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The Power of Click Chemistry for Molecular Machines and Surface Patterning (Hardcover, Edition.)
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The Power of Click Chemistry for Molecular Machines and Surface Patterning (Hardcover, Edition.)
Series: Springer Theses
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The union of covalent and noncovalent chemistries manifested in the
mechanical bond represents one of the great chemical triumphs of
the last half century. However, until recently, the preparation of
mechanically interlocked compounds has often been an inefficient
and limiting process. This thesis provides a detailed account of
the great strides taken to increase the synthetic accessibility of
donor-acceptor mechanically interlocked molecules by the
application of highly efficient and ultra mild chemical
transformations during their template-directed synthesis. These new
departures in synthesis have indeed played a transformative role in
that more complex, higher-order, and functional architectures -
once only a dream - are now comfortably within reach. Specifically,
the formation of mechanical bonds in higher order rotaxanes and
catenanes has become ever easier through the use of highly
efficient click chemistries. The resulting mechanically interlocked
compounds are functional molecular media for a host of applications
including information storage, mechanical actuation, and drug
release.
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