Acid-base cements have been known since the mid-nineteenth century and offer an alternative to polymerization as a route for forming solid substances. They are quick setting materials and some have unusual properties for cements, such as adhesion and translucency. They find diverse applications ranging from the biomedical to the industrial. Despite this there has been a failure to recognize them as constituting a single, well defined class of material. This book attempts to remedy this situation by unifying the subject and treating this range of materials as a single class. Following a brief historical overview, an introductory chapter defines these cements as materials that are formed by reacting a basic powder with an acidic liquid to yield a salt-like matrix. The nature of the cementation process and the cement-forming acids and bases are discussed. Other chapters are devoted to the methods of study, the structure of water and simple polyelectrolyte theory. In the remaining chapters the various types of cements classified according the anionic constituent of the matrix, are described. Thus, there are chapters on polyalkenoate, phosphate, oxychloride, oxysulphate and the non-aqueous phenolate cements. A chapter is devoted to miscellaneous aqueous cements which include the recently discovered polyphosphonate cements.

The Physics and Chemistry of Solids is one of the first textbooks to discuss the physics, chemistry and materials aspects of solids from a unified viewpoint. Coverage includes both fundamental principles along with the very latest developments, such as combinatorial library synthesis, mesoporous materials, fullerenes and nanotubules, optical localization and the experimental observation of fractional electronic charge. Lucidly written and richly illustrated, this book will appeal to physicists, chemists, material scientists and engineers studying the solid state. The Physics and Chemistry of Solids features:

• A unique integrated approach to the solid state.
• A carefully structured text, with the first four chapters covering the properties of atoms in solids, whilst the remaining four concentrate on the behaviour of electrons in materials.
• Relatively self-contained chapters allowing for flexibility in the order in which they can be used.
• Many references, examples and applications, along with over 200 problems, carefully selected to test and refresh the reader’s knowledge and extend their understanding.

This book is one of the first attempts to lift the artificial boundary between solid state physics and chemistry. This book is well structured and written in a clear style. Professor Tjipke Hibma, University of Gröningen.

…this is an excellent book. Dr Paul Monk, Manchester Metropolitan University. There has been a real need for a text to cover this area. I must admit my deepest admiration for the way the author has put the text together. Dr Mike Morris, University College Cork.

…this promises to be an excellent text. Dr Anthony Powell, Heriot-Watt University.

This book covers the fundamentals of conventional transmission electron microscopy (CTEM) as applied to crystalline solids. In addition to including a large selection of worked examples and homework problems, the volume is accompanied by a supplementary website (http://ctem.web.cmu.edu/) containing interactive modules and over 30,000 lines of free Fortran 90 source code. The work is based on a lecture course given by Marc De Graef in the Department of Materials Science and Engineering at Carnegie Mellon University.

How can elements be combined to produce a solid with specified properties? This book acquaints readers with the established principles of crystallography and cohesive forces needed to address the fundamental relationship among composition, structure and bonding. Starting with an introduction to periodic trends, the book discusses crystal structures and the various primary and secondary bonding types, and finishes by describing a number of models for predicting phase stability and structure. Its large number of worked examples, exercises, and detailed descriptions of numerous crystal structures make this an outstanding advanced undergraduate or graduate-level textbook for students of materials science.

Now in paperback, this book provides an overview of the physics of condensed matter systems. Assuming a familiarity with the basics of quantum mechanics and statistical mechanics, the book establishes a general framework for describing condensed phases of matter based on symmetries and conservation laws. After surveying the structure and properties of materials with different symmetries, it explores the role of spatial dimensionality and microscopic interactions in determining the nature of phase transitions. Particular attention is given to critical phenomena and renormalization group methods. The properties of liquids, liquid crystals, quasicrystals, crystalline solids, magnetically ordered systems and amorphous solids are investigated in terms of their symmetry, generalized rigidity, hydrodynamics and topological defect structure. In addition to serving as a course text, this book is an essential reference for students and researchers in physics, applied physics, chemistry, materials science and engineering, who are interested in modern condensed matter physics.

This book is for those familiar with solution-state NMR who are encountering solid-state NMR for the first time. It presents the current understanding and applications of solid-state NMR with a rigorous but readable approach, making it easy for someone who merely wishes to gain an overall impression of the subject without details. This dual requirement is met through careful construction of the material within each chapter.

