Dalton's theory of the atom is generally considered to be what made the atom a scientifically fruitful concept in chemistry. To be sure, by Dalton's time the atom had already had a two-millenium history as a philosophical idea, and corpuscular thought had long been viable in natural philosophy (that is, in what we would today call physics).
Atoms in Chemistry will examine episodes in the evolution of the concept of the atom, particularly in chemistry, from Dalton's day to our own. It begins with an overview of scientific atomic theories from the 17th through 20th centuries that analyzes corpuscular theories of matter proposed or entertained by natural philosophers in the 17th century. Chapters will focus on philosophical and religious conceptions of matter, 19th-century organic structural theories, the debate surrounding the truth of the atomic-molecular theory, and physical evidence accumulated in the late 19th and early 20th centuries that suggested that atoms were actually real, even if they were not exactly as Dalton envisioned them. The final chapter of this book takes the reader beyond the atom itself to some of the places associated with the history of scientific atomism. As a whole, this volume will serve as a passport to important episodes from the more than 200-year history of atoms in chemistry.

This introduction to quantum field theory (QFT) is written by a physical chemist for physical chemists, chemical physicists, and other non-physicists with knowledge of quantum theory but who want to explore ways in which they might use the power of QFT in their investigations. This book starts where many graduate courses in quantum theory that are offered to chemistry students leave off and first develops some of the necessary tools, such as Fock algebra, which is applied to solving the quantum oscillator problem. Then it is used to develop the theory of coherent states, time-dependent perturbation theory, and the treatment of bosons and fermions. With this background, the QFT of a perfect gas is derived and a connection to thermodynamics is demonstrated. Application to imperfect gases provides a new approach to modelling gas-liquid phase transitions. The book concludes with photons and their interaction with molecular ensembles, and brings us to full circle by deriving the blackbody radiation law, which started it all. The power of the QFT methodology and the breadth of its applications should fascinate the reader as it has the author.

This book describes the physical and chemical effects of radiation interaction with matter. Beginning with the physical basis for the absorption of charged particle radiations, Fundamentals of Radiation Chemistry provides a systematic account of the formation of products, including the nature and properties of intermediate species. Developed from first principles, the coverage of fundamentals and applications will appeal to an interdisciplinary audience of radiation physicists and radiation biologists. Only an undergraduate background in chemistry and physics is assumed as a prerequisite for the understanding of applications in research and industry.
Key Features
* Provides a working knowledge of radiation effects for students and non-experts
* Stresses the role of the electron both as a radiation and as a reactant species
* Contains clear diagrams of track models
* Includes a chapter on applications
* Written by an expert with more than thirty years of experience in a premiere research laboratory
* Culled from the author's painstaking research of journals and other publications over several decades

This book is aimed at advanced undergraduates, graduate students and other researchers who possess an introductory background in materials physics and/or chemistry, and an interest in the physical and chemical properties of novel materials, especially transition metal oxides. New materials often exhibit novel phenomena of great fundamental and technological importance. Contributing authors review the structural, physical and chemical properties of notable 4d- and 5d-transition metal oxides discovered over the last 10 years. These materials exhibit extraordinary physical properties that differ significantly from those of the heavily studied 3d-transition metal oxides, mainly due to the relatively strong influence of the spin- orbit interaction and orbital order in 4d- and 5d materials. The immense growth in publications addressing the physical properties of these novel materials underlines the need to document recent advances and the current state of this field. This book includes overviews of the current experimental situation concerning these materials.

Volume 37 is concerned with the use and role of modelling in chemical kinetics and seeks to show the interplay of theory or simulation with experiment in a diversity of physico-chemical areas in which kinetics measurements provide significant physical insight. Areas of application covered within the volume include electro- and interfacial chemistry, physiology, biochemistry, solid state chemistry and chemical engineering.
A leading contributor to this general area has been Professor W. John Albery, FRS, to whom the contributors and editors dedicate this book.

This text contains a collection of lectures presented at the NATO ASI on "Frontiers of Chemical Dynamics" in Kemer, Turkey. Even though these articles include and sometimes emphasize the latest developments in corresponding research fields, they all share a common denominator, namely, they are intended as lectures for students at various levels as well as scientists entering a new field. It can, therefore, be used as a supplementary textbook for graduate courses on chemical dynamics. The various aspects of dynamical problems are discussed by experimentalists, theoreticians and those who carry out "numerical experiments", although it is not always easy to distinguish between theory and experiment. Most of the topics discussed offer different approaches to the same problem which will give an overall picture.

