Historically, technological developments that have made use of the acidity/basicity of solids have often preceded an understanding of the phenomena involved. This, of course, is very expensive, and a far less efficient process than research based on a fundamental understanding of the science. For the last 50 years, therefore, a vast amount of research has been devoted to the subject: the rewards, in terms of technological advantage, were seen to be high. In the last few years, however, significant advances in the field have been achieved, in terms of our theoretical understanding, in instrumentation that allows research to be conducted "in situ" and under conditions appropriate to industrial processes, and in the realization that a closer coupling between science and technology can improve our quest. It is against such a background that "Acidity and Basicity of Solids" presents work in the field. This text should be suitable for specialized workers in the field and university teachers of introductory as well as graduate courses. The more general reader may find the reviews interesting.

Since Surface Coatings first appeared in 1974, the industry has undergone dramatic and rapid changes both in direction and emphasis, and this new edition mirrors these changes. Volume I includes coverage of aqueous systems, with chapters on emulsions and aqueous resins as well as providing an excellent introduction to polymer science, pigments, solvents and additives.

This monograph is intended to give the reader an appreciation of the wealth of phases, elements and inorganic compounds, which crystallize in layer-type or two dimensional structures. Originally this work was planned as a short review article but the large number of phases made it grow out to the size of a book. As is evident from the arrangement of the chapters our point of view was gradually transmuting from geometric to chemical. Moreover, the decision about the compounds that should be discussed was taken only during the course of the work, as is partly evident from the sequence of the references. For chemical or geometrical reason we have included also certain layered chain and molecular structures as well as some layered structures whose layers are linked by hydrogen bonds, thus are in fact three-dimensional. Instead of writing only a review with pseudo-scientific interpretations that later turn out to be wrong anyway we thought it more profitable to include the crystallographic data which are scattered in various original articles and hand books but never in one single volume. We have transcribed many of the data in order to make them correspond with the standard settings of the International Tables for X-Ray Crystallography. The figures are consistent with the data given in the tables. We apologize for errors and hope that their number is at a reasonably low level in spite of the time pressure."

As an instructor in various finishing courses, I have frequently made the statement over the years that "In the field of metal finishing there is very little black and white, just a great deal of grey. It is the purpose of the instructor to familiarize the student with the beacons that will guide him through this fog. " To a very considerable extent, a handbook such as this serves a similar purpose. It is also subject to similar limitations. Providing all the required information would result in a multi-volume encyclopedia rather than a usable handbook. In the pages that follow, you will therefore find frequent references to other sources where more detailed explanations or information can be found. The present goal is proper guidance and the provision ofthe most frequently required facts, not everything that is available. In the 13 years since the last edition, changes in the finishing industry have been profound but in one sense have resulted in simplifying matters rather than complicating them. Because technology has advanced to a level of complexity rendering "home brew" impracti cal in many cases, dependence on proprietary compounds has become common. Therefore, detailed solution compositions are often no longer significant or even practical. It is thus more important to provide instruction about the factors that affect the choice of the most suitable type of proprietary material.

This book is devoted to the rapidly developing field of oxide thin-films and heterostructures. Oxide materials combined with atomic-scale precision in a heterostructure exhibit an abundance of macroscopic physical properties involving the strong coupling between the electronic, spin, and structural degrees of freedom, and the interplay between magnetism, ferroelectricity, and conductivity. Recent advances in thin-film deposition and characterization techniques made possible the experimental realization of such oxide heterostructures, promising novel functionalities and device concepts. The book consists of chapters on some of the key innovations in the field over recent years, including strongly correlated oxide heterostructures, magnetoelectric coupling and multiferroic materials, thermoelectric phenomena, and two-dimensional electron gases at oxide interfaces. The book covers the core principles, describes experimental approaches to fabricate and characterize oxide heterostructures, demonstrates new functional properties of these materials, and provides an overview of novel applications.

The success of spintronics - the science and technology of storing, processing, sensing and communicating information using the quantum mechanical spin degree of freedom of an electron - is critically dependent on the ability to inject, detect and manipulate spins in semiconductors either by incorporating ferromagnetic materials into device architectures or by using external magnetic and electric fields. In spintronics, the controlled generation and manipulation of spin polarization in nonmagnetic semiconductors is required for the design of spin-sensitive devices ranging from spin-qubit hosts, quantum memory and gates, quantum teleporters, spin polarizers and filters, spin-field-effect-transistors, and spin-splitters, among others. One of the major challenges of spintronics is to control the creation, manipulation, and detection of spin polarized currents by purely electrical means. Another challenge is to preserve spin coherence in a device for the longest time or over the longest distance in order to produce reliable spintronic processors. These challenges remain daunting, but some progress has been made recently in overcoming some of the steepest obstacles. This book covers some of the recent advances in the field of spintronics using semiconductors.

