Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued.

Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued.

Key features: Supported by the latest research and based on the state-of-the-art computational methods in high-accuracy computational spectroscopy of molecules Authored by an authority in the field Accessible to both experts and non-experts working in the area of computational and experimental spectroscopy, in addition to graduate students

The Advances in Chemical Physics series provides the chemical physics and physical chemistry fields with a forum for critical, authoritative evaluations of advances in every area of the discipline. Filled with cutting-edge research reported in a cohesive manner not found elsewhere in the literature, each volume of the Advances in Chemical Physics series serves as the perfect supplement to any advanced graduate class devoted to the study of chemical physics.

This monograph stems from the lectures given during the summer course at the University of La Laguna, Canary Islands, Spain. It includes the main characterization techniques useful nowadays for ceramics, glasses, and glass-ceramics, and reviews the new microscopes for characterizing materials, and gives an overview of inorganic materials such as zeolites. The theory for XRD texture analysis and analytical methods are also covered. The book is not only up to date on these techniques but also on applications to inorganic materials, both amorphous and crystalline, such as glasses, glass-ceramics, and ceramics.

The Matching Method for Asymptotic Solutions in Chemical Physics Problems by A. M. Il'in, L. A. Kalyakin, and S. I. Maslennikov
Singularly Perturbed Problems with Boundary and Interior Layers: Theory and Application by V. F. Butuzov and A. B. Vasilieva
Numerical Methods for Singularly Perturbed Boundary Value Problems Modeling Diffusion Processes by V. L. Kolmogorov and G. I. Shishkin
An important addition to the Advances in Chemical Physics series, this volume makes available for the first time in English the work of leading Russian researchers in singular perturbation theory and its application. Since boundary layers were first introduced by Prandtl early in this century, rapid advances have been made in the analytic and numerical investigation of these phenomena, and nowhere have these advances been more notable than in the Russian school of singular perturbation theory. The three chapters in this volume treat various aspects of singular perturbations and their numerical solution, and represent some of the best work done in this area:
* The first chapter, "The Matching Method for Asymptotic Solutions in Chemical Physics Problems," is concerned with the analysis of some singular perturbation problems that arise in chemical kinetics. In this chapter the matching method is applied to find asymptotic solutions to some dynamical systems of ordinary differential equations whose solutions have multiscale time dependence.
* The second chapter, "Singularly Perturbed Problems with Boundary and Interior Layers: Theory and Application," offers a comprehensive overview of the theory and application of asymptotic approximations for many different kinds of problems in chemical physics governed by either ordinary or partial differential equations with boundary and interior layers.
* The third chapter, "Numerical Methods for Singularly Perturbed Boundary Value Problems Modeling Diffusion Processes," discusses the numerical difficulties that arise in solving the problems described in the first two chapters, and proposes rigorous criteria for determining whether or not a numerical method is satisfactory for such problems. Methods satisfying these criteria are then constructed and applied to obtain numerical solutions to a range of sample problems.

Timely, authoritative, and invaluable to researchers in all areas of chemical physics, Singular Perturbation Problems in Chemical Physics is an essential resource.

This book provides an overview of the underlying physics and technology of modern waveguide optoelectronics. By presenting these two aspects together in a coherent manner, readers will gain an appreciation of the fundamental physical limits to device performance as well as a critical understanding of the state of the art. Starting from the fundamental optical properties of matter, the book moves on to describe methods of device design, with an emphasis on low dimensional systems. The potential of III-IV semiconductors is highlighted because of their ability to incorporate lasers, waveguides, modulators and detectors. However, other technologies - principally lithium niobate and fibre devices - are studied and contrasted. The role of nonlinear optics and femtosecond pulses within the framework of waveguide optics is evaluated. Optical fibre devices show considerable promise in a range of systems applications and such devices are discussed and compared with planar devices. Finally, progress towards photonic and optoelectronic integrated circuits is addressed.

In recent years a number of non-linear Raman spectroscopic techniques have been substantially developed and are now proving to be powerful methods for the solution of many problems not only in spectroscopy but also in chemistry, physics and biology. These techniques include hyper Rayleigh and hyper Raman spectroscopy, coherent anti-Stokes Raman Spectroscopy (CARS), Raman Gain and In verse Raman Spectroscopy, Photoacoustic Raman Spectroscopy (PARS) and the Raman Induced Kerr Effect (RIKE). Hyper Raman spectro scopy although experimentally difficult is valuable for investi gating transitions which are not active in the infrared or in the linear Raman effect; and the other non-linear Raman effects can provide signal strength and resolution which are orders of magni tude higher than those obtainable with linear Raman spectroscopy. The thirty chapters in this book will form the basis of lectures presented at the NATO Advanced Study Institute in Bad Windsheim, F. R. Germany from August 23 - September 3, 1982."

