There is not an extensive literature on street sweeping. Much of the research that has been completed exists in the "gray" area of technical reports and government documents. Furthermore, a great deal of this research is locally based, and has not been widely published. Indeed, our review of the scientific literature, revealed that, while storm water quality has received a lot of attention, few academicians have been involved in street sweeping research per se. Thus, throughout our research into street we sweeper effectiveness, sweeping protocols, and sweeping practices, wished that there had been a book summarizing some of the important issues associated with street sweeping. As our frustration grew, we realized that we were uniquely poised to write such a book as our research had encompassed a variety of different projects including sweeper testing, waste management, and related storm water quality. Also, early on in this exercise, we recognized that there was a growing demand for information about street sweeping policies and management, especially for studies focusing on the effectiveness of different sweeping schedules, on waste management operations, and on non-point, pollution reduction practices associated with storm water runoff. It was abundantly clear that there was a profound lack of research on street sweeping that could assist with developing local, regional, or national policies. There was, in effect, little guidance for city managers on these issues.

Motivation The other day I was waiting at the station for my train. Next to me a young lady was nonchalantly leaning against the wall. Suddenly, she took a cigarette pack out of her handbag, pulled out the last cigarette, put it between her lips, crushed the empty pack, threw it on the ground and hedonistically lit the cigarette. I thought to myself, "What a behavior? ." The nearest trashcan was just five meters away. So I bent down, took the crushed pack and gave it back to her, saying that she had lost it. She looked at me in a rather deranged way, but she said nothing and of waste to the trashcan. brought the piece Often people are not aware of the waste they produce. They get rid of it and that's it. As soon as the charming lady dropped the cigarette pack, the problem was solved for her. The pack was on the ground and it suddenly no longer belonged to her. It is taken for granted that somebody else will do the cleaning up. There is a saying that nature does not produce waste. For long as humans obtained the goods they needed from the ground where they lived, the waste that was produced could be handled by nature. This has drastically changed due to urbanization and waste produced by human activities has become a severe burden.

A survey of recent developments in the field of plutonium disposal by the application of advanced nuclear systems, both critical and subcritical. Current national R&D plans are summarized. The actinide-fuelled critical reactors are associated with control problems, since they tend to have a small delayed neutron fraction coupled with a small Doppler effect and a positive void coefficient. Current thinking is turning to accelerator-driven subcritical systems for the transmutation of actinides. The book's conclusion is that the various systems proposed are technically feasible, even though not yet technically mature. The book presents a unique summary and evaluation of all relevant possibilities for burning surplus plutonium, presented by experts from a variety of different disciplines and interests, including the defence establishment. The obvious issue - the non-proliferation of nuclear weapons - is vital, but the matter represents a complex technological challenge that also requires an assessment in economic terms.

In this timely volume, scientists examine examine the physical, structural, and analytical chemistry of fuel combustion. Their contributions also address the issue of combustion efficiency and how air quality can be protected or improved. Supported by numerous illustrations, this volume be appreciated by researchers and students working in various areas of chemistry.

In 1969 the North Atlantic Treaty Organization (NATO) established the Committee on Chal- lenges of Modern Society (CCMS). The subject of air pollution was from t,lw start one of the priority problems under study within the framework of various pilot. studi('s undertaken by this committee. The organization of a periodic conference dealing with air pollution modelling and its application has become one of the main activities within the pilot ~tudy relatillg to air pollution. The first five international conferences were organized by the United Statcs as the pilot country; the second five by the Federal Republic of Germany: thc third five by sselgium; the next four by The Netherlands; ami the two most recent by Delllllark. This volume contains the papers presented at the 21st NATOjCCMS International Technical Meeting (ITM) on Air Pollution Modelling and Its Application, held in ssaltimorc. Maryland, during November 6-10, 1995. This ITM was jointly organized by the Riso National Laboratory of Denmark (Pilot Country); by the EPA National Exposurp Research Labora- tory, United States (Host Country); and by thc American MNeorologiea.! Soci('t.: *. Cnited States (Host Organization). The ITM was attended by 137 participants representing 29 countri('~ from North and South America, Europe, Asia and Australia. The members of t.hc NATO/CCMS Scientific Committee for the 21st ITM were R.M. van Aalst (The Nethcrlallds), D. Allfossi (Haly), C. Borrego (Portugal), N. Chaumerliac (Francc), H. van Dop (Thc :\Tethcrla.nds). S.-E. Gryning.

