This monograph stems from the lectures given during the summer course at the University of La Laguna, Canary Islands, Spain. It includes the main characterization techniques useful nowadays for ceramics, glasses, and glass-ceramics, and reviews the new microscopes for characterizing materials, and gives an overview of inorganic materials such as zeolites. The theory for XRD texture analysis and analytical methods are also covered. The book is not only up to date on these techniques but also on applications to inorganic materials, both amorphous and crystalline, such as glasses, glass-ceramics, and ceramics.

The Advances in Chemical Physics series provides the chemical physics and physical chemistry fields with a forum for critical, authoritative evaluations of advances in every area of the discipline. Filled with cutting-edge research reported in a cohesive manner not found elsewhere in the literature, each volume of the Advances in Chemical Physics series serves as the perfect supplement to any advanced graduate class devoted to the study of chemical physics.

The Matching Method for Asymptotic Solutions in Chemical Physics Problems by A. M. Il'in, L. A. Kalyakin, and S. I. Maslennikov
Singularly Perturbed Problems with Boundary and Interior Layers: Theory and Application by V. F. Butuzov and A. B. Vasilieva
Numerical Methods for Singularly Perturbed Boundary Value Problems Modeling Diffusion Processes by V. L. Kolmogorov and G. I. Shishkin
An important addition to the Advances in Chemical Physics series, this volume makes available for the first time in English the work of leading Russian researchers in singular perturbation theory and its application. Since boundary layers were first introduced by Prandtl early in this century, rapid advances have been made in the analytic and numerical investigation of these phenomena, and nowhere have these advances been more notable than in the Russian school of singular perturbation theory. The three chapters in this volume treat various aspects of singular perturbations and their numerical solution, and represent some of the best work done in this area:
* The first chapter, "The Matching Method for Asymptotic Solutions in Chemical Physics Problems," is concerned with the analysis of some singular perturbation problems that arise in chemical kinetics. In this chapter the matching method is applied to find asymptotic solutions to some dynamical systems of ordinary differential equations whose solutions have multiscale time dependence.
* The second chapter, "Singularly Perturbed Problems with Boundary and Interior Layers: Theory and Application," offers a comprehensive overview of the theory and application of asymptotic approximations for many different kinds of problems in chemical physics governed by either ordinary or partial differential equations with boundary and interior layers.
* The third chapter, "Numerical Methods for Singularly Perturbed Boundary Value Problems Modeling Diffusion Processes," discusses the numerical difficulties that arise in solving the problems described in the first two chapters, and proposes rigorous criteria for determining whether or not a numerical method is satisfactory for such problems. Methods satisfying these criteria are then constructed and applied to obtain numerical solutions to a range of sample problems.

Timely, authoritative, and invaluable to researchers in all areas of chemical physics, Singular Perturbation Problems in Chemical Physics is an essential resource.

In recent years a number of non-linear Raman spectroscopic techniques have been substantially developed and are now proving to be powerful methods for the solution of many problems not only in spectroscopy but also in chemistry, physics and biology. These techniques include hyper Rayleigh and hyper Raman spectroscopy, coherent anti-Stokes Raman Spectroscopy (CARS), Raman Gain and In verse Raman Spectroscopy, Photoacoustic Raman Spectroscopy (PARS) and the Raman Induced Kerr Effect (RIKE). Hyper Raman spectro scopy although experimentally difficult is valuable for investi gating transitions which are not active in the infrared or in the linear Raman effect; and the other non-linear Raman effects can provide signal strength and resolution which are orders of magni tude higher than those obtainable with linear Raman spectroscopy. The thirty chapters in this book will form the basis of lectures presented at the NATO Advanced Study Institute in Bad Windsheim, F. R. Germany from August 23 - September 3, 1982."

The study of surfaces has experienced dramatic growth over the past decade. Now, the editors of the internationally celebrated series Advances in Chemical Physics have brought together in this self-contained, special topic volume contributions from leading researchers in the field treating some of the most crucial aspects of the experimental and theoretical study of surfaces. This work delves into such core issues as:

• Kinetics and dynamics of hydrogen adsorption on silicon surfaces.
• Potential energy surfaces of transition- metal-catalyzed chemical reactions.
• High-resolution helium atom scattering as a proof of surface vibrations.
• Ordering and phase transitions in adsorbed monolayers of diatomic molecules.
• The influence of dimensionality on static and dynamic properties of a system.
• New applications to fields as varied as catalysts and the passage of molecules through membranes.

