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Modern Aspects of Electrochemistry - No. 12 (Paperback, Softcover reprint of the original 1st ed. 1977)
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Modern Aspects of Electrochemistry - No. 12 (Paperback, Softcover reprint of the original 1st ed. 1977)
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The first chapter in the present volume takes up a well-known theme
in modern context: the ideas concerning non-Stokesian mechanisms of
ion transport. We are happy that one of the great pioneers of
modern electrochemistry, T. Erdey-Gniz, in collaboration with S.
Lengyel, has consented to write this article for us. Along with it
is a solution-oriented article in spectroscopic vein, namely, that
by A. Covington and K. E. Newman on the analysis of solution
constituents by means of nuclear magnetic resonance studies.
Progress in the electrochemistry of the double layer has perked up,
and the advances have been triggered from critical experiments, one
showing that fluoride ions are specifically adsorbed, and the other
showing that the position of maximum disorder of the water
molecules occurs at a charge opposite to that needed for interpreta
tions of capacitance humps in terms of water molecules. M. A.
Habib, who has contributed to the theory in this area, reviews the
con sequences of these changes in information. The rise in the
price of energy toward a situation in which sources other than the
fossil fuels become economical implies much for the fuel cell and
electrocatalysis. It has long been known that electrocatalysis in
real situations was more than a consideration of exchange current
densities, and a gap remains in the formulation of the theory of
supports for such catalysts, although Boudart has stressed so much
the vital nature of them. P. Stonehart and K. A. Kinoshita describe
progress in this area.
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