Chemical pretreatment of nuclear wastes refers to the sequence of separations processes used to partition such wastes into a small volume of high-level waste for deep geologic disposal and a larger volume of low-level waste for disposal in a near-surface facility. Pretreatment of nuclear wastes now stored at several U. S. Department of Energy sites ranges from simple solid-liquid separations to more complex chemical steps, such as dissolution of sludges and removal of selected radionuclides, e. g. , 90Sr, 99Tc, 137CS, and TRU (transuranium) elements. The driving force for development of chemical pretreatment processes for nuclear wastes is the economic advantage of waste minimization as reflected in lower costs for near-surface disposal compared to the high cost of disposing of wastes in a deep geologic repository. This latter theme is expertly and authoritatively discussed in the introductory paper by J. and L. Bell. Seven papers in this volume describe several separations processes developed or being developed to pretreat the large volume of nuclear wastes stored at the US DOE Hanford and Savannah River sites. These papers include descriptions of the type and amount of important nuclear wastes stored at the Hanford and Savannah River sites as well as presently envisioned strategies for their treatment and final disposal. A paper by Strachan et al. discusses chemical and radiolytic mechanisms for the formation and release of potentially explosive hydrogen gas in Tank 241-SY-101 at the Hanford site.

Co-utilization or blending of residuals offers a unique opportunity to develop products with particular characteristics that are able to target specific customer needs. The very notion of deliberately blending by-products suggests that the recycling and beneficial reuse industries are taking a quantitative step forward towards developing products rather than simply reusing residuals. At the same time that this step provides unique opportunities, it also presents unique challenges. The science associated with the beneficial use of one product may not apply when that product is mixed with another residual. Blending of materials may alter the chemistry of the components of the mixture. This may offer additional benefits, as in the case of disease suppression in composts, or present unexpected problems, as the use of lime-stabilized biosolids has done in Maryland. This book consists of the proceedings of the Beltsville Symposium. The organizers of the Symposium attempted to structure a meeting that would outline both the potential benefits of co-utilization as well as concerns. The editors have divided the proceedings into sections that describe the practical basis for co-utilization of residuals as well as the potential benefits. Specific considerations are described. Finally, case studies include descriptions of successful operations and data that detail results of research involving co-utilization materials. Blending of materials for specific objectives needs to be the focus of any successful co-utilization effort. The scientific implications of the mix need to be determined before a product can be used properly.

The authors explain the rewarding results from the interdisciplinary collaboration between an environmental study group working on coastal ecosystems and effects of oil spills and applied mathematicians modelling wave motion on sandy beaches. By using the unified Navier-Stokes equations with a Bingham fluid model for spilled oil, multi-phase flow analysis were made. Decomposition of spilled oil by bacteria was simulated as a chemical reaction, and the theoretical and numerical analysis suggested a countermeasure to help reduce stress on coastal ecosystems. The new understanding of how ecosystems both depend upon, and help to determine, the nature of the shoreline demonstrates promising ways to better assist and exploit the regenerative powers inherent in nature.

