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Insights into the Chemistry of Organic Structure-Directing Agents in the Synthesis of Zeolitic Materials (Paperback, Softcover reprint of the original 1st ed. 2018)
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Insights into the Chemistry of Organic Structure-Directing Agents in the Synthesis of Zeolitic Materials (Paperback, Softcover reprint of the original 1st ed. 2018)
Series: Structure and Bonding, 175
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This edited volume focuses on the host-guest chemistry of organic
molecules and inorganic systems during synthesis
(structure-direction). Organic molecules have been used for many
years in the synthesis of zeolitic nanoporous frameworks. The
addition of these organic molecules to the zeolite synthesis
mixtures provokes a particular ordering of the inorganic units
around them that directs the crystallization pathway towards a
particular framework type; hence they are called
structure-directing agents. Their use has allowed the discovery of
an extremely large number of new zeolite frameworks and
compositions. This volume covers the main aspects of the use of
organic molecules as structure-directing agents for the synthesis
of zeolites, including first an introduction of the main concepts,
then two chapters covering state-of-the-art techniques currently
used to understand the structure-directing phenomenon (location of
molecules by XRD and molecular modeling techniques). The most
recent trends in the types of organic molecules used as
structure-directing agents are also presented, including the use of
metal-complexes, the use of non-ammonium-based molecules (mainly
phosphorus-based compounds) and the role of supramolecular
chemistry in designing new large organic structure-directing agents
produced by self-aggregation. In addition the volume explores the
latest research attempting to transfer the asymmetric nature of
organic chiral molecules used as structure-directing agents to the
zeolite lattice to produce chiral enantioselective frameworks, one
of the biggest challenges today in materials chemistry. This volume
has interdisciplinary appeal and will engage scholars from the
zeolite community with a general interest in microporous materials,
which involves not only zeolite scientists, but also researchers
working on metal-organic framework materials. The concepts covered
will also be of interest for researchers working on the application
of materials after encapsulation of molecules of interest in
post-synthetic treatments. Further the work explores the main
aspects of host-guest chemistry in hybrid organo-inorganic
templated materials, which covers all types of materials where
organic molecules are used as templates and are confined within
framework-structured inorganic materials (intercalation compounds).
Therefore the volume is also relevant to the wider materials
chemistry community.
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