This book presents the physico-technical basis and current state of the technology of boronized layers. Special attention is given to the layer structure and morphology of allocated phases and distributions in a superficial zone of chemical compounds. Two- and multi-component phases of alloys and diffusion processes in a self-organizing mode are discussed. Surface hardening by boronizing increases the life time of mechanical tools. This is important for the mining industry, agriculture, textile and chemical industry. The book is important for thermochemical treatment and surface hardening of metals and alloys.

This book sheds new light on topological defects in widely differing systems, using the Velocity-Dependent One-Scale Model to better understand their evolution. Topological defects - cosmic strings, monopoles, domain walls or others - necessarily form at cosmological (and condensed matter) phase transitions. If they are stable and long-lived they will be fossil relics of higher-energy physics. Understanding their behaviour and consequences is a key part of any serious attempt to understand the universe, and this requires modelling their evolution. The velocity-dependent one-scale model is the only fully quantitative model of defect network evolution, and the canonical model in the field. This book provides a review of the model, explaining its physical content and describing its broad range of applicability.

This book mainly focuses on the theoretical and experimental study of non-Fourier heat conduction behavior. A novel thermomass theory is used as the theoretical basis, which provides a general heat conduction equation for the accurate prediction of non-Fourier heat conduction. In order to prove the validity of this thermomass theory, a large current was used to heat the metallic nanofilm at the minimum temperature of 3 K. The measured average temperature of the nanofilm was notably higher than the prediction of Fourier’s heat diffusion equation, while matching well with the general heat conduction equation. This is the first time that steady non-Fourier heat conduction has been observed. Moreover, this book concerns the role of electron-phonon interaction in metallic nanofilms, which involves the breakdown of the Wiedemann-Franz law at low temperatures and interfacial thermal resistance at femtosecond timescales. Readers will find useful information on non-Fourier heat conduction and the latest advances in the study of charge and heat transport in metallic nanofilms.

The release of this second volume of CHIPS 2020 coincides with the 50th anniversary of Moore's Law, a critical year marked by the end of the nanometer roadmap and by a significantly reduced annual rise in chip performance. At the same time, we are witnessing a data explosion in the Internet, which is consuming 40% more electrical power every year, leading to fears of a major blackout of the Internet by 2020. The messages of the first CHIPS 2020, published in 2012, concerned the realization of quantum steps for improving the energy efficiency of all chip functions. With this second volume, we review these messages and amplify upon the most promising directions: ultra-low-voltage electronics, nanoscale monolithic 3D integration, relevant-data, brain- and human-vision-inspired processing, and energy harvesting for chip autonomy. The team of authors, enlarged by more world leaders in low-power, monolithic 3D, video, and Silicon brains, presents new vistas in nanoelectronics, promising Moore-like exponential growth sustainable through to the 2030s.

Advances in Polymer Science enjoys a longstanding tradition and good reputation in its community. Each volume is dedicated to a current topic, and each review critically surveys one aspect of that topic, to place it within the context of the volume. The volumes typically summarize the significant developments of the last 5 to 10 years and discuss them critically, presenting selected examples, explaining and illustrating the important principles, and bringing together many important references of primary literature. On that basis, future research directions in the area can be discussed. Advances in Polymer Science volumes thus are important references for every polymer scientist, as well as for other scientists interested in polymer science - as an introduction to a neighboring field, or as a compilation of detailed information for the specialist.

This practically-oriented overview of nanotechnologies and nanosciences is designed to provide students and researchers with essential information on both the tools of manufacture and specific features of the nanometric scale. Specific applications and techniques covered include nanolithography, STM and AFM, nanowires and supramolecules, molecular electronics, pptronics, and simulation. Each section devotes space to industrial applications and prospective developments. The book provides the only pedagogical review on major nanosciences topics at this level.

This course-tested textbook conveys the fundamentals of magnetic fields and relativistic plasma in diffuse cosmic media, with a primary focus on phenomena that have been observed at different wavelengths. Theoretical concepts are addressed wherever necessary, with derivations presented in sufficient detail to be generally accessible. In the first few chapters the authors present an introduction to various astrophysical phenomena related to cosmic magnetism, with scales ranging from molecular clouds in star-forming regions and supernova remnants in the Milky Way, to clusters of galaxies. Later chapters address the role of magnetic fields in the evolution of the interstellar medium, galaxies and galaxy clusters. The book is intended for advanced undergraduate and postgraduate students in astronomy and physics and will serve as an entry point for those starting their first research projects in the field.

