Emerging disciplines in the border zone between physics and chemistry have 1 attracted the attention of historians of science particularly in the last 20 years. 2 Quantum chemistry, as an offshoot of theoretical chemistry, has recently acquired 3 some importance in the history of chemistry. It is the product of close 1 Cf. Hiebert, E. : Discipline Identi cation in Chemistry and Physics, in: Science in Context, 9(2) (1996), 93-119; Nye, M. J. : Physics and Chemistry: Commensurate or Incommensurate Sciences? in: The Invention of Physical Science, Intersections of Mathematics, Theology and Natural Philosophy since the Seventeenth Century - Essays in Honor of Erwin N. Hiebert. Kluwer Academic Publishers, Dordrecht 1992; From Chemical Philosophy to Theoretical Chemistry: Dynamics of Matter and Dynamics of Disciplines, 1800-1950. University of California Press, Berkeley 1994; Servos, J. W. : Physical Chemistry from Ostwald to Pauling, the Making of a Science in America. Princeton University Press, New Jersey 1990; Chemical Sciences in the 20th Century: Bridging Boundaries, edited by Carsten Reinhard. Wiley-VCH, Weinheim 2001 (incl. a comprehensive bibliography). 2 In an earlier article I point out that the term "quantum chemistry" [Quantenchemie] rst appeared in 1929. To my knowledge it was coined by the physicist Arthur Haas. Talks he had del- ered before the Viennese Chemico-Physical Society in the spring of 1929 are assembled in his book: Die Grundlagen der Quantenchemie: Eine Einleitung in vier Vortrage. It was published by the Akademische Verlagsgesellschaft in Leipzig.

n Angular Momentum Theory for Diatomic Molecules, R R method of trees, 3 construct the wave functions of more complicated systems for ex- ple many electron atoms or molecules. However, it was soon realized that unless the continuum is included, a set of hydrogenlike orbitals is not complete. To remedy this defect, Shull and Lowdin [273] - troduced sets of radial functions which could be expressed in terms of Laguerre polynomials multiplied by exponential factors. The sets were constructed in such a way as to be complete, i. e. any radial fu- tion obeying the appropriate boundary conditions could be expanded in terms of the Shull-Lowdin basis sets. Later Rotenberg [256, 257] gave the name "Sturmian" to basis sets of this type in order to emp- size their connection with Sturm-Liouville theory. There is a large and rapidly-growing literature on Sturmian basis functions; and selections from this literature are cited in the bibliography. In 1968, Goscinski [138] completed a study ofthe properties ofSt- rnian basis sets, formulating the problem in such a way as to make generalization of the concept very easy. In the present text, we shall follow Goscinski's easily generalizable definition of Sturmians.

Terahertz (THz) radiation with frequencies between 100 GHz and 30 THz has developed into an important tool of science and technology, with numerous applications in materials characterization, imaging, sensor technologies, and telecommunications. Recent progress in THz generation has provided ultrashort THz pulses with electric field amplitudes of up to several megavolts/cm. This development opens the new research field of nonlinear THz spectroscopy in which strong light-matter interactions are exploited to induce quantum excitations and/or charge transport and follow their nonequilibrium dynamics in time-resolved experiments. This book introduces methods of THz generation and nonlinear THz spectroscopy in a tutorial way, discusses the relevant theoretical concepts, and presents prototypical, experimental, and theoretical results in condensed matter physics. The potential of nonlinear THz spectroscopy is illustrated by recent research, including an overview of the relevant literature.

The first part of this third volume of Wigner's Collected Works is devoted to his analysis of symmetries in quantum mechanics, of the relativistic wave equations, of relativistic particle theory, and of field theory. It is introduced by the masterly annotation of Arthur S. Wightman. Abner Shimony annotates the second part where the reader will find Wigner's contributions to the foundations of quantum physics and to the problems of measurement.

