Density Functional Methods in Chemistry and Materials Science reports the results of this research. This book will be of particular interest to those research materials science from a theoretical standpoint. This work will demonstrate how the formalism has become a methodology leading to useful information on structural and electronic properties of a broad range of materials.

A polymer physics textbook for upper level undergraduates and first year graduate students that can also be used as a useful reference for scientists and engineers working with polymers.

The enormous size of polymer molecules causes their molecular motions to span a broad range of length scales and give rise to viscoelastic behavior. This rate-dependence of the properties is a predominant characteristic of soft materials (rubbers, biopolymers, lubricants, adhesives, etc.). Improving the performance and developing new applications for soft materials require an understanding of the basic principles of how molecular motions underlie physical properties.
This text is intended to provide grounding in fundamental aspects of the dynamic behavior of rubbery materials, adopting a molecular perspective in its treatment to emphasize how microscopic processes are connected to the observed macroscopic behavior. The latest discoveries and advances in the science and technology of rubbery materials are described and critically analyzed.

The second edition of a modern introduction to the chemistry and physics of solids. This textbook takes a unique integrated approach designed to appeal to both science and engineering students.

"Review of 1st edition"

"an extremely wide-ranging, useful book that is accessible to anyone with a firm grasp of high school science...this is an outstanding and affordable resource for the lifelong learner or current student." Choice, 2005

The book provides an introduction to the chemistry and physics of solids that acts as a foundation to courses in materials science, engineering, chemistry, and physics. It is equally accessible to both engineers and scientists, through its more scientific approach, whilst still covering the material essential to engineers.

This edition contains new sections on the use of computing methods to solve materials problems and has been thoroughly updated to include the many developments and advances made in the past 10 years, e.g. batteries, solar cells, lighting technology, lasers, graphene and graphene electronics, carbon nanotubes, and the Fukashima nuclear disaster.

The book is carefully structured into self-contained bite-sized chapters to enhance student understanding and questions have been designed to reinforce the concepts presented.

The supplementary website includes Powerpoint slides and a host of additional problems and solutions.

This book provides a comprehensive and unified account of the structure and properties of crystalline binary adducts. Perhaps better known as molecular complexes and compounds, these crystals are currently estimated (from molecular recognition studies) to make up one quarter of the world's crystals, providing evidence for some sort of special attraction between the two components. DNA is perhaps the most famous example but others (hydrates, solvates, host-guest inclusion complexes, donor-acceptor compounds) pervade the whole body of solid state chemistry. Although much research has been published, there has never been a comprehensive and unified treatment of the whole field. This book has been designed to fill this gap, comparing and contrasting the various examples and the different types of interaction (hydrogen bonding, inclusion and localized or delocalized charge transfer). More than 600 figures, 200 tables and 3500 references are included in the book. Since most 'parent compounds' form a number of adducts, the fraction of crystalline binary adducts is only going to grow making this account just the 'tip of the iceberg.'

This book has been written for those who study or professionally deal with solid state physics. It contains modern concepts about the physics of electrons in solids. It is written using a minimum of mathematics. The emphasis is laid on various physical models aimed at stimulating creative thinking. The book helps the reader choose the most efficient scheme of an experiment or the optimal algorithm of a calculation. Boltzmann and hopping types of conductivity are compared. The qualitative theory of weak localization is presented and its links with the true localization and metal-insulator transitions. Processes that determine the structure of impurity bands are revealed. The concepts introduced in this book are applied to descriptions of granular metals and quasicrystals, as well as the integer quantum Hall effect, emphasizing their universality.

This book describes how the arrangement and movement of atoms in a solid are related to the forces between atoms, and how they affect the behaviour and properties of materials. The book is intended for final year undergraduate students and graduate students in physics and materials science.

The weak or non-conventional hydrogen bond has been the subject of intense scrutiny over recent years. Now available in paperback, this highly acclaimed book provides a critical assessment on this interesting and occasionally controverstial interaction type.

This book is for those familiar with solution-state NMR who are encountering solid-state NMR for the first time. It presents the current understanding and applications of solid-state NMR with a rigorous but readable approach, making it easy for someone who merely wishes to gain an overall impression of the subject without details. This dual requirement is met through careful construction of the material within each chapter.

