Forty years after Ziegler's discovery of the "Aufbaureaktion" and
low-pressure ethene polymerization, transition metal catalyzed
olefin and diolefin polymerization continues to represent one of
the most active and exciting areas. Since the 1980s, outstanding
scientific innovations and process improvements have revolutionized
polyolefin technology and greatly simplified polymerization
processes. Well-defined catalyst systems are now at hand and
facilitate the understanding of basic reaction mechanisms and
correlations between catalyst structures, polymer microstructures,
and polymer properties. This book reviews some of the modern
approaches in organometallic chemistry, Ziegler-Natta catalysis,
polymerization processes, design of novel materials, and the
modelling in catalyst and process development.
General
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