The study of surfaces has experienced dramatic growth over the past decade. Now, the editors of the internationally celebrated series Advances in Chemical Physics have brought together in this self-contained, special topic volume contributions from leading researchers in the field treating some of the most crucial aspects of the experimental and theoretical study of surfaces. This work delves into such core issues as:

• Kinetics and dynamics of hydrogen adsorption on silicon surfaces.
• Potential energy surfaces of transition- metal-catalyzed chemical reactions.
• High-resolution helium atom scattering as a proof of surface vibrations.
• Ordering and phase transitions in adsorbed monolayers of diatomic molecules.
• The influence of dimensionality on static and dynamic properties of a system.
• New applications to fields as varied as catalysts and the passage of molecules through membranes.

This valuable resource provides important insights into the current state of knowledge about surface properties. Prigogine and Rice's latest work will stimulate the imagination and motivate the exploration of other aspects of this fascinating subject.

The first volume in this series appeared in 1977, the second in 1980. From these volumes and the present one, some research trends in chemical communication can be perceived. In the 1977 volume, studies on 13 animal taxa were reported. In the present volume, the number is 25. This taxonomie diversi fication of research since the first volume of this series demon strates the wide variety of ecological adaptions, although no new general principles of chemical communication have ernerged. Further more, divergences in chemical comrnunication below the species level have become more apparent. In general, more sophisticated observa tions and techniques have led to greater awareness of the com plexities in chemical communication. As such awareness has also developed in the field of insect chemical communication, there has been a corresponding increase in the identification of the chemical compounds involved. However, in the vertebrates, no such correlation exists; in the present volume, conclusive chemical identifications of semiochemicals are remarkable by their paucity.

The polydiacetylenes are a class of polymers that are attrac ting increasing attention worldwide. There are many reasons for this interest one of the most important being the availability of many polydiacetylenes as macroscopic, high quality, single crystals. This fact was first reported in the pioneering work of Prof. G. Hegner on the solid-state polymerization of disub stituted diacetylenes in the late 1960s. Since then studies of the polymerization process and the properties of monomers and polymers have advanced understanding of solid-state reactivity and the physiCS of quasi-one-dimensional materials. More recently work on soluble polydiacetylenes, gels and films has been of interest for both academic and technological reasons. Progress in this area has required a combination of research disciplines ranging from synthetic organic chemistry to solid state physics. The interdisciplinary effort required for success ful research in polydiacetylenes was reflected in the mix of chemists, physicists and materials scientists who attended the Workshop. The emerging potential for commercial applications of polydiacetylenes was also evident in the nearly equal partici pation of academic and industrial/government scientists. The WOrkshop was the first major international meeting to focus solely on polydiacetylenes. It provided a forum in which problems of mutual interest could be discussed by scientists with diverse backgrounds and interests. It also satisfied the need for a review of the science of these materials at a time when this basic understanding is leading to technological applications."

"Physics of Cryocrystals offers the first comprehensive treatment of molecular cryosolids. The book focuses on the distinctions between molecular and atomic cryocrystals, especially on the role of molecular rotation. Also considered are how cryocrystals are used for investigating the lattice dynamics of crystals with isotropic and anisotropic interactions, phase transitions, melting, different kinds of electronic excitations in insulators, and impurity effects. Detailed tables and graphs of molecular parameters, essential thermodynamic data, and lattice-dynamic data serve to make Physics of Cryocrystals an invaluable sourcebook." "Contents" Physics of Cryocrystals offers the first comprehensive treatment of molecular cryosolids. The book focuses on the distinctions between molecular and atomic cryocrystals, especially on the role of molecular rotation. Also considered are how cryocrystals are used for investigating the lattice dynamics of crystals with isotropic and anisotropic interactions, phase transitions, melting, different kinds of electronic excitations in insulators, and impurity effects. Detailed tables and graphs of molecular parameters, essential thermodynamic data, and lattice-dynamic data serve to make Physics of Cryocrystals an invaluable sourcebook.