The book is divided into two parts: "Fundamentals" and "Further Applications." The section on Fundamentals contains relatively long chapters that deal with the basic theory and practice of solid-state NMR. The essential differences and extra scope of solid-state NMR over solution-state is dealt with in an introductory chapter. The basic techniques that all chapters rely on are collected into a second chapter to avoid unnecessary repetition later. Remaining chapters in the "Fundamentals" part deal with the major areas of solid-state NMR which all solid-state NMR spectroscopists should know about. Each begins with an overview of the topic that puts the chapter in context.

The basic principles upon which the techniques in the chapter rely are explained in a separate section. Each of these chapters exemplifies the principles and techniques with the applications most commonly found in current practice.

The "Further Applications" section contains a series of shorter chapters which describe the NMR techniques used in other, more specific areas. The basic principles upon which these techniques rely will be expounded only if not already in the Fundamentals part.

The Physics and Chemistry of Solids is one of the first textbooks to discuss the physics, chemistry and materials aspects of solids from a unified viewpoint. Coverage includes both fundamental principles along with the very latest developments, such as combinatorial library synthesis, mesoporous materials, fullerenes and nanotubules, optical localization and the experimental observation of fractional electronic charge. Lucidly written and richly illustrated, this book will appeal to physicists, chemists, material scientists and engineers studying the solid state. The Physics and Chemistry of Solids features:

• A unique integrated approach to the solid state.
• A carefully structured text, with the first four chapters covering the properties of atoms in solids, whilst the remaining four concentrate on the behaviour of electrons in materials.
• Relatively self-contained chapters allowing for flexibility in the order in which they can be used.
• Many references, examples and applications, along with over 200 problems, carefully selected to test and refresh the reader’s knowledge and extend their understanding.

…this is an excellent book. Dr Paul Monk, Manchester Metropolitan University. There has been a real need for a text to cover this area. I must admit my deepest admiration for the way the author has put the text together. Dr Mike Morris, University College Cork.

…this promises to be an excellent text. Dr Anthony Powell, Heriot-Watt University.

In this primer to the many-body theory of condensed-matter systems, the authors introduce the subject to the non-specialist in a broad, concise, and up-to-date manner. A wide range of topics are covered including the second quantization of operators, coherent states, quantum-mechanical Green's functions, linear response theory, and Feynman diagrammatic perturbation theory. Material is also incorporated from quantum optics, low-dimensional systems such as graphene, and localized excitations in systems with boundaries as in nanoscale materials. Over 100 problems are included at the end of chapters, which are used both to consolidate concepts and to introduce new material. This book is suitable as a teaching tool for graduate courses and is ideal for non-specialist students and researchers working in physics, materials science, chemistry, or applied mathematics who want to use the tools of many-body theory.

In crystal chemistry and crystal physics, the relations between the symmetry groups (space groups) of crystalline solids are of special importance. Part 1 of this book presents the necessary mathematical foundations and tools: the fundamentals of crystallography with special emphasis on symmetry, the theory of the crystallographic groups, and the formalisms of the needed crystallographic computations. Part 2 gives an insight into applications to problems in crystal chemistry. With the aid of numerous examples, it is shown how crystallographic group theory can be used to make evident relationships between crystal structures, to set up a systematic order in the huge amount of known crystal structures, to predict crystal structures, to analyse phase transitions and topotactic reactions in the solid state, to understand the formation of domains and twins in crystals, and to avoid errors in crystal structure determinations. A broad range of end-of-chapter exercises offers the possibility to apply the learned material. Worked-out solutions to the exercises can be found at the end of the book.

The quest for efficient and durable battery technologies is one of the key challenges for enabling the transition to renewable energy economies. Magnesium batteries, and in particular rechargeable non-aqueous systems, are an area of extensive opportunity and intense research. Rechargeable magnesium batteries hold numerous advantages over current lithium-ion batteries, namely the relative abundance of magnesium to lithium and the potential for magnesium batteries to greatly outperform their Li-ion counterparts. Magnesium Batteries comprehensively outlines the scientific and technical challenges in the field, covering anodes, cathodes, electrolytes and particularly promising systems such as the Mg-S cell. Edited by a leading figure in the field of electrochemical energy storage, with contributions from global experts, this book is a vital resource for students and researchers at all levels. Whether entering into the subject for the first time or extending their knowledge of battery materials across chemistry, physics, energy, engineering and materials science this book provides an ideal reference for anyone interested in the state-of-the-art and future of magnesium batteries.

