Since the first application of dendrimers in catalysis in the
mid 1990s, this field has advanced rapidly. As a consequence,
catalytically active dendrimers have emerged as a class of
molecular catalysts that has substantially enriched the field of
homogeneous (and in part heterogeneous) catalysis. A general survey
of transition metal dendrimer catalysts and the way they have
developed is followed by in-depth discussions of dendritic
transition metal catalysis based on non-covalent catalyst-support
interaction and an overview of the rapidly growing field of
stereoselective dendrimer catalysis. The development of
dendrimer-encapsulated bimetallic nanoparticles has provided the
interface with heterogeneous colloid catalysis. As cheaper and
readily accessible alternatives to regular dendrimers,
hyperbranched polymers are increasingly being used as catalyst
platforms. These topics are complemented by a review of
metallodendritic exoreptors for the redox recognition of oxo-anions
and halides.
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