We have shown that simple power-law dynamics is expected for flexible fractal objects. Although the predicted behavior is well established for linear polymers, the situationm is considerably more complex for colloidal aggregates. In the latter case, the observed K-dependence of (r) can be explained either in terms of non-asymptotic hydrodynamics or in terms of weak power-law polydispersity. In the case of powders (alumina, in particular) apparent fractal behavior seen in static scattering is not found in the dynamics. ID. W. Schaefer, J. E. Martin, P. Wiitzius, and D. S. Cannell, Phys. Rev. Lett. 52,2371 (1984). 2 J. E. Martin and D. W. Schaefer, Phys. Rev. Lett. 5:1,2457 (1984). 3 D. W. Schaefer and C. C. Han in Dynamic Light Scattering, R. Pecora ed, Plenum, NY, 1985) p. 181. 4 P. Sen, this book. S J. E. Martin and B. J. Ackerson, Phys. Rev. A :11, 1180 (1985). 6 J. E. Martin, to be published. 7 D. A. Weitz, J. S. Huang, M. Y. Lin and J. Sung, Phys. Rev. Lett. 53,1657 (1984) . 8 J. E. Martin, D. W. Schaefer and A. J. Hurd, to be published; D. W. Schaefer, K. D. Keefer, J. E. Martin, and A. J. Hurd, in Physics of Finely Divided Matter, M. Daoud, Ed., Springer Verlag, NY, 1985. 9 D. W. Schaefer and A. J. Hurd, to be published. lOJ. E. Martin, J. Appl. Cryst. (to be published).

Multiphoton processes in atoms in intense laser-light fields is gaining ground as a spectroscopic diagnostic tool. This text presents descriptions of processes occurring in atoms under the action of strong electromagnetic radiation, in particular, the shift, broadening and mixing of atomic states. The topics covered include tunnelling ionization, above-threshold ionization, ionization of multiply charged ions, resonance-enhanced ionization, super-intense radiation fields, and properties of Rydberg states strongly perturbed by laser radiation.

The use of numerical grid methods to solve the Schrodinger equation has rapidly evolved in the past decade.The early attempts to demonstrate the computational viability of grid methods have been largely superseded by applications to specific problems and deeper research into more sophisticated quadrature schemes. Underpinning this research, of course, is the belief that the generic nature of grid methods can enjoy a symbiotic development with advances in computer technology, harnessing this technology in an effective manner. The contributions to this proceedings demonstrate these points in full: several appli cations displayed creative use and extension of existing grid methodology; other research concentrated on the development of new quadrature schemes or mixed numerical meth ods. The research represented ranges from highly specific spectral simulations of van der Waals complexs to general schemes for reactive scattering. The novelty of grid methods in Density Functional Theory calculations should also be highlighted since it represents an alternative to standard basis set expansion techniques and might offer distinct advantages to the standard techniques. A deliberate attempt was made to present research material with more motivational and background discussion than is typical of research publications. It is hoped that these contributed proceedings will be useful to students and researchers outside the field to have a rapid and complete introduction to many of the exciting uses of grid methodology in atomic and molecular physics. Special thanks are due to the NATO Science Committee for its generous support of the activities of this workshop."

Conjugated polymers have important technological applications, including solar cells and light emitting devices. They are also active components in many important biological processes. In recent years there have been significant advances in our understanding of these systems, owing to both improved experimental measurements and the development of advanced computational techniques. The aim of this book is to describe and explain the electronic and optical properties of conjugated polymers. It focuses on the three key roles of electron-electron interactions, electron-nuclear coupling, and disorder in determining the character of the electronic states, and it relates these properties to experimental observations in real systems. A number of important optical and electronic processes in conjugated polymers are also described. The second edition has a more extended discussion of excitons in conjugated polymers. There is also a new chapter on the static and dynamical localization of excitons.

Taking an individual approach, this book focuses on the concepts underlying chemical physics. It presents the essence of a connected theory rather than mere explanations of apparently unrelated facts, helping readers to understand chemical phenomena in terms of the most fundamental laws of physics.

This is a textbook on the theory and calculation of molecular electromagnetic and spectroscopic properties designed for a one-semester course with lectures and exercise classes. The idea of the book is to provide thorough background knowledge for the calculation of electromagnetic and spectroscopic properties of molecules with modern quantum chemical software packages.
The book covers the derivation of the molecular Hamiltonian in the presence of electromagnetic fields, and of time-independent and time-dependent perturbation theory in the form of response theory. It defines many molecular properties and spectral parameters and gives an introduction to modern computational chemistry methods.