In this primer to the many-body theory of condensed-matter systems, the authors introduce the subject to the non-specialist in a broad, concise, and up-to-date manner. A wide range of topics are covered including the second quantization of operators, coherent states, quantum-mechanical Green's functions, linear response theory, and Feynman diagrammatic perturbation theory. Material is also incorporated from quantum optics, low-dimensional systems such as graphene, and localized excitations in systems with boundaries as in nanoscale materials. Over 100 problems are included at the end of chapters, which are used both to consolidate concepts and to introduce new material. This book is suitable as a teaching tool for graduate courses and is ideal for non-specialist students and researchers working in physics, materials science, chemistry, or applied mathematics who want to use the tools of many-body theory.

Solid Phase Microextraction: Theory and Practice Janusz Pawliszyn Solid phase microextraction (SPME) is a recently proposed solvent-free sampling and sample preparation technique. SPME represents a quick, sensitive, and economical approach that can be adopted for field work and can be easily integrated with present analytical instrumentation into an automation process. Written by the inventor of the technique, Solid Phase Microextraction: Theory and Practice describes the theoretical and practical aspects of this new technology, which received an "R&D 100" Award in 1994 recognizing its invention as a major advancement in the analytical sciences. Solid Phase Microextraction: Theory and Practice, the first book on SPME, offers the reader:

• An overview of SPME technique, theory, method development, and applications;
• Experiments for beginners;
• A summary of the practical applications of SPME in environmental, food, pharmaceutical, and forensic settings;
• Material suitable for SPME courses or self-guided study.

In the last thirty years or so, the subject of solid state chemistry has been transformed into materials chemistry by absorbing various features of modern chemical science. The materials investigated by chemists are no longer limited to inorganic materials but include a variety of organic materials. Synthesis has become a major aspect of materials chemistry, with a variety of chemical strategies, soft chemical approaches, in particular, being employed. Studies of structure, properties, phenomena and relating structure to properties are important aspects of materials chemistry.This timely book is a selection of C N R Rao's papers. They stand testament to his over 50 years of work on the chemistry of solid materials. The volume aims to inspire interested readers with a flavor of the current research in solid-state and materials chemistry.

The book deals with the environmentally friendly cleaning materials functionalized with TiO2, a widely known semiconductor giving rise to redox reactions under artificial or solar irradiation. The role of Titanium dioxide in the worldwide community is introduced first. The fundamental working principles of heterogeneous photocatalysis follow and a critical section on the semiconductor bulk and surface properties open the way to the differences between TiO2 blend features with respect to analogous thin film layouts. Then follows the main section of the book which deals with the techniques applied to manufactured commercial devices, ranging from glasses to textiles and from concrete and other construction materials to paintings. Also road asphalt and other devices, such as photocatalytic air conditioning machines are outlined. Last generation materials, not yet commercialized, and the deposition techniques applied to prepare them are also widely discussed. The final part of the book covers the difficult and modern topic of standardization and comparison of performance of photocatalytic processes and in particular the guidelines proposed by various worldwide organizations for standardization are discussed. The book covers the general matters as well as the practical applications with the supporting methods discussed in detail. This book brings together a team of highly experienced and well-published experts in the field, providing a comprehensive view of the applications of supported titanium dioxide.

This new volume in the series Physics and Chemistry of Materials with Layered Structures satisfies the need for a comprehensive review of the progress made in the decade 1972-1982 in the field of the electronic properties of layer compounds. Some recent theoretical and experimental developments are highlighted by authori tative physicists active in current research. The previous books of this series covering similar topics are volumes 3 and 4. The present review is mainly intended to fulfill the gap up to 1982 and part of 1983. I am indebted to all the authors for their friendly co-operation and continuous effort in preparing the contributions in their own fields of competence. I am sure that both the expertise scientists and the beginners in the field of the electronic properties of layered materials will find this book a valuable tool for their research work. Warm thanks are due to Prof. E. Mooser, General Editor of the series, for his constant and authoritative advice. * * * This book has been conceived as a tribute to Prof. Franco Bassani to whom the Italian tradition in the field of layer compounds, as well as in other fields of solid state physics, owes much. The authors of this review have all benefited at some time of their professional life from close cooperation with him. Istituto di Struttura della Materia, VINCENZO GRASSO Universitd di Messina IX V Grasso (ed.). Electronic Structure and Electronic Transitions in Layered Materials. ix."