With the end of the Cold War, new opportunities for interaction have opened up between the United States and the countries of the Former Soviet Union. Many of these important initiatives involve the US Department of Energy (DOE) and the Ministry of the Russian Federation for Atomic Energy (MINA TOM). Currently, collaboration is under way which involves reactor safety, the disposition of fissile materials from the weapons program, radioactive waste disposal, and the safety of nuclear warheads. Another fruitful area of interchange resulted from the radiochemical storage tank accident at the site of the Siberian Chemical Compound at Tomsk-7 in 1993. DOE and MINATOM agreed to meet and exchange information about the accident for the purposes of improving safety. A meeting on the Tomsk tank accident was held in Hanford, Washington in 1993, followed by a second meeting in st. Petersburg, Russia in 1994 in which the agenda expanded to include radiochemical processing safety. A third exchange took place in 1995 in Los Alamos, New Mexico, and additional papers were presented on nonreactor nuclear safety. Following a planning session in 1996 in Seattle, Washington, it was decided to hold a fourth technical exchange on the broader subject of nuclear materials safety management. Through a grant from the North Atlantic Treaty Organization (NATO) Disarmament Programme, the meeting took place on March 17- 21, 1997, in Amarillo, Texas as a NATO Advanced Research Workshop (ARW) through grant no. DISRM 961315.

This book represents the proceedings of the first major international meeting dedi cated to discuss environmental aspects of produced water. The 1992 International Pro duced Water Symposium was held at the Catamaran Hotel, San Diego, California, USA, on February 4-7, 1992. The objectives of the conference were to provide a forum where scientists, regulators, industry, academia, and the enviromental community could gather to hear and discuss the latest information related to the environmental considerations of produced water discharges. It was also an objective to provide a forum for the peer review and international publication of the symposium papers so that they would have wide availability to all parties interested in produced water environmental issues. Produced water is the largest volume waste stream from oil and gas production activities. Onshore, well over 90% is reinjected to subsurface formations. Offshore, and in the coastal zone, most produced water is discharged to the ocean. Over the past several years there has been increasing concern from regulators and the environmental commu nity. There has been a quest for more information on the composition, treatment systems and chemicals, discharge characteristics, disposal options, and fate and effects of the produced water. As so often happens, much of this information exists in the forms of reports and internal research papers. This symposium and publication was intended to make this information available, both for open discussion at the conference, and for peer review before publication."

The surplus of plutonium in the world is both an important security issue, and a fact with implications for nuclear energy and environmental policy internationally. The two perspectives are inextricably intertwined in considering options for dealing with the plutonium surplus. It was for this reason that two research programmes at the Royal Institute of International Affairs - respectively on Energy and Environment, and on International Security - jointly approached NATO with a view to organising a work shop on the issue. It was most welcome then to learn that the NATO Science Programe was already supporting plans for a workshop on the issue, initiated by Richard Garwin, and we were pleased to accept the resulting invitation to host that workshop. DrGarwin prepared the initial agenda and established contacts and initial approaches to many of the participants; we were able to develop the agenda further and extend participation in some complementary ways. The result was a most lively and broad-ranging internation al and inter-disciplinary discussion. As the hosts, the RIIA was also given lead responsibility for producing the pro ceedings of the workshop as a publication for NATO. Many of the papers to the work shop are more technical than usually involved in a workshop at the Royal Institute. Yet this is an area in which the policy options are unusually dependent upon a good under standing of the technical issues. which themselves are often a matter of dispute."

Significant amounts of liquid and solid radioactive waste have been generated in Russia during the production of nuclear weapons, and there is an urgent need to find suitable ways to manage these wastes in a way that protects both the current population and future generations. This book contains contributions from pure and applied scientists and other representatives from Europe, North America, and Russia, who are, or have been, actively involved in the field of radioactive waste management and disposal. First-hand experience of specific problems associated with defence-related wastes in the USA and the Russian Federation is presented, and current plans are described for the disposal of solid wastes arising from civilian nuclear power production programmes in other countries, including Belgium, Bulgaria, Canada, Germany and the UK. The book provides a good insight into ongoing research at local and national level within Russia, devoted to the safe disposal of defence-related radioactive waste. It also demonstrates how existing expertise and technology from civilian nuclear waste management programmes can be applied to solving the problems created by nuclear defence programmes. Contributions address methods of immobilisation, site selection methodology, site characterisation techniques and data interpretation, the key elements of safety/performance assessments of planned deep (geological) repositories for radioactive waste, and radionuclide transport modelling. Concerns associated with certain specific nuclear waste disposal concepts and repository sites are also presented.