This thesis reports on experiments in which the motion of a mechanical oscillator is measured with unprecedented precision. The position fluctuations of the oscillator-a glass nanostring-are measured with an imprecision that is sufficient to resolve its quantum zero-point motion within its thermal decoherence time. The concomitant observation of measurement back-action, in accordance with Heisenberg's uncertainty principle, verifies the principles of linear quantum measurements on a macroscopic mechanical object. The record of the measurement is used to perform feedback control so as to suppress both classical thermal motion and quantum measurement back-action. These results verify some of the central and long-standing predictions of quantum measurement theory applied to a macroscopic object. The act of measurement not only perturbs the subject of the measurement-the mechanical oscillator-but also changes the state of the light used to make the measurement. This prediction is verified by demonstrating that the optical field, after having interacted with the mechanical oscillator, contains quantum correlations that render its quadrature fluctuations smaller than those of the vacuum - i.e., the light is squeezed. Lastly, the thesis reports on some of the first feedback control experiments involving macroscopic objects in the quantum regime, together with an exploration of the quantum limit of feedback control. The book offers a pedagogical account of linear measurement theory, its realization via optical interferometry, and contains a detailed guide to precision optical interferometry..

This book shines bright light into the dim recesses of quantum theory, where the mysteries of entanglement, nonlocality, and wave collapse have motivated some to conjure up multiple universes, and others to adopt a "shut up and calculate" mentality. After an extensive and accessible introduction to quantum mechanics and its history, the author turns attention to his transactional model. Using a quantum handshake between normal and time-reversed waves, this model provides a clear visual picture explaining the baffling experimental results that flow daily from the quantum physics laboratories of the world. To demonstrate its powerful simplicity, the transactional model is applied to a collection of counter-intuitive experiments and conceptual problems.

This text builds a solid introduction to the concepts and techniques of quantum mechanics in settings where the phenomena treated are sufficiently simple that the student does not face two fundamental difficulties simultaneously: viz, that of learning quantum mechanics and that of learning how to assess the validity of models or the reliability of approximations. The treatment thus confines itself to systems that can either be solved exactly or be handled by well-controlled, plausible approximations. With few exceptions, this means systems with a small number of degrees of freedom. The exceptions are a first pass at many-electron atoms, the electromagnetic field, and the Dirac equation. (The inclusion of these last two topics reflects the now widely-held belief that every physicist should have at least a nodding acquaintance with these cornerstones of modern physics.) Born in Vienna, Kurt Gottfried emigrated to Canada in 1939 and received his Ph.D. in theoretical physics from MIT in 1955. He is professor of physics at Cornell University, and had previously been at Harvard University, the Massachusetts Institute of Technology, and at CERN in Geneva. He is the co-author of Concepts of Particle Physics (with V.F. Weisskopf), and of The Fallacy of Star Wars and Crisis, Stability, and Nuclear War. Gottfried has an active interest in arms control and human rights and is a founder and currently the Chair of the Union of Concerned Scientists.

In a distilled and pedagogical fashion, the contributions to this volume of the famous summer school in Les Houches cover the recent developments in supersymmetric string theory, the gauge theory/string theory correspondence and string duality. Further chapters deal with quantum gravity and D-brane geometry. Black hole mechanics and cosmology are treated too, as well as the AdS-CFT correspondence. The book is a comprehensive introduction to the recent developments in string/M-theory and quantum gravity. It addresses graduate students in physics and astrophysics.

This thesis presents two production cross-section measurements of pairs of massive bosons using final states with leptons, made with the ATLAS detector at the Large Hadron Collider. The first measurement, performed using data collected in 2012 at center-of-mass energy s = 8 TeV, is the first fiducial and differential cross-section measurement of the production of the Higgs Boson when it decays to four charged leptons (electrons or muons). The second measurement is the first fiducial and inclusive production cross-section measurement of WZ pairs at center-of-mass energy s = 13 TeV using final states with three charged leptons. A significant portion of the thesis focuses on the methods used to identify electrons from massive boson decay-important for many flagship measurements-and on assessing the efficiency of these particle identification techniques. The chapter discussing the WZ pair cross-section measurement provides a detailed example of an estimate of lepton background in the context of an analysis with three leptons in the final state.