The principal objective of this book is to stimulate interest in research that will extend available theory towards a greater understanding of the steps involved in solid-state decompositions and the properties of solids that control reactivities. Much of the activity in this field has been directed towards increasing the range of reactants for which decomposition kinetic data is available, rather than extending insights into the fundamental chemistry of the reactions being studied. The first part of the book (Chapters 1-6) is concerned with theoretical aspects of the subject. The second part (Chapters 7-17) surveys groups of reactions classified by similarities of chemical composition. The final Chapter (18) reviews the subject by unifying features identified as significant and proposes possible directions for future progress.

Studies of thermal reactions of ionic compounds have contributed considerably to the theory of solid-state chemistry. Furthermore, many of these rate processes have substantial technological importance, for example, in the manufacture of cement, the exploitation of ores and in the stability testing of drugs, explosives and oxidizing agents. Despite the prolonged and continuing research effort concerned with these reactions, there is no recent overall review. This book is intended to contribute towards correcting this omission. The essential unity of the subject is recognized by the systematic treatment of reactions, carefully selected to be instructive and representative of the subject as a whole. The authors have contributed more than 200 original research articles to the literature, many during their 25 years of collaboration.

Features of this book:

Gives a comprehensive in-depth survey of a rarely-reviewed subject.

Reviews methods used in studies of thermal decompositions of solids.

Discusses patterns of subject development perceived from an extensive literature survey.

This book is expected to be of greatest value and interest to scientists concerned with the chemical properties and reactions of solids, including chemists, physicists, pharmacists, material scientists, crystallographers, metallurgists and others. This wide coverage of the literature dealing with thermal reactions of solids will be of value to both academic and industrial researchers by reviewing the current status of the theory of the subject. It could also provide a useful starting point for the exploitation of crystalline materials in practical and industrial applications. The contents will also be relevant to a wide variety of researchers, including, for example, those concerned with the stabilities of polymers and composite materials, the processing of minerals, the shelf-lives of pharmaceuticals, etc.
"

Scattering Methods and their Application in Colloid and Interface Science offers an overview of small-angle X-ray and neutron scattering techniques (SAXS & SANS), as well as static and dynamic light scattering (SLS & DLS). These scattering techniques are central to the study of soft matter, such as colloidal dispersions and surfactant self-assembly. The theoretical concepts are followed by an overview of instrumentation and a detailed description of the evaluation techniques in the first part of the book. In the second part, several typical application examples are used to show the strength and limitations of these techniques.

Basics of Polymer Chemistry is of great interest to the chemistry audience. The basic properties of polymers, including diverse fundamental and applied aspects, are presented. This book constitutes a basis for understanding polymerization, and it presents a comprehensive overview of the scientific research of polymers. The chapters presented can be used as a reference for those interested in understanding the sustainable development in polymers. Basics of Polymer Chemistry provides a balanced coverage of the key developments in this field, and highlights recent and emerging technical achievements. The topics covered present a comprehensive overview of the subject area and are therefore of interest to professors and students. The recent developments in polymerization using catalysts, homo and copolymerization are presented, and it contains current efforts in designing new polymer architectures. Improved property performance attributes of the polymers by controlling their molecular-structural characteristics such as molecular weight distribution, monomer type content distribution, and branching level are also discussed.

This book presents a systematic description of the electronic and physico-chemical properties of transition-metal carbides and nitrides. This is the first book devoted to the theoretical modelling of refractory carbides and nitrides and alloys based on them. It makes use of computational methods to calculate their spectroscopic, electric, magnetic, superconducting, thermodynamical and mechanical properties. Calculated results on the electronic band structure of ideal binary transition metal carbides and nitrides are presented, and the influence of crystal lattice defects, vacancies and impurities are studied in detail. Data available on chemical bonding and the properties of multi-component carbide- and nitride-based alloys, as well as their surface electronic structure, are described and compared with those of bulk crystals.

The close relationship between experimentalists and theorists whether solid state chemists or physicists has, in the last few years, inspired much research in the field of materials with quasi one-dimensional structures.

Part II of this two-volume set deals with the experimental treatment of pseudo-one-dimensional conductors. Included are contributions on platinum chains, (SN)x and (SNBry)x, the optical properties of 1-D inorganic metals, CDW transport in transition metal chalcogenides, and a lattice dynamical study of transition metal trichalcogenides.