This valuable resource provides important insights into the current state of knowledge about surface properties. Prigogine and Rice's latest work will stimulate the imagination and motivate the exploration of other aspects of this fascinating subject.

Key features: Supported by the latest research and based on the state-of-the-art computational methods in high-accuracy computational spectroscopy of molecules Authored by an authority in the field Accessible to both experts and non-experts working in the area of computational and experimental spectroscopy, in addition to graduate students

The first volume in this series appeared in 1977, the second in 1980. From these volumes and the present one, some research trends in chemical communication can be perceived. In the 1977 volume, studies on 13 animal taxa were reported. In the present volume, the number is 25. This taxonomie diversi fication of research since the first volume of this series demon strates the wide variety of ecological adaptions, although no new general principles of chemical communication have ernerged. Further more, divergences in chemical comrnunication below the species level have become more apparent. In general, more sophisticated observa tions and techniques have led to greater awareness of the com plexities in chemical communication. As such awareness has also developed in the field of insect chemical communication, there has been a corresponding increase in the identification of the chemical compounds involved. However, in the vertebrates, no such correlation exists; in the present volume, conclusive chemical identifications of semiochemicals are remarkable by their paucity.

We have shown that simple power-law dynamics is expected for flexible fractal objects. Although the predicted behavior is well established for linear polymers, the situationm is considerably more complex for colloidal aggregates. In the latter case, the observed K-dependence of (r) can be explained either in terms of non-asymptotic hydrodynamics or in terms of weak power-law polydispersity. In the case of powders (alumina, in particular) apparent fractal behavior seen in static scattering is not found in the dynamics. ID. W. Schaefer, J. E. Martin, P. Wiitzius, and D. S. Cannell, Phys. Rev. Lett. 52,2371 (1984). 2 J. E. Martin and D. W. Schaefer, Phys. Rev. Lett. 5:1,2457 (1984). 3 D. W. Schaefer and C. C. Han in Dynamic Light Scattering, R. Pecora ed, Plenum, NY, 1985) p. 181. 4 P. Sen, this book. S J. E. Martin and B. J. Ackerson, Phys. Rev. A :11, 1180 (1985). 6 J. E. Martin, to be published. 7 D. A. Weitz, J. S. Huang, M. Y. Lin and J. Sung, Phys. Rev. Lett. 53,1657 (1984) . 8 J. E. Martin, D. W. Schaefer and A. J. Hurd, to be published; D. W. Schaefer, K. D. Keefer, J. E. Martin, and A. J. Hurd, in Physics of Finely Divided Matter, M. Daoud, Ed., Springer Verlag, NY, 1985. 9 D. W. Schaefer and A. J. Hurd, to be published. lOJ. E. Martin, J. Appl. Cryst. (to be published).

The use of numerical grid methods to solve the Schrodinger equation has rapidly evolved in the past decade.The early attempts to demonstrate the computational viability of grid methods have been largely superseded by applications to specific problems and deeper research into more sophisticated quadrature schemes. Underpinning this research, of course, is the belief that the generic nature of grid methods can enjoy a symbiotic development with advances in computer technology, harnessing this technology in an effective manner. The contributions to this proceedings demonstrate these points in full: several appli cations displayed creative use and extension of existing grid methodology; other research concentrated on the development of new quadrature schemes or mixed numerical meth ods. The research represented ranges from highly specific spectral simulations of van der Waals complexs to general schemes for reactive scattering. The novelty of grid methods in Density Functional Theory calculations should also be highlighted since it represents an alternative to standard basis set expansion techniques and might offer distinct advantages to the standard techniques. A deliberate attempt was made to present research material with more motivational and background discussion than is typical of research publications. It is hoped that these contributed proceedings will be useful to students and researchers outside the field to have a rapid and complete introduction to many of the exciting uses of grid methodology in atomic and molecular physics. Special thanks are due to the NATO Science Committee for its generous support of the activities of this workshop."

The 'Advances in Chemical Physics' series provides the chemical physics field with a forum for critical, authoritative evaluations of advances in every area of the discipline. This special volume focuses on atoms and photos near meso- and nanobodies, an important area of nontechnology.

Conjugated polymers have important technological applications, including solar cells and light emitting devices. They are also active components in many important biological processes. In recent years there have been significant advances in our understanding of these systems, owing to both improved experimental measurements and the development of advanced computational techniques. The aim of this book is to describe and explain the electronic and optical properties of conjugated polymers. It focuses on the three key roles of electron-electron interactions, electron-nuclear coupling, and disorder in determining the character of the electronic states, and it relates these properties to experimental observations in real systems. A number of important optical and electronic processes in conjugated polymers are also described. The second edition has a more extended discussion of excitons in conjugated polymers. There is also a new chapter on the static and dynamical localization of excitons.

