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The Poisson-Boltzmann Equation - An Introduction (Paperback, 1st ed. 2023)
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The Poisson-Boltzmann Equation - An Introduction (Paperback, 1st ed. 2023)
Series: SpringerBriefs in Physics
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This brief book introduces the Poisson-Boltzmann equation in three
chapters that build upon one another, offering a systematic entry
to advanced students and researchers. Chapter one formulates the
equation and develops the linearized version of Debye-Hückel
theory as well as exact solutions to the nonlinear equation in
simple geometries and generalizations to higher-order
equations.   Chapter two introduces the
statistical physics approach to the Poisson-Boltzmann equation. It
allows the treatment of fluctuation effects, treated in the loop
expansion, and in a variational approach. First applications are
treated in detail: the problem of the surface tension under the
addition of salt, a classic problem discussed by Onsager and
Samaras in the 1930s, which is developed in modern terms within the
loop expansion, and the adsorption of a charged polymer on a
like-charged surface within the variational approach.Â
Chapter three finally discusses the extension of Poisson-Boltzmann
theory to explicit solvent. This is done in two ways: on the
phenomenological level of nonlocal electrostatics and with a
statistical physics model that treats the solvent molecules as
molecular dipoles. This model is then treated in the mean-field
approximation and with the variational method introduced in Chapter
two, rounding up the development of the mathematical approaches of
Poisson-Boltzmann theory. After studying this book, a
graduate student will be able to access the research literature on
the Poisson-Boltzmann equation with a solid background.Â
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