Complex Systems Science in Biomedicine
Thomas S. Deisboeck and J. Yasha Kresh

Complex Systems Science in Biomedicine covers the emerging field of systems science involving the application of physics, mathematics, engineering and computational methods and techniques to the study of biomedicine including nonlinear dynamics at the molecular, cellular, multi-cellular tissue, and organismic level. With all chapters helmed by leading scientists in the field, Complex Systems Science in Biomedicine's goal is to offer its audience a timely compendium of the ongoing research directed to the understanding of biological processes as whole systems instead of as isolated component parts.
In Parts I & II, Complex Systems Science in Biomedicine provides a general systems thinking perspective and presents some of the fundamental theoretical underpinnings of this rapidly emerging field. Part III then follows with a multi-scaled approach, spanning from the molecular to macroscopic level, exemplified by studying such diverse areas as molecular networks and developmental processes, the immune and nervous systems, the heart, cancer and multi-organ failure. The volume concludes with Part IV that addresses methods and techniques driven in design and development by this new understanding of biomedical science.

Key Topics Include:
a [ Historic Perspectives of General Systems Thinking
a [ Fundamental Methods and Techniques for Studying Complex Dynamical Systems
a [ Applications from Molecular Networks to Disease Processes
a [ Enabling Technologies for Exploration of Systems in the Life Sciences

Complex Systems Science in Biomedicine is essential reading for experimental, theoretical, and interdisciplinary scientists working in the biomedical research field interested in a comprehensive overview of this rapidly emerging field.

About the Editors:
Thomas S. Deisboeck is currently Assistant Professor of Radiology at Massachusetts General Hospital and Harvard Medical School in Boston. An expert in interdisciplinary cancer modeling, Dr. Deisboeck is Director of the Complex Biosystems Modeling Laboratory which is part of the Harvard-MIT Martinos Center for Biomedical Imaging.

J. Yasha Kresh is currently Professor of Cardiothoracic Surgery and Research Director, Professor of Medicine and Director of Cardiovascular Biophysics at the Drexel University College of Medicine. An expert in dynamical systems, he holds appointments in the School of Biomedical Engineering and Health Systems, Dept. of Mechanical Engineering and Molecular Pathobiology Program. Prof. Kresh is Fellow of the American College of Cardiology, American Heart Association, Biomedical Engineering Society, American Institute for Medical and Biological Engineering.

Solid-state chemistry is becoming increasingly important as its relevance is recognized in subjects as diverse as superconductivity and heterogeneous catalysis. There has been a long-felt need for an authoritative account of the properties of inorganic solids and of the methods for studying them, written at a level suitable for final-year undergraduates studying the subject as a special topic or for first-year graduate students embarking on research in the field. This and the previous volume aim to fill that gap.

This second volume deals with the electronic structure and bonding in solids, and then focuses on several important classes of inorganic compounds.

As inorganic materials are put to more and more practical uses--mainly in electric, magnetic, and optical devices--materials scientists must have an increasingly sophisticated understanding of the chemical and physical properties of inorganic compounds. This volume--the first of its kind in twenty years--provides a unified presentation of the chemistry of non-stoichiometric compounds based on statistical thermodynamics and structural inorganic chemistry. Four modern examples of non-stoichiometric compounds--ionic conducting compounds, hydrogen absorbing alloys, magnetic materials, and electrical materials--are discussed in detail. Students and researchers in structural inorganic chemistry, crystallography, materials science, and solid state physics will find this much-needed book both practical and informative.

Praise for the First Edition:

"Very useful for researchers in solid-state chemistry and as a textbook of advanced inorganic chemistry for PhD students." —Advanced Materials.

This book provides unified coverage of the structure, properties, and synthesis of transition metal oxides. Written by two world-class scientists, it offers both an excellent window on modern solid-state chemistry and a gateway to understanding the behavior of inorganic solids.

Scientists and advanced students in inorganic and solid-state chemistry, materials science, ceramics, and condensed matter science will welcome this updated Second Edition, which features new or expanded material on:

• Oxyanion derivatives of cuprates, mercury cuprates, ladder compounds, and new oxide systems
• Giant magnetoresistance, superconductivity, and nonlinear materials
• Recently developed synthetic strategies and examples, including soft chemistry routes

Plus:

• Hundreds of illustrations
• Helpful references.