The book is divided into two parts: "Fundamentals" and "Further Applications." The section on Fundamentals contains relatively long chapters that deal with the basic theory and practice of solid-state NMR. The essential differences and extra scope of solid-state NMR over solution-state is dealt with in an introductory chapter. The basic techniques that all chapters rely on are collected into a second chapter to avoid unnecessary repetition later. Remaining chapters in the "Fundamentals" part deal with the major areas of solid-state NMR which all solid-state NMR spectroscopists should know about. Each begins with an overview of the topic that puts the chapter in context.

The basic principles upon which the techniques in the chapter rely are explained in a separate section. Each of these chapters exemplifies the principles and techniques with the applications most commonly found in current practice.

The "Further Applications" section contains a series of shorter chapters which describe the NMR techniques used in other, more specific areas. The basic principles upon which these techniques rely will be expounded only if not already in the Fundamentals part.

In the new edition of this widely praised textbook, all the chapters have been revised and the authors have brought the work completely up to date by the addition of new material on numerous topics. In recent years, solid state chemistry has emerged as a very important element of mainstream chemistry and materials science. Students, teachers and researchers need to understand the chemistry of solids because of the crucial role this plays in determining the properties of materials. An understanding of solid state chemistry is also essential in materials design, and many fascinating relationships between the structure and properties of solids have been discovered by chemists. This text requires only an understanding of basic physics, chemistry and crystallography, and is enhanced with the most recent examples, case studies and references. It will be of value to advanced students and researchers studying solid state chemistry and materials science as a text and reference work.

Of related interest...

LASER IONIZATION MASS ANALYSIS

Edited by Akos Vertes, Renaat Gijbels, and Fred Adams

Edited by three of the field's leading authorities and featuring contributions from thirteen chemists, this book offers a comprehensive look at the new hardware and investigative possibilities of this form of analysis. The book clearly links theory with applications as well as hardware with hard science. Among topics covered are lasers in mass spectrometry, including instrumentation basic to ion generation for mass analysis; methods of using low and medium laser irradiance; high laser irradiance regime; exotic applications of laser ionization mass spectrometry in space research. 1993 (0-471-53673-3) 584 pp.

STATISTICAL METHODS IN ANALYTICAL CHEMISTRY —Peter C. Meier and Richard E. Zünd

Designed to address the practical day-to-day needs of lab chemists, this practical guide demonstrates the ways in which statistics can be used effectively in analytical work. Chapters 1 and 2 present classical statistical techniques, illustrating them in the context of simple situations. Chapter 3 expands the discussion into ancillary techniques, such as exploratory data analysis, made possible with computing. Chapter 4 presents a number of complex examples that might confront the analyst, while emphasizing the conflicting demands imposed on a possible solution. Chapter 5 presents core sections of programs which complement the equations. Complete with a floppy disk of ready-made programs and data files, here is a clear, real-world introduction to maximizing statistical tools in the lab. 1993 (0-471-58454-1) 352 pp.

PHOTOCHEMICAL VAPOR DEPOSITION—J. G. Eden

Here is an extremely useful overview of photochemical vapor deposition, both its characteristics and potential. The book focuses on the properties of films that have been created by this versatile method and the conditions under which they are grown. The author works from the position that while photochemical vapor deposition (photo-CVD) is not the solution to all low-temperature deposition methodologies, it does provide an added dimension of flexibility to and control over the growth process and has proven to be valuable for those materials and growth steps in device fabrication that are sensitive to the processing temperature. Whenever applicable, the properties of electronic devices incorporating photo-CVD films are presented and numerous tables detail the deposition parameters as well as electrical and structural properties of the films of specific materials. 1992 (0-471-55083-3) 208 pp.

Research and development of solid state gas sensor devices began in the 1950s with several uncoordinated independent efforts. The number and pace of these investigations later accelerated in response to increasing pressure placed on the environment and public health by industrial activities. Since 1970, several thousand articles have been written on the subject, and laboratories around the globe have introduced novel methodologies and devices to address needs associated with particular technological developments. Despite the rapid development of this important new technology, very little has been done to review and coordinate data related to sensor science and technology itself.

Physics, Chemistry and Technology of Solid State Gas Sensor Devices focuses on the underlying principles of solid state sensor operation and reveals the rich fabric of interdisciplinary science that governs modern sensing devices. Beginning with some historical and scientific background, the text proceeds to a study of the interactions of gases with surfaces. Subsequent chapters present detailed information on the fabrication, performance, and application of a variety of sensors.

