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Vibrationally Mediated Photodissociation (Hardcover)
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Vibrationally Mediated Photodissociation (Hardcover)
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Vibrationally Mediated Photodissociation (VMP) deals with the
influence of vibrational excitation of the ground electronic state
of a molecule on its dissociation following excitation of this
state to a higher electronic state. Aimed at students and
academics, this is the first book devoted to the effect of
vibrational pre-excitation on molecular dynamics in the gas phase.
In particular, it deals with the influence of this excitation on
the dissociation of molecules (ie: on the branching ratio between
the dissociation products and its dependence on the vibrational
state being excited). The effect in the gas phase has been
extensively studied, both theoretically and experimentally and
encompasses diverse areas of chemical physics. This monograph
presents the methodology of VMP, using state-of-the-art specific
examples. Overviews of earlier works are included as well, to serve
as a background for current research. Wherever appropriate,
original works are quoted, including the original drawings. The
contents include a brief review of theoretical and experimental
methods relevant to VMP and specific examples. Also included are a
bibliography, author and subject index. From the description of the
motivation, the approach, the execution of the experiment and the
analysis of the results of the specific examples, the reader will
get a comprehensive understanding of the field. The book is aimed
at senior undergraduate and graduate students of chemistry and
physics. It serves as an introduction to VMP for beginners and as a
literature guide to those acquainted with the subject but not
necessarily working on VMP.
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