This book presents a systematic description of the electronic and physico-chemical properties of transition-metal carbides and nitrides. This is the first book devoted to the theoretical modelling of refractory carbides and nitrides and alloys based on them. It makes use of computational methods to calculate their spectroscopic, electric, magnetic, superconducting, thermodynamical and mechanical properties. Calculated results on the electronic band structure of ideal binary transition metal carbides and nitrides are presented, and the influence of crystal lattice defects, vacancies and impurities are studied in detail. Data available on chemical bonding and the properties of multi-component carbide- and nitride-based alloys, as well as their surface electronic structure, are described and compared with those of bulk crystals.

Acid-base cements have been known since the mid-nineteenth century and offer an alternative to polymerization as a route for forming solid substances. They are quick setting materials and some have unusual properties for cements, such as adhesion and translucency. They find diverse applications ranging from the biomedical to the industrial. Despite this there has been a failure to recognize them as constituting a single, well defined class of material. This book attempts to remedy this situation by unifying the subject and treating this range of materials as a single class. Following a brief historical overview, an introductory chapter defines these cements as materials that are formed by reacting a basic powder with an acidic liquid to yield a salt-like matrix. The nature of the cementation process and the cement-forming acids and bases are discussed. Other chapters are devoted to the methods of study, the structure of water and simple polyelectrolyte theory. In the remaining chapters the various types of cements classified according the anionic constituent of the matrix, are described. Thus, there are chapters on polyalkenoate, phosphate, oxychloride, oxysulphate and the non-aqueous phenolate cements. A chapter is devoted to miscellaneous aqueous cements which include the recently discovered polyphosphonate cements.

The structure of much of solid-state theory comes directly from group theory, but until now there has been no elementary introduction to the band theory of solids which adopts this approach. This book provides such an introduction, employing only the simplest and most basic of group theoretical ideas, and emphasizing the significance of symmetry in determining many of the essential concepts used in the subject. Given the extensive training of chemists in applying group theory, there is no quicker entry into the subject than by means of the approach used in this book. Many topics were chosen with the needs of chemists in mind, and many of the examples have a chemical flavour. Numerous problems are included which enable the reader to apply the major ideas and to complete some parts of the treatment. Chemists will find this a valuable introduction to band theory, and the book will also appeal to all physical scientists who would like to go a little beyond the elementary treatments so far available.

This sixth volume of the Crystallographic Computing series explores the application of windowing techniques and object-oriented programming to crystallography. Featuring presentations given at the renowned Vesprem School on Crystallographic Computing, the book covers a wide range of subjects regarding the state of crystallographic software, such as recent advances in powder diffraction techniques, structure and solution, and refinement. The tricky problem of dealing with disorder in the interpretation of diffraction data is given clear coverage. In addition, introductory sections explaining new features in program systems are included, and, in an age of ever-increasing quantities of data, the rationale behind the standardization and portability of crystallographic data through the use of CIF files is cogently defined. The book will appeal to crystallography teachers, students, and researchers interested in the latest computer applications in their field.

Most people are familiar with the fact that diamond and graphite are both composed only of carbon; yet they have very different properties which result from the very different structures of the two solids - they are polymorphs of carbon. Understanding the relationship between the structures and the properties of materials is of fundamental importance in developing and producing new materials with improved or new properties. The existence of polymorphic systems allows the direct study of the connection between structures and properties. This book provides grounding on the fundamental structural and energetic basis for polymorphism, the preparation and characterization of polymorphic substances and its importance in the specific areas of pharmaceuticals, pigments and high energy (explosive) materials. The closing chapter describes the intellectual property implications and some of the precedent patent litigations in which polymorphism has played a central role. The book contains over 2500 references to provide a ready entry into the relevant literature.

Most people are familiar with the fact that diamond and graphite are both composed only of carbon; yet they have very different properties which result from the very different structures of the two solids - they are polymorphs of carbon. Understanding the relationship between the structures and the properties of materials is of fundamental importance in developing and producing new materials with improved or new properties. The existence of polymorphic systems allows the direct study of the connection between structures and properties. This book provides grounding on the fundamental structural and energetic basis for polymorphism, the preparation and characterization of polymorphic substances and its importance in the specific areas of pharmaceuticals, pigments and high energy (explosive) materials. The closing chapter describes the intellectual property implications and some of the precedent patent litigations in which polymorphism has played a central role. The book contains over 2500 references to provide a ready entry into the relevant literature.