Types of sensor devices discussed include:

• Gas-sensitive solid state semiconductor sensors
• Photonic and photoacoustic gas sensors
• Fiber optic sensors
• Piezoelectric quartz crystal microbalance sensors
• Surface acoustic wave sensors
• Pyroelectric and thermal sensors

For analytical chemists using solid state sensors in environment-related analysis, and for electrical engineers working with solid state sensors, this book will expand and unify their understanding of these devices, both in theory and practice.

In this primer to the many-body theory of condensed-matter systems, the authors introduce the subject to the non-specialist in a broad, concise, and up-to-date manner. A wide range of topics are covered including the second quantization of operators, coherent states, quantum-mechanical Green's functions, linear response theory, and Feynman diagrammatic perturbation theory. Material is also incorporated from quantum optics, low-dimensional systems such as graphene, and localized excitations in systems with boundaries as in nanoscale materials. Over 100 problems are included at the end of chapters, which are used both to consolidate concepts and to introduce new material. This book is suitable as a teaching tool for graduate courses and is ideal for non-specialist students and researchers working in physics, materials science, chemistry, or applied mathematics who want to use the tools of many-body theory.

The principal objective of this book is to stimulate interest in research that will extend available theory towards a greater understanding of the steps involved in solid-state decompositions and the properties of solids that control reactivities. Much of the activity in this field has been directed towards increasing the range of reactants for which decomposition kinetic data is available, rather than extending insights into the fundamental chemistry of the reactions being studied. The first part of the book (Chapters 1-6) is concerned with theoretical aspects of the subject. The second part (Chapters 7-17) surveys groups of reactions classified by similarities of chemical composition. The final Chapter (18) reviews the subject by unifying features identified as significant and proposes possible directions for future progress.

Studies of thermal reactions of ionic compounds have contributed considerably to the theory of solid-state chemistry. Furthermore, many of these rate processes have substantial technological importance, for example, in the manufacture of cement, the exploitation of ores and in the stability testing of drugs, explosives and oxidizing agents. Despite the prolonged and continuing research effort concerned with these reactions, there is no recent overall review. This book is intended to contribute towards correcting this omission. The essential unity of the subject is recognized by the systematic treatment of reactions, carefully selected to be instructive and representative of the subject as a whole. The authors have contributed more than 200 original research articles to the literature, many during their 25 years of collaboration.

Features of this book:

Gives a comprehensive in-depth survey of a rarely-reviewed subject.

Reviews methods used in studies of thermal decompositions of solids.

Discusses patterns of subject development perceived from an extensive literature survey.

This book is expected to be of greatest value and interest to scientists concerned with the chemical properties and reactions of solids, including chemists, physicists, pharmacists, material scientists, crystallographers, metallurgists and others. This wide coverage of the literature dealing with thermal reactions of solids will be of value to both academic and industrial researchers by reviewing the current status of the theory of the subject. It could also provide a useful starting point for the exploitation of crystalline materials in practical and industrial applications. The contents will also be relevant to a wide variety of researchers, including, for example, those concerned with the stabilities of polymers and composite materials, the processing of minerals, the shelf-lives of pharmaceuticals, etc.
"

The book deals with the environmentally friendly cleaning materials functionalized with TiO2, a widely known semiconductor giving rise to redox reactions under artificial or solar irradiation. The role of Titanium dioxide in the worldwide community is introduced first. The fundamental working principles of heterogeneous photocatalysis follow and a critical section on the semiconductor bulk and surface properties open the way to the differences between TiO2 blend features with respect to analogous thin film layouts. Then follows the main section of the book which deals with the techniques applied to manufactured commercial devices, ranging from glasses to textiles and from concrete and other construction materials to paintings. Also road asphalt and other devices, such as photocatalytic air conditioning machines are outlined. Last generation materials, not yet commercialized, and the deposition techniques applied to prepare them are also widely discussed. The final part of the book covers the difficult and modern topic of standardization and comparison of performance of photocatalytic processes and in particular the guidelines proposed by various worldwide organizations for standardization are discussed. The book covers the general matters as well as the practical applications with the supporting methods discussed in detail. This book brings together a team of highly experienced and well-published experts in the field, providing a comprehensive view of the applications of supported titanium dioxide.

Scattering Methods and their Application in Colloid and Interface Science offers an overview of small-angle X-ray and neutron scattering techniques (SAXS & SANS), as well as static and dynamic light scattering (SLS & DLS). These scattering techniques are central to the study of soft matter, such as colloidal dispersions and surfactant self-assembly. The theoretical concepts are followed by an overview of instrumentation and a detailed description of the evaluation techniques in the first part of the book. In the second part, several typical application examples are used to show the strength and limitations of these techniques.