This book summarizes the basic physics of graphite and newly discovered phenomena in this material. The book contains the knowledge needed to understand novel properties of functionalized graphite demonstrating the occurrence of remarkable phenomena in disordered graphite and graphite-based heterostructures. It also discusses applications of thin graphitic samples in future electronics. Graphite consists of a stack of nearly decoupled two-dimensional graphene planes. Because of the low dimensionality and the presence of Dirac fermions, much of graphite physics resembles that of graphene. On the other hand, the multi-layered nature of the graphite structure together with structural and/or chemical disorder are responsible for phenomena that are not observed yet in graphene, such as ferromagnetic order and superconductivity. Each chapter was written by one or more experts in the field whose contributions were relevant in the (re)discovery of (un)known phenomena in graphite. The book is intended as reference for beginners and experts in the field, introducing them to many aspects of the new physics of graphite, with a fresh overview of recently found phenomena and the theoretical frames to understand them.

This volume contains the collected works of the eminent chemist and physicist Lars Onsager, one of the most influential scientists of the 20th Century. The volume includes Onsager's previously unpublished PhD thesis, a biography by H C Longuet-Higgins and M E Fisher, an autobiographical commentary, selected photographs, and a list of Onsager discussion remarks in print. Onsager's scientific achievements were characterized by deep insights into the natural sciences. His two best-known accomplishments are his reciprocal relations for irreversible processes, for which he received the 1968 Nobel Prize in Chemistry, and his explicit solution of the two-dimensional Ising model, a mathematical tour de force that created a sensation when it appeared. In addition, he made significant theoretical contributions to other fields, including electrolytes, colloids, superconductivity, turbulence, ice, electrons in metals, and dielectrics. In this volume, Onsager's contributions are divided into the following fields: irreversible processes; the Ising model; electrolytes; colloids; helium II and vortex quantization; off-diagonal long-range order and flux quantization; electrons in metal; turbulence; ion recombination; fluctuation theory; dielectrics; ice and water; biology; Mathieu functions. The different fields are evaluated by leading experts. The commentators are P W Anderson, R Askey, A Chorin, C Domb, R J Donnelly, W Ebeling, J-C Justice, H N W Lekkerkerker, P Mazur, H P McKean, J F Nagle, T Odijk, A B Pippard, G Stell, G H Weiss, and C N Yang.

Advances in Quantum Chemistry publishes articles and invited reviews by leading international researchers in quantum chemistry. Quantum chemistry deals particularly with the electronic structure of atoms, molecules, and crystalline matter and describes it in terms of electron wave patterns. It uses physical and chemical insight, sophisticated mathematics and high-speed computers to solve the wave equations and achieve its results. Advances highlights these important, interdisciplinary developments.

Polarization Spectroscopy of Ionized Gases describes the physical principles of the technique and its applications to remote sensing. Transport phenomena and local anisotropies can be studied. The theoretical part of the book considers the basic phenomena of the ordering of the velocities of fast exciting charged particles. The polarization of the outer electron shells of excited atoms or molecules is described, and a variety of effects are examined in detail. An integral equation is derived which gives the intensity and polarization of emitted lines. Methods for solving the equation are analyzed. Universal spectropolarimetric remote sensing has been applied to low pressure gas discharges in the laboratory and to non-thermal processes in the solar atmosphere. For researchers interested in the remote sensing of ionized gases.

Key features: Supported by the latest research and based on the state-of-the-art computational methods in high-accuracy computational spectroscopy of molecules Authored by an authority in the field Accessible to both experts and non-experts working in the area of computational and experimental spectroscopy, in addition to graduate students

The book introduces the fundamental aspects of digital imaging and covers four main themes: Ultrasound techniques and imaging applications, Magnetic resonance and MPJ in hospital, Digital imaging with X-rays, Emission tomography (PET and SPECT). Each of these topics is developed by analysing the underlying physics principles and their implementation, quality and safety aspects, clinical performance and recent advancements in the field. Some issues specific to the individual techniques are also treated, e.g. choice of radioisotopes or contrast agents, optimisation of data acquisition and storage, readout electronics, modelling and computer algorithms for imaging and measurement in ultrasounds and tomography applications.

Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued.

Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued.

This monograph stems from the lectures given during the summer course at the University of La Laguna, Canary Islands, Spain. It includes the main characterization techniques useful nowadays for ceramics, glasses, and glass-ceramics, and reviews the new microscopes for characterizing materials, and gives an overview of inorganic materials such as zeolites. The theory for XRD texture analysis and analytical methods are also covered. The book is not only up to date on these techniques but also on applications to inorganic materials, both amorphous and crystalline, such as glasses, glass-ceramics, and ceramics.

This book provides an overview of the underlying physics and technology of modern waveguide optoelectronics. By presenting these two aspects together in a coherent manner, readers will gain an appreciation of the fundamental physical limits to device performance as well as a critical understanding of the state of the art. Starting from the fundamental optical properties of matter, the book moves on to describe methods of device design, with an emphasis on low dimensional systems. The potential of III-IV semiconductors is highlighted because of their ability to incorporate lasers, waveguides, modulators and detectors. However, other technologies - principally lithium niobate and fibre devices - are studied and contrasted. The role of nonlinear optics and femtosecond pulses within the framework of waveguide optics is evaluated. Optical fibre devices show considerable promise in a range of systems applications and such devices are discussed and compared with planar devices. Finally, progress towards photonic and optoelectronic integrated circuits is addressed.

In recent years a number of non-linear Raman spectroscopic techniques have been substantially developed and are now proving to be powerful methods for the solution of many problems not only in spectroscopy but also in chemistry, physics and biology. These techniques include hyper Rayleigh and hyper Raman spectroscopy, coherent anti-Stokes Raman Spectroscopy (CARS), Raman Gain and In verse Raman Spectroscopy, Photoacoustic Raman Spectroscopy (PARS) and the Raman Induced Kerr Effect (RIKE). Hyper Raman spectro scopy although experimentally difficult is valuable for investi gating transitions which are not active in the infrared or in the linear Raman effect; and the other non-linear Raman effects can provide signal strength and resolution which are orders of magni tude higher than those obtainable with linear Raman spectroscopy. The thirty chapters in this book will form the basis of lectures presented at the NATO Advanced Study Institute in Bad Windsheim, F. R. Germany from August 23 - September 3, 1982."

The first volume in this series appeared in 1977, the second in 1980. From these volumes and the present one, some research trends in chemical communication can be perceived. In the 1977 volume, studies on 13 animal taxa were reported. In the present volume, the number is 25. This taxonomie diversi fication of research since the first volume of this series demon strates the wide variety of ecological adaptions, although no new general principles of chemical communication have ernerged. Further more, divergences in chemical comrnunication below the species level have become more apparent. In general, more sophisticated observa tions and techniques have led to greater awareness of the com plexities in chemical communication. As such awareness has also developed in the field of insect chemical communication, there has been a corresponding increase in the identification of the chemical compounds involved. However, in the vertebrates, no such correlation exists; in the present volume, conclusive chemical identifications of semiochemicals are remarkable by their paucity.

The polydiacetylenes are a class of polymers that are attrac ting increasing attention worldwide. There are many reasons for this interest one of the most important being the availability of many polydiacetylenes as macroscopic, high quality, single crystals. This fact was first reported in the pioneering work of Prof. G. Hegner on the solid-state polymerization of disub stituted diacetylenes in the late 1960s. Since then studies of the polymerization process and the properties of monomers and polymers have advanced understanding of solid-state reactivity and the physiCS of quasi-one-dimensional materials. More recently work on soluble polydiacetylenes, gels and films has been of interest for both academic and technological reasons. Progress in this area has required a combination of research disciplines ranging from synthetic organic chemistry to solid state physics. The interdisciplinary effort required for success ful research in polydiacetylenes was reflected in the mix of chemists, physicists and materials scientists who attended the Workshop. The emerging potential for commercial applications of polydiacetylenes was also evident in the nearly equal partici pation of academic and industrial/government scientists. The WOrkshop was the first major international meeting to focus solely on polydiacetylenes. It provided a forum in which problems of mutual interest could be discussed by scientists with diverse backgrounds and interests. It also satisfied the need for a review of the science of these materials at a time when this basic understanding is leading to technological applications."