Taking an individual approach, this book focuses on the concepts underlying chemical physics. It presents the essence of a connected theory rather than mere explanations of apparently unrelated facts, helping readers to understand chemical phenomena in terms of the most fundamental laws of physics.

This is a textbook on the theory and calculation of molecular electromagnetic and spectroscopic properties designed for a one-semester course with lectures and exercise classes. The idea of the book is to provide thorough background knowledge for the calculation of electromagnetic and spectroscopic properties of molecules with modern quantum chemical software packages.
The book covers the derivation of the molecular Hamiltonian in the presence of electromagnetic fields, and of time-independent and time-dependent perturbation theory in the form of response theory. It defines many molecular properties and spectral parameters and gives an introduction to modern computational chemistry methods.

Bio-nanocomposites combine the enhanced properties of commercial polymer nanocomposites with the low environmental impact of biodegradable material, making them a topic of great current interest. Because of their tremendous role in reducing dependency on commercial non-biodegradable polymers, and their environmentally-friendly nature, bio-nanocomposites need to be studied in greater detail. In this book, recent advancements in their development are brought together in a single text, to provide researchers with a thorough insight into the various systems, and to open up future perspectives. Although the commercial applications of these bio-nanocomposites are in their infancy, these materials have a huge commercial potential. In setting out the next generation of advances in nanocomposite technology, this book opens the way for further developments in the field.
Describing the subject as a whole, from a basic introduction to the more specific systems and advancements, this book can be used both as a professional reference and for teaching purposes.

Microfluidics deals with fluids flowing in miniaturized systems. It is a young discipline, which is expected to substantially expand over the next few years, stimulated by the considerable development of applications in the pharmaceutical, biomedical and chemical engineering domains.
The book is an introduction to this discipline. In the first chapter, it presents a short historical background and discusses the main perspectives of the domain, at economical and scientific levels. Then the physics of miniaturization and the fluid mechanics of microflows are discussed. In the following three chapters, dispersion, electrical and thermal phenomena in miniaturized devices are presented. A brief introduction to microfabrication techniques is given in chapter six and the book concludes by providing a few examples of microfludic systems.
The book is written in a simple, direct, pedagogical way. It emphasizes concepts and understanding, rather than technical detail. It offers a cross-disciplinary view of the field embracing biological, chemical, physical and engineering perspectives. By using the book, the reader will have concepts, methods and data to grasp situation, which typically arise in mircofludic systems.

Reviews of previous volumes ..".continues the tradition of this series on high-quality authoritative chapters in a wide-range of chemical physics topics." Journal of the American Chemical Society. The newest volume in the prestigious Advances in Chemical Physics Series, edited by Nobel Prize winner, Ilya Prigogine and renowned authority Stuart A. Rice, provides general information about a wide variety of topics in chemical physics. Experts present comprehensive analyses of subjects of interest, and encourage the expression of individual points of view. This approach to presenting an overview of a subject will both stimulate new research and serve as a personalized learning text for beginners in the field.

Leading research, perspectives, and analysis of dynamical systems and irreversibility

Edited by Nobel Prize winner Ilya Prigogine and renowned authority Stuart A. Rice, the Advances in Chemical Physics series provides a forum for critical, authoritative evaluations in every area of the discipline. In a format that encourages the expression of individual points of view, experts in the field present comprehensive analyses of subjects of interest. Volume 122 collects papers from the XXI Solvay Conference on Physics, dedicated to the exploration of "Dynamical Systems and Irreversibility." Ioannis Antoniou, Deputy Director of the International Solvay Institutes for Physics and Chemistry, edits and assembles this cutting-edge research, including articles such as "Non-Markovian Effects in the Standard Map," "Harmonic Analysis of Unstable Systems," "Age and Age Fluctuations in an Unstable Quantum System," and discussion of many more subjects. Advances in Chemical Physics remains the premier venue for presentations of new findings in its field.

This comprehensive and systematic text provides the polymer scientist and technologist with a firm grounding in the principles underlying the wide applications of block copolymers. The first text of its kind for over ten years, this informative book is essential to the polymer chemistry, physics and materials science researcher in industry and academia, and postgraduates in related fields.