Leon N. Moses In June 1991, the Transportation Center at Northwestern University sponsored Hazmat Transport '91: A National Conference on the Transportation of Hazardous Materials and Wastes. The faculty associated with the center were aware that there had been many professional, industrial and government conferences and meetings on the subject. However, they believed that the unique capacity of the Transportation Center to bring together leaders from industry and government, as well as leading scholars from economics, law, engineering, psychology and sociology who have done research on the problems associated with the transportation of hazardous materials and wastes (hazmats), could produce a set of integrated insights and understandings that would go well beyond those of previous conferences. The papers that make up this volume were all delivered at Hazmat Transport '91. From a legislative point of view, they tend to deal with issues associated with the Hazardous Materials Transportation Act of 1975 (HMTA), the original act passed to regulate the transportation of hazardous materials, and the Hazardous Materials Transportation Uniform Safety Act of 1990 (HMTVSA). There were talks and papers presented at the conference that focused on other recent legislation and transportation issues with which HMTUSA does not deal. The conference proceedings volume also had discussions and papers on significant managerial and regulatory issues that could not be included in this volume because of constraints on its size. Therefore, this essay is made up of three parts.

Prior to 1979, consideration of the problem of the carcinogenicity of the aromatic amine class of chemicals took place primarily in poster sessions and symposia of annual meetings of the American Association for Cancer Research and analogous international associations. In November 1979 the first meeting concerned with the aromatic amines was held in Rockville, Haryland under primary sponsorship of the National Cancer Institute. The proceedings from this meeting were published as Monograph 58 of the Journal of the National Cancel' Institute in 1981. The second meeting in this series, the Second International Conference on N-Substituted Aryl Compounds, was held in March/April of 1982 in Hot Springs, Arkansas. The National Cancer Institute and The National Center for Toxicological Research were the primary sponsors of this meeting. The proceedings were published as Volume 49 of the journal En-vil'onmental Health Perspectives in 1983. The third meeting in this series was held in April of 1987 at the Dearborn Hyatt in Dearborn, Michigan. The principal sponsor of this meeting was the Heyer L. Pre ntis Comprehensive Cancer Center of Metropolitan Detroit. The proceedings, Carcinogenic and Mutagenic Responses to Aromatic Amines and Nitroal'enes, were published in 1987 by Elsevier Press. The fourth meeting was held in Cleveland, Ohio, on July 15-19, 1989.

Based on a symposium sponsored by the Environmental Division of the American Chemical Society, Perchlorate in the Environment is the first comprehensive book to address perchlorate as a potable water contaminant. The two main topics are: analytical chemistry (focusing on ion chromatography and electrospray ionization mass spectrometry), and treatment or remediation. Also included are topics such as ion exchange, phytoremediation, bacterial reduction of perchlorate, bioreactors, and in situ bioremediation. To provide complete coverage, background chapters on fundamental chemistry, toxicology, and reulatory issues are also included. The authors are environmental consultants, government researchers, industry experts, and university professors from a wide array of disciplines.

A survey of the feasibility of aircraft- and satellite-based methods for revealing environmental-geological problems. Throughout, a balanced ratio between explanations on the methodological/technical side and presentations of case studies is maintained. The comparison of case studies from North America and Germany shows how the respective territorial conditions lead to distinct methodological approaches. Equally, the considerable dissimilarities in population density and in distances between waste disposal areas, settlements, and areas of protected groundwater necessitate a "diversified methods" approach.

Since their first industrial use polymers have gained a tremendous success. The two volumes of "Polymers - Opportunities and Risks" elaborate on both their potentials and on the impact on the environment arising from their production and applications. Volume 11 "Polymers - Opportunities and Risks I: General and Environmental Aspects" is dedicated to the basics of the engineering of polymers - always with a view to possible environmental implications. Topics include: materials, processing, designing, surfaces, the utilization phase, recycling, and depositing. Volume 12 "Polymers - Opportunities and Risks II: Sustainability, Product Design and Processing" highlights raw materials and renewable polymers, sustainability, additives for manufacture and processing, melt modification, biodegradation, adhesive technologies, and solar applications. All contributions were written by leading experts with substantial practical experience in their fields. They are an invaluable source of information not only for scientists, but also for environmental managers and decision makers.

