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Conformation of Macromolecules - Thermodynamic & Kinetic Demonstrations (Hardcover, Illustrated Ed)
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Conformation of Macromolecules - Thermodynamic & Kinetic Demonstrations (Hardcover, Illustrated Ed)
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Conformation is statistical property of the macromolecules
consisting of a number of N structural units, links, position of
which in a space one relatively to other is not inflexibly fixed by
chemical bonds and assumes the possible random configurations. The
number of possible configurations at N >> 1 is so great that
permits to use the statistical methods at their analysis. That is
why the conformation is a result of statistical averaging on all
possible configurations of the macromolecule. It was for a long
time notified and confirmed by computer modelling that the
conformation of polymeric chain should be described by
self-avoiding random walks statistics (SARW) but not Gaussian
random walks statistics, assuming the phantom behaviour of
polymeric chains. Nevertheless, Gaussian statistics is dominating
at the analysis of thermodynamic, dynamic and kinetic stainings of
the macromolecules conformation. This book will be useful for
scientists who are engaged in the physical chemistry of polymers
and their solutions.
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