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Assigning Structures to Ions in Mass Spectrometry (Paperback)
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Assigning Structures to Ions in Mass Spectrometry (Paperback)
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Summarizing our present knowledge of the structures and chemistry
of small organic cations in the gas phase, Assigning Structures to
Ions in Mass Spectrometry presents the methods necessary for
determining gas-phase ion structures. It is a comprehensive
resource of background material that is essential for the
interpretation and understanding of organic mass spectra. Following
a historical introduction of chief discoveries, the book surveys
current experimental methods for ion production and separation as
well as those designed to reveal qualitative and quantitative
aspects of gas-phase ions. It also examines the computational
chemistry and theoretical calculations that provide complementary
thermochemical, structural, and mechanistic information. Five
selected case studies illustrate specific challenges associated
with ion structure assignment and thermochemical problems. The last
major section of the book contains the data for describing or
identifying all ions containing C alone and C with H, O, N, S, P,
halogens, and small organic cations. Presenting material written by
leading researchers in the field, Assigning Structures to Ions in
Mass Spectrometry underscores the importance of understanding the
behavior of small organic ions and gas-phase ion chemistry for
making new ion structure assignments
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