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Fundamental Aspects of Corrosion Films in Corrosion Science (Hardcover, 1991 ed.)
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Fundamental Aspects of Corrosion Films in Corrosion Science (Hardcover, 1991 ed.)
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The purpose of this book is to stimulate thinking among corrosion
scientists and engineers to examine corrosion mechanisms and corro
sion control from another perspective. While the presence of corro
sion films in electrochemical corrosion has been recognized for
over a century, the contribution of these films to all facets of
corrosion has not been explored to a significant degree. Rather the
role of films in certain mechanisms (i.e., stress corrosion
cracking) has been empha sized, yet almost ignored for other
corrosion mechanisms. This is viewed by the author as solely
attributable to the lack of investigation into, and an
understanding of, the contribution of films to these mech anisms or
forms of attack. The lack of emphasis and study of corrosion films
and their contribution to all forms of corrosion attack are
probably the result of current university instruction that utilizes
two popular corrosion texts (Uhlig and Fontana and Greene) for
teaching. These texts provide an excellent understanding at the
undergraduate level of corrosion funda mentals; however, the major
implicit premise in these texts is that bulk properties of an alloy
or metal control the corrosion resistance in a particular
environment. For many applications and for a simple under standing
of corrosion mechanics, this approach is sufficient. Yet, research
on corrosion films indicate these films often have an entirely
different composition than the bulk metal (ratio of alloying
elements)."
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