The management and disposal of radioactive wastes are key international issues requiring a sound, fundamental scientific basis to insure public and environmental protection. Large quantities of existing nuclear waste must be treated to encapsulate the radioactivity in a form suitable for disposal. The treatment of this waste, due to its extreme diversity, presents tremendous engineering and scientific challenges. Geologic isolation of transuranic waste is the approach currently proposed by all nuclear countries for its final disposal. To be successful in this endeavor, it is necessary to understand the behavior of plutonium and the other actinides in relevant environmental media. Conceptual models for stored high level waste and waste repository systems present many sCientific difficulties due to their complexity and non-ideality. For example, much of the high level nuclear waste in the US is stored as alkaline concentrated electrolyte materials, where the chemistry of the actinides under such conditions is not well understood. This lack of understanding limits the successful separation and treatment of these wastes. Also, countries such as the US and Germany plan to dispose of actinide bearing wastes in geologic salt deposits. In this case, understanding the speciation and transport properties of actinides in brines is critical for confidence in repository performance and risk assessment activities. Many deep groundwaters underlying existing contaminated sites are also high in ionic strength. Until recently, the scientific basis for describing actinide chemistry in such systems was extremely limited."

A review of such natural disasters as floods and landslides, highlighting the possibility of safe and correct land planning and management by means of a global approach to territory. Since the events deriving from slope and fluvial dynamics are commonly triggered by the same factor, occur at the same time and are closely related, this book analyses floods and slope stability phenomena as different aspects of the same dynamic system: the drainage basin.

The purpose of these proceedings was to address the technological, economic, insti- tutional and social questions raised by the rapidly evolving u se of biotechnology for the protection. restoration, and sustainability of our environment. The symposium, "Biotech- nology in the Sustainable Environment" emphasized the future-oriented nature of biotech- nology, that is, the potential use of biotechnology in upstream decisions about materials management, in addition to the status and directions of urrent c applications. This sympo- sium incorporated statc-of-the-science. as well as risk and policy issues into the lopics of biotechnology and remediation, waste treatment, environmental evaluation and monitor- ing, and versatility and future directions in biotechnology and sustainability. Achieving a sustainable environment cannot be accomplished by one discipline or one sector of soci- ety. Likewise, long-term environmental sustainability cannot be accomplished by one gov- ernment. Sustainability must be a global effort as is evident from the multinational participation in these proceedings. The importance of biotechnology, sustainability, and the environment is highlighted by the combined support that this discipline receives from industry and the government. In this regard, we acknowledge the foresight of the sponsors and supporters of this sympo- sium: Eastman Chemical Company, E. !. DuPont De Nemours and Company, Inc.

The ffiM Japan International Symposium Energy and Environment - Global Warming was held in the Keidanren Guesthouse at the foot of Mt. Fuji, from October 21 to 24, 1990. The symposium was conducted in the context of ffiM Japan's longstanding commitment to good corporate citizenship. On this beautiful planet with its inter-dependent waters, lands and atmo sphere, we consider that the problems relating to the global environment are the most serious that the human race will face in the near future. The symposium provided an opportunity for forty scientists and researchers, from a wide variety of international backgrounds, to address matters relating to the global environment in an international forum. Eighteen papers were presented followed by panel and group discussions, on which the concluding remarks and recommendations are based. We chose three types of papers to target different aspects of the condition of the global environment: the natural science component; the socio-economic component; and the energy component which links these two. On the first day the symposium began with a plenary speech by Dr. J. Kondo followed by three keynote speeches, each with a particular focus. The following day, six speakers offered papers relating to the previous day's keynote speeches."

