Water, with its simple molecular structure, reveals a complex
nature upon interaction with other molecules and surfaces. Water at
Interfaces: A Molecular Approach provides a broad,
multidisciplinary introduction to water at interfaces, focusing on
its molecular characteristics. The book considers interfaces at
different length scales from single water molecules to involvement
of large numbers of water molecules, and from one-dimensional to
three-dimensional interfaces. It begins with individual water
molecules, describing their basic properties and the fundamental
concepts that form the basis of this book.
The text explores the main interfaces involving pure and ion-free
condensed (liquid and solid) water, including water vapor/liquid
water, liquid/oil, and liquid/solid interfaces. It examines water
molecules on ideal surfaces well-ordered (crystalline) and
defect-free covering topics such as electronic structure using
frontier orbitals and substrate-induced structuring. The book
discusses the affinity of water to surfaces, hydrophobicity and
hydrophilicity, emphasizing two extreme cases of affinity. It then
addresses real solid surfaces where water/solid interfaces play a
key role in actual working conditions, examining water
purification, photocatalytic activity, corrosion and degradation,
and atmospheric agents.
The final chapter deals with the interaction of water with the
heterogeneous and complex surfaces of biomolecules, which can both
influence the structure of the surrounding water and be modulated
by the surrounding liquid. The author discusses simple to more
complex biomolecules from peptides to proteins, nucleic acids, and
membranes."
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