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Energy-Level Control at Hybrid Inorganic/Organic Semiconductor Interfaces (Paperback, Softcover reprint of the original 1st ed. 2017)
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Energy-Level Control at Hybrid Inorganic/Organic Semiconductor Interfaces (Paperback, Softcover reprint of the original 1st ed. 2017)
Series: Springer Theses
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This work investigates the energy-level alignment of hybrid
inorganic/organic systems (HIOS) comprising ZnO as the major
inorganic semiconductor. In addition to offering essential
insights, the thesis demonstrates HIOS energy-level alignment
tuning within an unprecedented energy range. (Sub)monolayers of
organic molecular donors and acceptors are introduced as an
interlayer to modify HIOS interface-energy levels. By studying
numerous HIOS with varying properties, the author derives generally
valid systematic insights into the fundamental processes at work.
In addition to molecular pinning levels, he identifies
adsorption-induced band bending and gap-state density of states as
playing a crucial role in the interlayer-modified energy-level
alignment, thus laying the foundation for rationally controlling
HIOS interface electronic properties. The thesis also presents
quantitative descriptions of many aspects of the processes, opening
the door for innovative HIOS interfaces and for future applications
of ZnO in electronic devices.
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