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Books > Science & Mathematics > Chemistry > Physical chemistry > Catalysis
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Oxygenates by Homologation or CO Hydrogenation with Metal Complexes (Hardcover, 1994 ed.)
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Oxygenates by Homologation or CO Hydrogenation with Metal Complexes (Hardcover, 1994 ed.)
Series: Catalysis by Metal Complexes, 16
Expected to ship within 10 - 15 working days
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The homogeneous catalytic hydrogenation of CO and the carbonylation
and homologation of alcohols and their derivatives emerged nearly
40 years ago, in the U.S.A. and Germany. Since that time, the two
topics have generally been reviewed separately, with no concern for
their common aspects, in terms of both the chemical transformations
involved, nor for the catalytic aspects, until Japanese workers,
during the National C1 Chemistry Project, which ran from 1980 to
1987, unified both the scientific and technological approaches in
the field. The literature from 1940--1980 has been well reviewed,
and so the time is now ripe for a thorough, careful review of work
accomplished since then. Under the editorial inspiration of
Professor Braca, Oxygenates by Homologation or CO Hydrogenation
with Metal Complexes presents an authoritative reconsideration and
review of research on oxygenate production by CO hydrogenation, and
the homologation of alcohols, aldehydes, ethers and esters in the
presence of transition metal complexes. The three chapters of the
book, each presenting a masterly overview of its topic, are
entitled: Monoalcohols, Glycols and their Ethers and Esters by CO
Hydrogenation; Alcohols and Derivatives by Homologation with
SynGas; and Hydrocarbonylation of Aldehydes and their Derivatives.
The chapters are presented in a common format, presenting the
performances of the catalytic systems of different metals, followed
by a general discussion of the reaction mechanism along the
successive reaction steps, from the activation of the substrates up
to their chemical modification and the restoration of the
catalysts. Attention is also paid to the problems of stability and
deactivation of thecatalytic systems and to the difficulties of the
industrial development of the reactions. (2nd text) This volume
presents an overview of the current status of research into
homogeneous phase catalytic carbon monoxide hydrogenation and the
carbonylation and homologation of alcohols and their derivatives,
with emphasis on the progress which has been made since 1982. The
concents are divided into three major chapters. Chapter 1 deals
with monoalcohols, glycols and their ethers and esters by carbon
monoxide hydrogenation. Chapter 2 discusses alcohols and their
derivatives by homologation with syngas. Chapter 3 considers the
hydrocarbonylation of aldehydes and their derivatives. The
organization of the material in each of these chapters follows a
common scheme. The performance of catalytic systems of different
metals is presented and then reaction mechanisms are discussed for
successive reaction steps, from the activation of substrates to
their chemical modifications and the restoration of catalysts.
Attention is also paid to problems of stability and deactivation of
catalytic systems. The difficulties associated with the industrial
development of the various reactions is also considered. For
research organic chemists in academia and industry whose work
involves catalysis.
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