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Oxide-Ion Conduction in the Dion-Jacobson-Type Layered Perovskites (Hardcover, 1st ed. 2022)
Loot Price: R4,677
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Oxide-Ion Conduction in the Dion-Jacobson-Type Layered Perovskites (Hardcover, 1st ed. 2022)
Series: Springer Theses
Expected to ship within 18 - 22 working days
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This book reports a study of a class of Dion-Jacobson-type layered
perovskite oxides in which high oxide-ion conductivities in phases
were discovered for the first time in the world. The oxide-ion
conductors are important in various energy conversion devices and
environmental protection applications such as solid-oxide fuel
cells, oxygen gas sensors, oxygen separation membranes, and
oxygen-based catalysts. The discoveries are based on a new
screening method, called the bond valence method, combined with an
original design concept. The present finding of high oxide-ion
conductivity reported in the thesis suggested the potential of
Dion-Jacobson phases as a platform to identify superior oxide-ion
conductors. To understand what causes such high oxide-ion
conductivities in these layered perovskite oxides, the author
analyzed their crystal structures at high temperature and described
the relationship between oxide-ion conductivities and their crystal
structures. A deep understanding of the mechanisms of oxide-ion
diffusivity at an atomic level in the Dion-Jacobson phases is
clarified. The discovery of these materials, the new screening
method, and the original design concept make possible the
realization of many environment-friendly technologies. The findings
in this thesis facilitate the possibilities for many novel
applications that will help lead to a sustainable future.
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