"Physics of Cryocrystals offers the first comprehensive treatment of molecular cryosolids. The book focuses on the distinctions between molecular and atomic cryocrystals, especially on the role of molecular rotation. Also considered are how cryocrystals are used for investigating the lattice dynamics of crystals with isotropic and anisotropic interactions, phase transitions, melting, different kinds of electronic excitations in insulators, and impurity effects. Detailed tables and graphs of molecular parameters, essential thermodynamic data, and lattice-dynamic data serve to make Physics of Cryocrystals an invaluable sourcebook." "Contents" Physics of Cryocrystals offers the first comprehensive treatment of molecular cryosolids. The book focuses on the distinctions between molecular and atomic cryocrystals, especially on the role of molecular rotation. Also considered are how cryocrystals are used for investigating the lattice dynamics of crystals with isotropic and anisotropic interactions, phase transitions, melting, different kinds of electronic excitations in insulators, and impurity effects. Detailed tables and graphs of molecular parameters, essential thermodynamic data, and lattice-dynamic data serve to make Physics of Cryocrystals an invaluable sourcebook.

We have shown that simple power-law dynamics is expected for flexible fractal objects. Although the predicted behavior is well established for linear polymers, the situationm is considerably more complex for colloidal aggregates. In the latter case, the observed K-dependence of (r) can be explained either in terms of non-asymptotic hydrodynamics or in terms of weak power-law polydispersity. In the case of powders (alumina, in particular) apparent fractal behavior seen in static scattering is not found in the dynamics. ID. W. Schaefer, J. E. Martin, P. Wiitzius, and D. S. Cannell, Phys. Rev. Lett. 52,2371 (1984). 2 J. E. Martin and D. W. Schaefer, Phys. Rev. Lett. 5:1,2457 (1984). 3 D. W. Schaefer and C. C. Han in Dynamic Light Scattering, R. Pecora ed, Plenum, NY, 1985) p. 181. 4 P. Sen, this book. S J. E. Martin and B. J. Ackerson, Phys. Rev. A :11, 1180 (1985). 6 J. E. Martin, to be published. 7 D. A. Weitz, J. S. Huang, M. Y. Lin and J. Sung, Phys. Rev. Lett. 53,1657 (1984) . 8 J. E. Martin, D. W. Schaefer and A. J. Hurd, to be published; D. W. Schaefer, K. D. Keefer, J. E. Martin, and A. J. Hurd, in Physics of Finely Divided Matter, M. Daoud, Ed., Springer Verlag, NY, 1985. 9 D. W. Schaefer and A. J. Hurd, to be published. lOJ. E. Martin, J. Appl. Cryst. (to be published).

Multiphoton processes in atoms in intense laser-light fields is gaining ground as a spectroscopic diagnostic tool. This text presents descriptions of processes occurring in atoms under the action of strong electromagnetic radiation, in particular, the shift, broadening and mixing of atomic states. The topics covered include tunnelling ionization, above-threshold ionization, ionization of multiply charged ions, resonance-enhanced ionization, super-intense radiation fields, and properties of Rydberg states strongly perturbed by laser radiation.

The use of numerical grid methods to solve the Schrodinger equation has rapidly evolved in the past decade.The early attempts to demonstrate the computational viability of grid methods have been largely superseded by applications to specific problems and deeper research into more sophisticated quadrature schemes. Underpinning this research, of course, is the belief that the generic nature of grid methods can enjoy a symbiotic development with advances in computer technology, harnessing this technology in an effective manner. The contributions to this proceedings demonstrate these points in full: several appli cations displayed creative use and extension of existing grid methodology; other research concentrated on the development of new quadrature schemes or mixed numerical meth ods. The research represented ranges from highly specific spectral simulations of van der Waals complexs to general schemes for reactive scattering. The novelty of grid methods in Density Functional Theory calculations should also be highlighted since it represents an alternative to standard basis set expansion techniques and might offer distinct advantages to the standard techniques. A deliberate attempt was made to present research material with more motivational and background discussion than is typical of research publications. It is hoped that these contributed proceedings will be useful to students and researchers outside the field to have a rapid and complete introduction to many of the exciting uses of grid methodology in atomic and molecular physics. Special thanks are due to the NATO Science Committee for its generous support of the activities of this workshop."