Most people are familiar with the fact that diamond and graphite are both composed only of carbon; yet they have very different properties which result from the very different structures of the two solids - they are polymorphs of carbon. Understanding the relationship between the structures and the properties of materials is of fundamental importance in developing and producing new materials with improved or new properties. The existence of polymorphic systems allows the direct study of the connection between structures and properties. This book provides grounding on the fundamental structural and energetic basis for polymorphism, the preparation and characterization of polymorphic substances and its importance in the specific areas of pharmaceuticals, pigments and high energy (explosive) materials. The closing chapter describes the intellectual property implications and some of the precedent patent litigations in which polymorphism has played a central role. The book contains over 2500 references to provide a ready entry into the relevant literature.

Long awaited, this textbook fills the gap for convincing concepts to describe amorphous solids. Adopting a unique approach, the author develops a framework that lays the foundations for a theory of amorphousness. He unravels the scientific mysteries surrounding the topic, replacing rather vague notions of amorphous materials as disordered crystalline solids with the well-founded concept of ideal amorphous solids. A classification of amorphous materials into inorganic glasses, organic glasses, glassy metallic alloys, and thin films sets the scene for the development of the model of ideal amorphous solids, based on topology- and statistics-governed rules of three-dimensional sphere packing, which leads to structures with no short, mid or long-range order. This general model is then concretized to the description of specific compounds in the four fundamental classes of amorphous solids, as well as amorphous polyethylene and poly(methyl)methacrylate, emphasizing its versatility and descriptive power. Finally, he includes example applications to indicate the abundance of amorphous materials in modern-day technology, thus illustrating the importance of a better understanding of their structure and properties. Equally ideal as supplementary reading in courses on crystallography, mineralogy, solid state physics, and materials science where amorphous materials have played only a minor role until now.

The quest for efficient and durable battery technologies is one of the key challenges for enabling the transition to renewable energy economies. Magnesium batteries, and in particular rechargeable non-aqueous systems, are an area of extensive opportunity and intense research. Rechargeable magnesium batteries hold numerous advantages over current lithium-ion batteries, namely the relative abundance of magnesium to lithium and the potential for magnesium batteries to greatly outperform their Li-ion counterparts. Magnesium Batteries comprehensively outlines the scientific and technical challenges in the field, covering anodes, cathodes, electrolytes and particularly promising systems such as the Mg-S cell. Edited by a leading figure in the field of electrochemical energy storage, with contributions from global experts, this book is a vital resource for students and researchers at all levels. Whether entering into the subject for the first time or extending their knowledge of battery materials across chemistry, physics, energy, engineering and materials science this book provides an ideal reference for anyone interested in the state-of-the-art and future of magnesium batteries.

Corrosion is a high-cost and potentially hazardous issue in numerous industries. The potential use of diverse carbon nanoallotropes in corrosion protection, prevention and control is a subject of rising attention. This book covers the current advancements of carbon nanoallotropes in metal corrosion management, including the usage of nanostructure materials to produce high-performance corrosion inhibitors and corrosion-resistant coatings.

This book offers comprehensive information on the developments and applications of the solid phase microextraction (SPME) technique. The first part of the book briefly introduces readers to the fundamentals of SPME, while subsequent sections describe the applications of SPME technique in detail, including environmental analysis (air, water, soil/sediments), food analysis (volatile/nonvolatile compounds), and bioanalysis (plants, animal tissues, body fluids). The advantages and future challenges of the SPME technique are also discussed. Including recent research advances and further developments of SPME, the book offers a practical reference guide and a valuable resource for researchers and users of SPME techniques. The target audience includes analytical chemists, environmental scientists, biological scientists, material scientists, and analysts, as well as students at universities/institutes in related fields. Dr. Gangfeng Ouyang is a Professor at the School of Chemistry and Chemical Engineering, Sun Yat-sen University, China. Dr. Ruifen Jiang is an Associate Professor at the School of Environment, Jinan University, China.