Primarily intended for postgraduate students and researchers in the fields of condensed matter science, chemical physics and material science, who plan to use the muon spin rotation, relaxation amd resonance (mSR) techniques, this book combines for the first time a detailed discussion of the physical information contained in the measured polarization functions with real-life examples taken from the literature.
It is divided in three main parts. The first part presents some typical results of the application of mSR and explains the basic principles involved. The second part is the core of this book. It presents a comprehensive discussion of the measured polarisation functions. In the third part we analyse in four chapters selected examples taken from the following fields: diffusion properties of muon and muonium, magnetism, superconductivity, and muonium centres in materials. The book is completed by an epilogue and eight appendices.

Microfluidics deals with fluids flowing in miniaturized systems. It is a young discipline, which is expected to substantially expand over the next few years, stimulated by the considerable development of applications in the pharmaceutical, biomedical and chemical engineering domains.
The book is an introduction to this discipline. In the first chapter, it presents a short historical background and discusses the main perspectives of the domain, at economical and scientific levels. Then the physics of miniaturization and the fluid mechanics of microflows are discussed. In the following three chapters, dispersion, electrical and thermal phenomena in miniaturized devices are presented. A brief introduction to microfabrication techniques is given in chapter six and the book concludes by providing a few examples of microfludic systems.
The book is written in a simple, direct, pedagogical way. It emphasizes concepts and understanding, rather than technical detail. It offers a cross-disciplinary view of the field embracing biological, chemical, physical and engineering perspectives. By using the book, the reader will have concepts, methods and data to grasp situation, which typically arise in mircofludic systems.

A stand-alone, monograph present results on mechanochemical synthesis of nanostructured composite materials on the base of inorganic and organic components The book summarizes and systematizes the results of a fundamentally new complex approach to the creation of composite polymer-inorganic systems by mechanochemical treatment, both as a result of the traditional approach with the use of dynamic mills (mechanical reactors) and ultrasonic action on powder mixtures In addition, the book will present a chapter that will focus on the method of mechanochemical preparation of materials for high-energy systems, which are the most promising, since it allows the most productive management of the formation of new structural compositions that increase the energy intensity of the system.

Electroinduced Drift of Neutral Charge Clusters in Salt Solutions presents studies of the processes accompanying the effect of periodic electric and magnetic fields on salt solutions in polar dielectric liquids. The authors explain phenomena from a physical point of view, without theoretical constructions and mathematical calculations. This is done in order to make the book accessible to a wide audience and to help the reader navigate in a multilateral topic that is touched upon when studying processes that occur in liquid media under the external influence of an electromagnetic nature. Additional Features: Explores the phenomenon of selective drift of solvated ions in polar dielectric liquids Applies general principles of electricity and magnetism to describe experimental results Demonstrates how small perturbations of the equilibrium distribution determine not the corrections to the effects but the effects themselves Approaches nonequilibrium molecular physics as a science of physical and chemical processes This book will be useful to specialists, engineers and graduate students, especially those recording and transmitting information in liquid media.

Leading research, perspectives, and analysis of dynamical systems and irreversibility

Edited by Nobel Prize winner Ilya Prigogine and renowned authority Stuart A. Rice, the Advances in Chemical Physics series provides a forum for critical, authoritative evaluations in every area of the discipline. In a format that encourages the expression of individual points of view, experts in the field present comprehensive analyses of subjects of interest. Volume 122 collects papers from the XXI Solvay Conference on Physics, dedicated to the exploration of "Dynamical Systems and Irreversibility." Ioannis Antoniou, Deputy Director of the International Solvay Institutes for Physics and Chemistry, edits and assembles this cutting-edge research, including articles such as "Non-Markovian Effects in the Standard Map," "Harmonic Analysis of Unstable Systems," "Age and Age Fluctuations in an Unstable Quantum System," and discussion of many more subjects. Advances in Chemical Physics remains the premier venue for presentations of new findings in its field.

This series provides the chemical physics community with a forum for critical, authoritative evaluations of advances in every area of the discipline. Volume 111 continues to report recent advances with significant, up-to-date chapters by internationally-recognized researchers.

Prigogine and Rice's highly acclaimed series, Advances in Chemical Physics, provides a forum for critical, authoritative reviews of current topics in every area of chemical physics. Edited by J.K. Vij, this volume focuses on recent advances in liquid crystals with significant, up-to-date chapters authored by internationally recognized researchers in the field.