This thesis presents results crucial to the emerging field of indirect excitons. These specially designed quasiparticles give the unique opportunity to study fundamental properties of quantum degenerate Bose gases in semiconductors. Furthermore, indirect excitons allow for the creation of novel optoelectronic devices where excitons are used in place of electrons. Excitonic devices are explored for the development of advanced signal processing seamlessly coupled with optical communication. The thesis presents and describes the author's imaging experiments that led to the discovery of spin transport of excitons. The many firsts presented herein include the first studies of an excitonic conveyer, leading to the discovery of the dynamical localization-delocalization transition for excitons, and the first excitonic ramp and excitonic diode with no energy-dissipating voltage gradient.

In this monograph, we shall present a new mathematical formulation of quantum theory, clarify a number of discrepancies within the prior formulation of quantum theory, give new applications to experiments in physics, and extend the realm of application of quantum theory well beyond physics. Here, we motivate this new formulation and sketch how it developed. Since the publication of Dirac's famous book on quantum mechanics [Dirac, 1930] and von Neumann's classic text on the mathematical foundations of quantum mechanics two years later [von Neumann, 1932], there have appeared a number of lines of development, the intent of each being to enrich quantum theory by extra polating or even modifying the original basic structure. These lines of development have seemed to go in different directions, the major directions of which are identified here: First is the introduction of group theoretical methods [Weyl, 1928; Wigner, 1931] with the natural extension to coherent state theory [Klauder and Sudarshan, 1968; Peremolov, 1971]. The call for an axiomatic approach to physics [Hilbert, 1900; Sixth Problem] led to the development of quantum logic [Mackey, 1963; Jauch, 1968; Varadarajan, 1968, 1970; Piron, 1976; Beltrametti & Cassinelli, 1981], to the creation of the operational approach [Ludwig, 1983-85, 1985; Davies, 1976] with its application to quantum communication theory [Helstrom, 1976; Holevo, 1982), and to the development of the C* approach [Emch, 1972]. An approach through stochastic differential equations ("stochastic mechanics") was developed [Nelson, 1964, 1966, 1967].

This book describes the subject of electrodynamics at classical as well as quantum level, developed as an interaction at a distance. Thus it has electric charges interacting with one another directly and not through the medium of a field. In general such an interaction travels forward and backward in time symmetrically, thus apparently violating the principle of causality. It turns out, however, that in such a description the cosmological boundary conditions become very important. The theory therefore works only in a cosmology with the right boundary conditions; but when it does work it is free from the divergences that plague a quantum field theory.

This book describes the subject of electrodynamics at classical as well as quantum level, developed as an interaction at a distance. Thus it has electric charges interacting with one another directly and not through the medium of a field. In general such an interaction travels forward and backward in time symmetrically, thus apparently violating the principle of causality. It turns out, however, that in such a description the cosmological boundary conditions become very important. The theory therefore works only in a cosmology with the right boundary conditions; but when it does work it is free from the divergences that plague a quantum field theory.

This monograph is accessible to anyone with an undergraduate background in quantum mechanics, electromagnetism and some solid state physics. It describes in detail the properties of particles and fields in quasi-two-dimensional systems used to approximate realistic quantum heterostructures. Here the authors treat wires, i.e. they assume an infinite hardwall potential for the system. They discuss bound states, the properties of transmission and reflection, conductance, etc. It is shown that the simple models developed in this book in detail are capable of understanding even complex physical phenomena. The methods are applied to optical states in photonic crystals, and similarities and differences between those and electronic states in quantum heterostructures and electromagnetic fields in waveguides are discussed.

In this thesis the author discusses the phenomenology of supersymmetric models by means of experimental data set analysis of the electric dipole moment. There is an evaluation of the elementary processes contributing to the electric dipole moments within R-parity-violating supersymmetry, which call for higher-order perturbative computations.