This book provides a comprehensive survey of modern molecular astrophysics. It includes an introduction to molecular spectroscopy and then addresses the main areas of current molecular astrophysics, including galaxy formation, star forming regions, mass loss from young as well as highly evolved stars and supernovae, starburst galaxies plus the tori and discs near the central engines of active galactic nuclei. All chapters have been written by invited authors who are acknowledged experts in their fields. The thorough editorial process has ensured a uniformly high standard of exposition and a coherent style. The book is unique in giving a detailed view of its wide-ranging subject. It will provide the standard introduction for research students in molecular astrophysics. The book will be read by research astronomers and astrophysicists who wish to broaden the basis of their knowledge or are moving their activities into this burgeoning field. It will enable chemists to learn the astrophysics most related to chemistry as well as instruct physicists about the molecular processes most important in astronomy.

This series provides the chemical physics community with a forum for critical, authoritative evaluations of advances in every area of the discipline. Volume 111 continues to report recent advances with significant, up-to-date chapters by internationally-recognized researchers.

A stand-alone, monograph present results on mechanochemical synthesis of nanostructured composite materials on the base of inorganic and organic components The book summarizes and systematizes the results of a fundamentally new complex approach to the creation of composite polymer-inorganic systems by mechanochemical treatment, both as a result of the traditional approach with the use of dynamic mills (mechanical reactors) and ultrasonic action on powder mixtures In addition, the book will present a chapter that will focus on the method of mechanochemical preparation of materials for high-energy systems, which are the most promising, since it allows the most productive management of the formation of new structural compositions that increase the energy intensity of the system.

Prigogine and Rice's highly acclaimed series, Advances in Chemical Physics, provides a forum for critical, authoritative reviews of current topics in every area of chemical physics. Edited by J.K. Vij, this volume focuses on recent advances in liquid crystals with significant, up-to-date chapters authored by internationally recognized researchers in the field.

Electroinduced Drift of Neutral Charge Clusters in Salt Solutions presents studies of the processes accompanying the effect of periodic electric and magnetic fields on salt solutions in polar dielectric liquids. The authors explain phenomena from a physical point of view, without theoretical constructions and mathematical calculations. This is done in order to make the book accessible to a wide audience and to help the reader navigate in a multilateral topic that is touched upon when studying processes that occur in liquid media under the external influence of an electromagnetic nature. Additional Features: Explores the phenomenon of selective drift of solvated ions in polar dielectric liquids Applies general principles of electricity and magnetism to describe experimental results Demonstrates how small perturbations of the equilibrium distribution determine not the corrections to the effects but the effects themselves Approaches nonequilibrium molecular physics as a science of physical and chemical processes This book will be useful to specialists, engineers and graduate students, especially those recording and transmitting information in liquid media.

Recent advances in both experimental techniques and theoretical methodologies have meant that increasingly sophisticated studies concerning the formation, structures, energetics, and reaction dynamics of state- or energy-selected molecular ions can now be performed. In order to better serve the ion chemistry and physics community, each volume of this series will be dedicated to reviewing a specific topic, emphasizing new experimental and theoretical developments in the study of ions. The Wiley Series in Ion Chemistry and Physics will help stimulate new research directions and point to future opportunities in the field of ion chemistry and physics. This fourth volume is devoted to developments associated with the high resolution study of molecular photoionization, presented from both experimental and theoretical viewpoints. This field has been revolutionized in recent years through the rapid development of zero kinetic energy (ZEKE) photoelectron spectroscopy, which is featured prominently within this volume. These advances have expanded the researcher' s ability to probe not just structural features, but also the detailed dynamics of a system, resulting in the interest and applicability of the technique being broadened to areas of chemical physics extending beyond the traditional study of photoionization per se. Each of the twelve chapters making up this volume is written by leading researchers in their respective fields.

Low Energy Ion - Surface Interactions Edited by J. Wayne Rabalais, University of Houston, Texas, USA Recent advances in experimental techniques and theoretical methodologies mean that increasingly detailed and sophisticated studies of state - or energy - selected molecular ions can now be performed. Each volume in this series will be dedicated to reviewing a specific topic, emphasizing new experimental and theoretical developments in the study of ions. This volume details the current understanding of Low Energy Ion - Surface Interactions, along with some of the novel applications. Each of the ten chapters is authored by active researchers in the field who are at the forefront of research in their particular areas. This up-to-date compilation, detailing developments occurring within the last five years, will be particularly useful to researchers and teachers involved with Low Energy Ion - Surface Interactions.