This manuscript was made possible by the exceptional support provided by INSA (Institut National des Sciences Appliquees) Toulouse, the University of New Mexico and the University of Cincinnati College of Engineering. The authors, as listed in this book, took the time to prepare excellent manuscripts focusing on scientific and technical areas relevant to emerging environmental issues. These manuscripts were rigorously reviewed and refereed by scientists and engineers before inclusion in this book. An introductory chapter was prepared to summarize and integrate technical issues covered and the last chapter was written to present policy perspectives. The editors are most grateful to the contributors, sponsor organizations, and many colleagues who were kind enough to assist us in making this manuscript possible. Background information about the editors, principal authors and other contributor: s to this manuscript follows. Editors Professor Dr. Ravi K. Jain Associate Dean for Research and International Engineering College of Engineering University of Cincinnati Mail Location 0018 Cincinnati OH 45221-0018 U.S.A

Purpose ofthe Workshop In the spirit of enhancing developments in science and technology by facilitating international scientific cooperation, the Science Committee of NATO is sponsoring AR W's in several selected priority areas. The objective of this workshop was to discuss what microbial mediated problems have been experienced in the area of nuclear waste management and spent fuel storage. Long term storage of high-level wastes in repositories is just starting in some countries. However, low and medium level wastes have been stored for several decades. In the area of spent fuel interim, storage has been extended at many locations far beyond the intended time. It was a priority of the workshop to examine and discuss what deleterious effects have been observed under these storage conditions or under conditions used in simulated trial tests for predicting material performance under the storage conditions. For example, one chronic problem that was discussed was possibility that microbial influenced corrosion (MIC) could be taking place in the wet storage of spent fuel thereby initiating or accelerating the process of corrosion. Another discussion in the area of waste forms, focused on the presence ofbiofilms which may be breaking down the structure of the waste form and thereby jeopardizing its integrity. The meeting focused on discussing the observations and data collected relating to problems encountered in the storage of these types of wastes, and sharing this information with others that have not monitored their facilities for similar problems.

This book originated in a series of cross-disciplinary conversations in the years 1984-1990 between the editor, who is a physician-researcher involved in clinical and laboratory research, and a dioxin toxicologist. During the years in which the conversations took place, an extraordinary amount of new scientific literature was published related to dioxins, defined for purposes of this text as the chlorinated dibenzo-p-dioxins, dibenzofurans, polychlorinated biphe nyls (PCB's) and other compounds that are structurally and toxicologically similar to 2,3,7,8-tetrachlorodibenzo-p-dioxin (2,3,7 ,8-TCDD), the most extensively studied and most toxic of this group of chemicals. Dioxins also began to interest not only chemists and toxicologists, but also specialists from diverse disciplines such as wildlife and environmental science, immunology, neuroscience,public health, epidemiology, med icine, government, law, sociology, and journalism. Specialists from such varied disciplines, while familiar with their own literature, frequently did not have time to follow the dioxin literature outside their specialty area. In addition, each specialty had unique knowledge, methods, and perspectives. Cross disciplinary conversation was necessary, but all too frequently, specialists from the various disciplines did not speak the same language, resulting in misunderstanding.

The discipline of surface and colloid chemistIy has experienced a considerable resurgence since the early sixties. This perhaps reflects a growing realisation of the wide applicability of modern colloid and surface theory to many important industrial, medical and environmental problems. This increased activity has resulted in a very complex and at times even confusing area of science being consolidated within a firm theoretical framework. The clearer insights gained into the underlying principles have no doubt acted in an autocatalytic manner to stimulate further interest in an expanding range of applications. A good example in the area of environmental chemistry has been the realization of the important role played by colloidal material and surface interactions in natural biogeochemical processes that has been the subject of increasing attention over the last few decades. This is well illustrated by the numerous studies carried out to elucidate the speciation, toxicity, transport and fate of pollutants in aquatic systems. In the vast majority cases these have clearly implicated some involvement of an aSSOciation between the of pollutant (e. g. trace metal, toxic organic compound or nutrient) and a colloidal component (e. g. particle, humic substance, foam). In order to understand these interactions fully and their effect on pollutant mobility it is important to develop a full appreciation of the surface chemistry of these complex systems. Australian SCientists have long been prominent in the area of colloid and surface chemistry particularly dUring the latter half of this century.