A new method based on linear programming is developed and for the first time the non-trivial parameter space of R-parity violation respecting the constraints from existing experimental data of the electric dipole moment is revealed. As well, the impressive efficiency of the new method in scanning the parameter space of the R-parity-violating sector is effectively demonstrated. This new method makes it possible to extract from the experimental data a more reliable constraint on the R-parity violation.

In this fascinating and accessible book, physicist Victor J. Stenger guides the lay reader through the key developments of quantum mechanics and the debate over its apparent paradoxes. In the process, he critically appraises recent metaphysical fads popularized by such authors as Deepak Chopra and Fritjof Capra. Dr. Stenger's knack for elucidating scientific ideas and controversies in language that the nonspecialist can comprehend opens up to the widest possible audience a wealth of information on the most important findings of contemporary physics. Stenger makes it clear that current scientific hypotheses about the material nature of reality are all we need to explain the available evidence and that mystical notions say more about the human need to believe than about the fundamental makeup of the universe.

This thesis discusses in detail the measurement of the polarizations of all S-wave vector quarkonium states in LHC proton-proton collisions with the CMS detector. Heavy quarkonium states constitute an ideal laboratory to study non-perturbative effects of quantum chromodynamics and to understand how quarks bind into hadrons. The experimental results are interpreted through an original phenomenological approach, which leads to a coherent picture of quarkonium production cross sections and polarizations within a simple model, dominated by one single color-octet production mechanism. These findings provide new insights into the dynamics of heavy quarkonium production at the LHC, an important step towards a satisfactory understanding of hadron formation within the standard model of particle physics.

The problem of irreversibility is ubiquitous in physics and chemistry. The present book attempts to present a unified theoretical and conceptual framework for the description of various irreversible phenomena in quantum mechanics. In a sense, this book supplements conventional textbooks on quantum mechanics by including the theory of irreversibilities. However, the content and style of this book are more appropriate for a monograph than a textbook. We have tried to arrange the material so that, as far as possible, the reader need not continually refer elsewhere. The references to the literature make no pretense of completeness. The book is by no means a survey of present theoretical work. We have tried to highlight the basic principles and their results, while the attention has been mainly paid to the problems in which the author himself has been involved. The book as a whole is designed for the reader with knowledge of theoretical physics (especially quantum mechanics) at university level. This book is based on the courses of lectures given at the Chemistry Department of Tel-Aviv University.

This volume contains the proceedings of the NATO Advanced Research Workshop on Quantum Chaos -- Theory and Experiment', held at the Niels Bohr Institute, University of Copenhagen, from 28 May to 1 June 1991. The work brings together leading quantum chaos theorists and experimentalists and greatly improves our understanding of the physics of quantum systems whose classical limit is chaotic. Quantum chaos is a subject of considerable current interest in a variety of fields, in particular nuclear physics, chemistry, statistical mechanics, atomic physics, condensed matter physics and nonlinear dynamics. The volume contains lectures about the currently most active fronts of quantum chaos, such as scars, semiclassical methods, quantum diffusion, random matrix spectra, quantum chaos in atomic and nuclear physics, and possible implications of quantum chaos for the problem of quantum measurement. Part of the book -- The Physics of Quantum Measurements -- is dedicated to the memory of John Bell.

The nonlocality phenomena exhibited by entangled quantum systems are certainly one of the most extraordinary aspects of quantum theory. This book discusses this phe nomenon according to several points of view, i.e., according to different interpretations of the mathematics of the quantum formalism. The several interpretations of the Copenhagen interpretation, the many worlds, the de Broglie-Bohm, quantum logics, the decohering by the environment approach and the histories approach interpretations are scrutinized and criticized in detail. Recent results on cryptography, quantum bit commitment, quantum erasers and teleportation are also presented and discussed. In preparing the book we benefited from discussions with many people, but we would like, in particular, to express our gratitude to Professor B. d'Espagnat for his useful comments and suggestions. We are grateful also to Ms. L. Gentry EI-Dash for the English revision, to Dr. 1. E. Maiorino for the production of the figures and a careful reading of the manuscript, and for the statI of Plenum for advice and for having produced a nice book. Finally, the authors thank FAPESP (contract no. I 99612657-0) for a grant making this book possible. A. A. ORIB AND W. A. RODRIGUES, JR."