Chemistry has a vital role to play in materials processing and in the development of new materials that can meet the changing needs of today's technology. This volume addresses both the basic underlying principles and the technological relevance of major topics in advanced materials chemistry, including:

• Electron transfer salt-based conductors, superconductors, and magnets
• Advanced polymeric materials-functional electroactive polymers
• Polymers in electronics
• Chemical vapor deposition
• An introduction to the nonlinear optical properties of organic materials
• Nanoparticles and nanostructural materials
• Nanoporous materials
• Molecular precursor routes to inorganic solids
• Layered transition metal oxides and chalcogenides
• Biomaterials

Bringing together a battery of important information in a single source, this stand-alone reference is an invaluable companion for aspiring and practicing organic, inorganic, solid-state, and surface chemists, as well as polymer and materials scientists.

A thorough exploration of the atomic structures and properties of the essential engineering interfaces—an invaluable resource for students, teachers, and professionals

The most up-to-date, accessible guide to solid-vapor, solid-liquid, and solid-solid phase transformations, this innovative book contains the only unified treatment of these three central engineering interfaces. Employing a simple nearest-neighbor broken-bond model, Interfaces in Materials focuses on metal alloys in a straightforward approach that can be easily extended to all types of interfaces and materials. Enhanced with nearly 300 illustrations, along with extensive references and suggestions for further reading, this book provides:

• A simple, cohesive approach to understanding the atomic structure and properties of interfaces formed between solid, liquid, and vapor phases
• Self-contained discussions of each interface—allowing separate study of each phase transformation
• A comparative look at the different interfaces, including atomic structure and crystallography; anisotropy, roughening, and melting; interfacial stability and segregation; continuous and ledge growth models; and atomistic modeling
• An analysis of nearest-neighbor broken-bond results against thermodynamic and kinetic descriptions of the interfaces
• Problem sets at the end of each chapter, emphasizing the key concepts detailed in the text

Spanning the fields of chemical, electrical and computer engineering, materials science, solid-state physics, and microscopy, Interfaces in Materials bridges a major gap in the literature of surface and interface science.

Discover the exciting, promising field of molecular level artificial photosynthesis
This special volume of Progress in Inorganic Chemistry presents the theory and practice of molecular artificial photosynthesis-a field holding tremendous promise now that molecular solar energy materials are fast becoming competitive with their solid-state counterparts.
The only book on the market to address this important area of inorganic research, Molecular Level Artificial Photosynthetic Materials shows us, in effect, how to imitate the complex natural processes of photosynthesis-featuring state-of-the-art strategies and techniques for creating artificial photosynthetic devices at the molecular level. It takes a multidisciplinary approach, drawing on materials science techniques used in the design of solar energy devices, examining the molecular nature of the chemistry involved, and applying existing knowledge in inorganic photochemistry and photophysics to the growing pool of molecular photonic materials.
Composed of seven superbly crafted contributions by leading experts in the field, this comprehensive work
* Describes molecular components integrated within nanophase materials, gels, zeolites, thin films, and layered solids
* Uses novel time resolved vibrational spectroscopies to elucidate fundamental electron and energy transfer mechanisms in complex supramolecular compounds
* Highlights practical applications such as the conversion of light into electricity, solar detoxification of pollutants, and the production of useful fuels-including the splitting of water into hydrogen and oxygen
* Points to areas of future research and usefulness for inorganic photochemists, as well as for students, chemists, material scientists, physicists, and engineers in a wide range of fields

This volume focuses on the wealth of existing literature on physical metallurgy, and deals with materials in different states of order and the process of order evolution. It is a valuable reference by students and researchers in the field of materials science and metallurgy.

Powder diffraction is a widely used scientific technique in the characterization of materials with broad application in materials science, chemistry, physics, geology, pharmacology and archaeology. Powder Diffraction: Theory and Practice provides an advanced introductory text about modern methods and applications of powder diffraction in research and industry. The authors begin with a brief overview of the basic theory of diffraction from crystals and powders. Data collection strategies are described including x-ray, neutron and electron diffraction setups using modern day apparatus including synchrotron sources. Data corrections, essential for quantitative analysis are covered before the authors conclude with a discussion of the analysis methods themselves. The information is presented in a way that facilitates understanding the information content of the data, as well as best practices for collecting and analyzing data for quantitative analysis. This long awaited book condenses the knowledge of renowned experts in the field into a single, authoritative, overview of the application of powder diffraction in modern materials research. The book contains essential theory and introductory material for students and researchers wishing to learn how to apply the frontier methods of powder diffraction