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Modern Aspects of Electrochemistry - No. 13 (Paperback, Softcover reprint of the original 1st ed. 1979)
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Modern Aspects of Electrochemistry - No. 13 (Paperback, Softcover reprint of the original 1st ed. 1979)
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The present volume contains five chapters covering areas of
contemporary interest in the fields of electrolyte solutions, the
state of solvent molecules at electrode surfaces, charged colloid
interfaces, surface chemistry of oxide electrodes and electro
chemistry, and bioelectrochemistry of charge transfer complexes.
The first chapter, by Barthel, Wachter, and Gores, covers the topic
of conductance of nonaqueous pro tic and aprotic electro lyte
solutions. This field is not only of intrinsic interest in itself,
illustrating the important departures of ion-transport behavior in
organic solvents from that, more well known, in water, but the
information and extensive new data presented in this chapter will
be of interest to those working with nonaqueous alkali-metal
batteries where the conductivity and ion-association behavior of
electrolytes in various solvents other than water is of great
importance. The second chapter is devoted to a very fundamental and
ubiquitous aspect of electrochemistry of electrodes: the state of
solvent molecules, adsorbed and oriented, at their surfaces. The
role of solvent adsorption and orientation in double-layer proper
ties, it will be recalled, remained poorly understood until the
early 1960s. This chapter, by Trasatti, gives a thorough account of
the present state of knowledge of solvent orientation at electrode
interfaces and of the unsuspected (until recent years) role it
plays in properties of the double layer and in determining the
potential profile at charged metal surfaces in solution."
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