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Critical Stability Constants - Second Supplement (Paperback, Softcover reprint of the original 1st ed. 1989)
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Critical Stability Constants - Second Supplement (Paperback, Softcover reprint of the original 1st ed. 1989)
Series: Critical Stability Constants, 6
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Over the past twenty five years the Commission on Equilibrium Data
of the Analytical Division of the International Union of Pure and
Applied Chemistry has been sponsoring a noncritical compilation of
metal complex formation constants and related equilibrium
constants. This work was extensive in scope and resulted in
publication of two large volumes of Stability Constants by the
Chemical Society (London). The first volume, edited by L. G. Sillen
(for inorganic ligands) and by A. E. Martell (for organic ligands),
was published in 1964 and covered the literature through 1962. The
second volume, subtitled Supplement No. 1, edited by L. G. Sillen
and E. Hogfeldt (for inorganic ligands), and A. E. Martell and R.
M. Smith (for organic ligands), was published in 1971 and covered
the literature up to 1969. These two large compilations attempted
to cover all papers in the field related to metal complex
equilibria (heats, entropies, and free energies). Most recently a
noncritical compilation of organic ligands by D. D. Perrin
(Pergamon Press) extended coverage of the literature through 1973
and a similar volume for inorganic ligands by E. Hogfeldt covered
through 1974. Since it was the policy of the Commission during that
period to avoid decisions concerning the quality and reliability of
the published work, th~ compilation would frequently contain from
ten to twenty values for a single equilibrium constant.
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