This Thesis in biological physics has two components, describing the use of X-ray scattering techniques to study the structure of two different stacked lipid membrane systems. The first part focuses on the interaction between a short 11-mer peptide, Tat, which is part of the Tat protein in the HIV-1 virus. Although highly positively charged, the Tat protein has been shown to translocate through hydrocarbon lipid bilayers easily, without requiring the cell's energy, which is counter to its Born self-energy. In this work Tat's location in the headgroup region was demonstrated using a combined X-ray scattering and molecular dynamics approach. Bilayer thinning was observed as well as softening of different membrane mimics due to Tat. It was concluded that Tat's headgroup location, which increases the area/lipid, and its bilayer softening likely reduce the energy barrier for passive translocation. The second part is a rigorous investigation of an enigmatic phase in the phase diagram of the lipid dimyristoylphosphatidylcholine (DMPC). The ripple phase has fascinated many researchers in condensed matter physics and physical chemistry as an example of periodically modulated phases, with many theoretical and simulation papers published. Despite systematic studies over the past three decades, molecular details of the structure were still lacking. By obtaining the highest resolution X-ray data so far, this work revealed the complex nature of the chain packing, as well as confirming that the major side is thicker than the minor side of the saw-tooth ripple structure. The new model shows that the chains in the major arm are tilted with respect to the bilayer normal and that the chains in the minor arm are slightly more disordered than all-trans gel-phase chains, i.e., the chains in the minor arm are more fluid-like. This work provides the highest resolution X-ray structure of the ripple phase to-date.

The structural phase transition is one of the most fundamental problems in solid state physics. Layered transition-metal dichalcogenides provide us with a most exciting area for the study of structural phase transitions that are associated with the charge density wave (CDW). A large variety of structural phase transitions, such as commensurate and incommensurate transitions, and the physical proper ties related to the formation of a CDW, have been an object of intense study made for many years by methods employing modem microscopic techniques. Rather recently, efforts have been devoted to the theoretical understanding of these experimental results. Thus, McMillan, for example, has developed an elegant phenomenological theory on the basis of the Landau free energy expansion. An extension of McMillan's theory has provided a successful understanding of the successive phase transitions observed in the IT- and 2H-compounds. In addition, a microscopic theory of lattice instability, lattice dynamics, and lattice distortion in the CDW state of the transition-metal dichalcogenides has been developed based on their electronic structures. As a result, the driving force of the CDW formation in the IT- and 2H-compounds has become clear. Furthermore, the effect of lattice fluctuations on the CDW transition and on the anomalous behavior of various physical properties has been made clear microscopically."

Elementary Processes in Excitations and Reactions on Solid Surfaces explores the fundamental nature of dynamics on solid surfaces. Attempts are made to reveal various aspects of elementary processes in excitations and reactions on solid surfaces by recent theoretical and experimental developments of the subjects such as molecular beams interacting with surfaces, ion beam scattering, laser-induced dynamical processes, electronically induced dynamical processes, and optical properties of solid surfaces. This volume is devided into three parts. Part I is concerned mainly with the rich reaction dynamics on potential-energy surfaces. Part II is devoted to the interplay of excitations. In Part III, new and rapidly developing methods are introduced.

Surfaces and interfaces play an increasingly important role in today's solid state devices. In this book the reader is introduced, in a didactic manner, to the essential theoretical aspects of the atomic and electronic structure of surfaces and interfaces. The book does not pretend to give a complete overview of contemporary problems and methods. Instead, the authors strive to provide simple but qualitatively useful arguments that apply to a wide variety of cases. The emphasis of the book is on semiconductor surfaces and interfaces but it also includes a thorough treatment of transition metals, a general discussion of phonon dispersion curves, and examples of large computational calculations. The exercises accompanying every chapter will be of great benefit to the student.

A detailed and timely overview of recent developments in active quasi-optical arrays

In recent years, active quasi-optics has emerged as one of the most dynamic fields of contemporary research—a highly unconventional approach to microwave and millimeter-wave power generation that integrates solid-state devices into a single quasi-optical component in which all devices operate in unison. This book defines and describes active quasi-optical arrays, reviews the current state of the art, and answers numerous basic and technical questions on the design, analysis, and application of these devices.

The contributors to this volume are leading researchers in the field who present results and views from government, industrial, and university laboratories and offer a balanced discussion on a high technical level. They also offer insight into the applicability and commercial value of this technology for military systems, manufacturing processes, communications, and consumer products. Topics presented include:

• Analysis and design methodologies for quasi-optical active arrays
• Power-added and power-combining efficiencies of quasi-optical amplifier arrays
• Phase-shifterless beam steering in oscillator and amplifier arrays
• Integrating quasi-optical active components into a compact subsystem
• Design and fabrication of quasi-optical oscillators, amplifiers, multipliers, and tuners
• Characterization and measurement of quasi-optical components

This book is devoted to the physics, chemistry and materials science of diffusion, mass transport, and reactivity of solids including: physics and chemistry of defects in solids; reactions in and on solids, e.g. intercalation, corrosion, oxidation, sintering; and ion transport measurements, mechanisms and theory.