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Th Thorium - Supplement Volume C 3 Compounds with Nitrogen (Paperback, 8th ed. 1987. Softcover reprint of the original 8th ed. 1987)
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Th Thorium - Supplement Volume C 3 Compounds with Nitrogen (Paperback, 8th ed. 1987. Softcover reprint of the original 8th ed. 1987)
Series: Gmelin Handbook of Inorganic and Organometallic Chemistry - 8th edition, T-h / A-E / C / 3
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This volume C 3, as a part of the Gmelin "Thorium" Handbook, Series
C, describes the thorium-nitrogen compounds. Included are compounds
both of technological importance like the nitrides and the nitrates
and those of merely scientific interest, such as amides and related
compounds. However, due to the decreasing technical importance of
the nuclear thorium fuel cycle, especially with the advanced fuels
like the nitride ThN, in recent years, the thorium compounds with
nitrogen have been investigated much less extensively than the
correspond ing uranium compounds. In order to have the data for the
Th-N-X systems accumulated in one specific volume, the decision was
made to publish this volume without incorporating other Th systems.
ThN is the compound with the lowest N :Th ratio. In addition to its
(former) nuclear interest due to its thermal and radiation
stability, it has many very interesting physicochemical properties.
Thorium nitrate, the other well-investigated compound, is of
importance because it is (in the form of an adduct with
tri-n-butylphosphate) the extracted compound when burnt-up thorium
fuels are reprocessed. Despite the wealth of accumulated data on
the chemical and physicochemical properties of the compounds
discussed, the knowledge of the compounds and of the systems is far
from satisfactory - it must be deepened and improved in further
studies. I would like to thank the competent authors for their
critical contributions as well as the Gmelin-Institute for the
excellent cooperation provided, especially Prof. Dr. Fluck and Dr.
Keim, the editor-in-chief of this volume.
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