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The Plasma Chemistry of Polymer Surfaces - Advanced Techniques for Surface Design (Hardcover)
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The Plasma Chemistry of Polymer Surfaces - Advanced Techniques for Surface Design (Hardcover)
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More than 99% of all visible matter in the universe occurs as
highly ionized gas plasma with high energy content. Electrical low-
and atmospheric-pressure plasmas are characterized by continuous
source of moderate quantities of energy or enthalpy transferred
predominantly as kinetic energy of electrons. Therefore, such
energetically unbalanced plasmas have low gas temperature but
produce sufficient energy for inelastic collisions with atoms and
molecules in the gas phase, thus producing reactive species and
photons, which are able to initiate all types of polymerizations or
activate any surface of low reactive polymers. However, the broadly
distributed energies in the plasma exceed partially the binding
energies in polymers, thus initiating very often unselective
reactions and polymer degradation. The intention of this book is to
present new plasma processes and new plasma reactions of high
selectivity and high yield. This book aims to bridge classical and
plasma chemistry, particularly focusing on polymer chemistry in the
bulk and on the surface under plasma exposure. The stability of
surface functionalization and the qualitative and quantitative
measurement of functional groups at polymer surface are featured
prominently, and chemical pathways for suppressing the undesirable
side effects of plasma exposure are proposed and illustrated with
numerous examples. Special attention is paid to the smooth
transition from inanimate polymer surfaces to modified bioactive
polymer surfaces. A wide range of techniques, plasma types and
applications are demonstrated.
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