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Lower Rim Functionalised calix[4]arenes (Paperback)
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Lower Rim Functionalised calix[4]arenes (Paperback)
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Total price: R2,083
Discovery Miles: 20 830
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The need of monitoring and controlling the concentration of heavy
metal ions such as Pb(II) or Cd(II), which have toxic effects on
all living organisms inspires chemists to synthesise more and more
selective compounds able to recognize and to bind such metals. This
book presents a review as well as the own researches on synthesis
and binding abilities of calix 4]arene-derivatives, such as amides,
hydroxamates and their thiocarbonyl analogues. The theoretical
bases of the methods used to study ligand-cation interactions, such
as 1H NMR spectroscopy, X-ray diffraction, liquid-liquid
extraction, UV absorption spectrophotometry, potentiometry and
microcalorimetry are described and followed by the own results and
discussion. The last part of this book is ascribed to studies of
ionophoric properties of calix 4]arene-thioamides and calix
4]arene-hydroxamates in ion-selective membrane electrodes. The
results are followed by a short theoretical introduction to
ion-selective electrodes. The description of the most important
analytical methods used in supramolecular chemistry together with
the data interpretation, may serve as a guide for those working in
this field of chemistry.
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