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Molecular Electronic Control Over Tunneling Charge Transfer Plasmons Modes (Hardcover, 1st ed. 2018)
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Molecular Electronic Control Over Tunneling Charge Transfer Plasmons Modes (Hardcover, 1st ed. 2018)
Series: Springer Theses
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This thesis describes the controlled immobilization of molecules
between two cuboidal metal nanoparticles by means of a
self-assembly method to control the quantum plasmon resonances. It
demonstrates that quantum-plasmonics is possible at length scales
that are useful for real applications. Light can interact with
certain metals and can be captured in the form of plasmons, which
are collective, ultra-fast oscillations of electrons that can be
manipulated at the nano-scale. Surface plasmons are considered as a
promising phenomenon for potentially bridging the gap between
fast-operating-speed optics and nano-scale electronics. Quantum
tunneling has been predicted to occur across two closely separated
plasmonic resonators at length scales (<0.3 nm) that are not
accessible using present-day nanofabrication techniques. Unlike
top-down nanofabrication, the molecules between the closely-spaced
metal nanoparticles could control the gap sizes down to
sub-nanometer scales and act as the frequency controllers in the
terahertz regime, providing a new control parameter in the
fabrication of electrical circuits facilitated by quantum plasmon
tunneling.
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