This work unites the concepts of laser cooling and matter-wave interferometry to develop an interferometric laser cooling technique in an experimental system of cold rubidium atoms. Serving as an introduction to graduate level coherent optical atomic manipulation, the thesis describes the theory of stimulated Raman transitions and atom interferometry, along with the experimental methods for preparing and manipulating cold atoms, before building on these foundations to explore tailored optical pulse sequences and novel atomic cooling techniques. Interferometric cooling, originally proposed by Weitz and Hansch in 2000, is based upon the coherent broadband laser pulses of Ramsey interferometry and in principle allows laser cooling of atomic and molecular species outside the scope of traditional Doppler laser cooling. On the path toward cooling, composite pulses - quantum error correction methods, developed by chemists to mitigate the effects of in homogeneities in NMR spectroscopy - are investigated with a view to improving the performance of atom interferometers.

The articles in this book have been selected from the lectures of a NATO Advanced Study Institute held at Bad Lauterberg (Germany) in August 1995. Internationally well-known researchers in the field of mesoscopic quantum physics provide insight into the fundamental physics underlying the mesoscopic transport phenomena in structured semiconductor inversion layers. In addition, some of the most recent achievements are reported in contributed papers. The aim of the volume is not to give an overview over the field. Instead, emphasis is on interaction and correlation phenomena that turn out to be of increasing importance for the understanding of the phenomena in the quantum Hall regime, and in the transport through quantum dots. The present status of the quantum Hall experiments and theory is reviewed. As a "key example" for non-Fermi liquid behavior the Luttinger liquid is introduced, including some of the most recent developments. It is not only of importance for the fractional quantum Hall effect, but also for the understanding of transport in quantum wires. Furthermore, the chaotic and the correlation aspects of the transport in quantum dot systems are described. The status of the experimental work in the area of persistent currents in semiconductor systems is outlined. The construction of one of the first single-electron transistors is reported. The theoretical approach to mesoscopic transport, presently a most active area, is treated, and some aspects of time-dependent transport phenomena are also discussed.

In this book the author extends the concepts previously introduced in his "Quantum Field Theory in Condensed Matter Physics" to situations in which the strong electronic correlations are crucial for the understanding of the observed phenomena. Starting from a model field theory to illustrate the basic ideas, more complex systems are analysed in turn. A special chapter is devoted to the description of antiferromagnets, doped Mott insulators and quantum Hall liquids from the point of view of gauge theory. This advanced text is written for graduate students and researchers working in related areas of physics.

Few people studying Gauge Field Theory need to be convinced of the importance of the work of 't Hooft. This volume contains a selection of articles and review topics covering his well-known studies on the renormalization of non-Abelian gauge theorems, topological phenomena in gauge field theory and thoughts on the role of black holes in quantum gravity. The chapters are tied together by thoughtful commentaries which provide a background and the illumination of hindsight - together they form a clear and coherent picture of the physical and theoretical importance of gauge theories and the gauge principle. This book is ideal for students and researchers. Gerard 't Hooft is Professor of Theoretical Physics at the University of Utrecht, The Netherlands. He has taught at Harvard, SLAC and Caltech prior to his present position. Other distinguished honors include being awarded the Dannie Heineman Prize, the Honorary Doctorate of Science from the University of Chicago, Wolf Prize of the State of Israel, Pius XI Medal (Vatican), and the Lorentz Medal (KNAW, Amsterdam).

High Field Science is a proceedings volume from a meeting at Lawrence Livermore Laboratory, and contains papers from the top experts in the fields of ultraintense laser technology, laser fusion energy, high energy laser electron acceleration, bright X-ray sources by lasers, laboratory laser astrophysics, and applications to relativity, high density and high energy physics.