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Phase Diagrams and Ceramic Processes (Paperback, Softcover reprint of hardcover 1st ed. 1997)
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Phase Diagrams and Ceramic Processes (Paperback, Softcover reprint of hardcover 1st ed. 1997)
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Ceramic products are fabricated from selected and consolidated raw
materials through the application of thermal and mechanical energy.
The complex connec tions between thermodynamics, chemical
equilibria, fabrication processes, phase development, and ceramic
properties define the undergraduate curriculum in Ceramic Science
and Ceramic Engineering. Phase diagrams are usually introduced into
the engineering curriculum during the study of physical chemistry,
prior to specialization into ceramic engineering. This creates an
artificial separation between consideration of the equilibrium
description of the chemically heterogeneous system and the
engineering and physical processes required for phase,
microstructure, and property development in ceramic materials.
Although convenient for instructional purposes, the separa tion of
these topics limits the effective application of phase diagram
information by the ceramic engineer in research and manufacturing
problem solving. The nature of oxide phases, which define their
useful engineering properties, are seldom linked to the stability
of those phases which underlies their reliability as engineered
products. Similarly, ceramic fabrication processes are seldom dis
cussed within the context of the equilibrium or metastable phase
diagram. In this text, phase diagrams are presented with a
discussion of ceramics' properties and processing. Particular
emphasis is placed on the nature of the oxides themselves-their
structural and dielectric properties-which results in unique and
stable product performance. Any set of systematic property
measurements can be the basis for a phase diagram: every experiment
is an experiment in the approach to phase equilibrium."
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