Heterogeneous catalysis has been essential to the development of
efficient chemical processes for more than a century, and this
field has been traditionally part of the solid state chemistry and
surface science communities. The design of better catalysts has
raised the following questions: "what is the structure of the
active sites?" and "how to control their nature?" The necessary
need to develop more sustainable chemical processes and the success
of homogeneous catalysis relying on molecular organometallic
chemistry has led the community of molecular chemists to
investigate the preparation of single-site heterogeneous catalysts.
The authors discuss the molecular design, the preparation, the
characterisation and the catalytic applications of well-defined
oxides and metal particles. The readers will acquire a molecular
understanding of heterogeneous catalysis, which will help them
develop a critical view and which will attract them to study this
fascinating field.
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