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Design, Synthesis and Characterization of new Supramolecular Architectures (Paperback, 2011 ed.)
Loot Price: R2,733
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Design, Synthesis and Characterization of new Supramolecular Architectures (Paperback, 2011 ed.)
Series: Springer Theses
Expected to ship within 10 - 15 working days
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This thesis focuses on the bottom-up design, construction and
operation of supramolecular systems capable of behaving as devices
and machines on the molecular scale, which is a topic of great
interest in nanoscience and a fascinating challenge in
nanotechnology. In particular, the systems investigated here
include: polyviologen dendrimers capable of behaving as hosts and
chargestoring devices; molecular machines based on
pseudorotaxanes/rotaxanes and operated by photoinduced proton
transfer, or photoisomerization reactions; and a simple
unimolecular multiplexer/demultiplexer. The systems have been
characterized using a variety of techniques including absorption
and emission spectra, laser flash photolysis, NMR spectroscopy,
electrochemical experiments, stopped flow measurements. This
research addresses a large number of open problems in the
nanosciences, dealing with a wide range of the most advanced
applications of supramolecular systems.
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