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Intermolecular Forces and Their Evaluation by Perturbation Theory (Paperback, Softcover reprint of the original 1st ed. 1981)
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Intermolecular Forces and Their Evaluation by Perturbation Theory (Paperback, Softcover reprint of the original 1st ed. 1981)
Series: Lecture Notes in Chemistry, 25
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The aim of these notes is to offer a modern picture of the pertur
bative approach to the calculation of intermolecular forces. The
point of view taken is that a perturbative series truncated at a
low order can provide a valuable way for valuating interaction
energies, especial ly if one limits oneself to the case of
intermediate- and long-range distances between the interacting
partners. Although the situation corresponding to short distances
is essen tially left out from our presentation, the problems which
are within the range of the theory form a vast and important class:
a large var iety of phenomena of matter, in fact, depends on the
existence of in teractions among atoms or molecules, which over a
substantial range of distances should be classified as weak in
comparison to the interactions occurring inside atoms or molecules.
We are aware of the omission of some topics, which in principle
could have been included in our review. For instance, a very scarce
at tention has been paid to the analysis of problems involving
interacting partners in degenerate states, which is of particular
relevance in the case of interactions between excited atoms (only a
rather quick presen tation of the formal apparatus of degenerate
perturbation theory is in cluded in Chap. III). Interactions
involving the simultaneous presence of more than two atoms (or
mOlecules) have not been considered, with the consequent
non-necessity of considering nonadditive effects which characterize
the general N-body problem."
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