The book introduces ‘the state of the art' of pulsed laser ablation and its applications. It is based on recent theoretical and experimental studies. The book reaches from the basics to advanced topics of pulsed laser ablation. Theoretical and experimental fundamental phenomena involved in pulsed laser ablation are discussed with respect to material properties, laser wavelength, fluence and intensity regime of the light absorbed linearly or non-linearly in the target material. The energy absorbed by the electrons leads to atom/molecule excitation, ionization and/or direct chemical bond breaking and is also transferred to the lattice leading to material heating and phase transitions. Experimental non-invasive optical methods for analyzing these phenomena in real time are described. Theoretical models for pulsed laser ablation and phase transitions induced by laser beams and laser-vapour/plasma interaction during the plume expansion above the target are also presented. Calculations of the ablation speed and dimensions of the ablated micro- and nano-structures are performed. The validity and required refinement of different models in different experimental conditions is provided. The pulsed laser deposition process which bases on collecting the ablated particles on a surface is analyzed in terms of efficiency and quality of the deposited films as a function of ambient conditions, target material, laser parameters and substrate characteristics. The interaction between the incident laser and the ablation plasma is analyzed with respect to its influence on the structures of the deposited films and its capacity to generate high harmonics and single attosecond pulses which are highly desirable in pump-probe experiments.

This thesis focuses on magnetic reconnection processes in the boundary layer of the interplanetary magnetic cloud. Magnetic reconnection is an important and frontier topic in the realm of physics. Various physical phenomena can be observed during the reconnection process but lots of them are not fully understood. This thesis provides the first observational evidence of energetic electrons associated with magnetic reconnection in the solar wind and discusses the particle acceleration problems. In addition, after analyzing the particle flux variations in Magnetic Cloud Boundary Layer, the thesis proposes a possible new criterion for the identification of magnetic reconnection in the solar wind. These tantalizing results could be particular clues to understand the dynamical problems in magnetic reconnection processes.

The application of molecules in technological devices hinges on the proper understanding of their behavior on metallic electrodes or substrates. The intrinsic molecular electronic and magnetic properties are modified at a metallic interface, and greatly depend on the atomic configuration of the molecule-metal bond. This poses certain problems, such as the lack of reproducibility in the transport properties of molecular junctions, but also offers the possibility to induce new charge and spin configurations that are only present at the interface. The results presented in this thesis address this issue, providing a comprehensive overview of the influence of molecule-metal and molecule-molecule interactions on the electronic and magnetic properties of molecules adsorbed on metallic substrates. Using metal-phthalocyanines (MePc), a commonly used metal-organic complex as a model system, each chapter explores different aspects of the interaction with silver surfaces: the local adsorption geometry, self-assembly, the modifications of the electronic and magnetic characteristics due to hybridization and charge transfer, and finally the manipulation of molecular charge and spin states by electron doping using alkali atoms moved with the STM tip.

This thesis conceptualizes and implements a new framework for designing materials that are far from equilibrium. Starting with state-of-the-art optimization engines, it describes an automated system that makes use of simulations and 3D printing to find the material that best performs a user-specified goal. Identifying which microscopic features produce a desired macroscopic behavior is a problem at the forefront of materials science. This task is materials design, and within it, new goals and challenges have emerged from tailoring the response of materials far from equilibrium. These materials hold promising properties such as robustness, high strength, and self-healing. Yet without a general theory to predict how these properties emerge, designing and controlling them presents a complex and important problem. As proof of concept, the thesis shows how to design the behavior of granular materials, i.e., collections of athermal, macroscopic identical objects, by identifying the particle shapes that form the stiffest, softest, densest, loosest, most dissipative and strain-stiffening aggregates. More generally, the thesis shows how these results serve as prototypes for problems at the heart of materials design, and advocates the perspective that machines are the key to turning complex material forms into new material functions.

The presentations at this NASA-hosted Symposium in honor of Mino Freund will touch upon the fields, to which his prolific mind has made significant contributions. These include low temperature physics, cosmology, and nanotechnology with its wide-ranging applicability to material science, neuroscience, Earth sciences and satellite technology. To learn more about Mino’s career you can download the "Tribute" http://multimedia.seti.org/mino/Tribute.pdf which outlines his journey from (i) low-temperature physics and superconductivity at the ETH Zürich to (ii) building one remarkable milliKelvin refrigerator for the US-Japan IRTS mission at UC Berkeley and ISAS in Japan to (iii) a decade in cosmology, to (iv) being on the micro-bolometer team at NASA Goddard for the HAWC instrument on SOFIA, to (v) developing at AFRL the nanotechnology portfolio for the entire Air Force. This was followed by six years at the NASA Ames Research Center, where Mino formulated his far-ahead ideas about swarms of capable nanosats circling the Earth, which have since started to become a reality. He engaged in a broad range of nanotechnology projects, including novel applications in neuroscience well before he himself was struck by the deadly brain tumor.

This book reflects the outcome of the 1st International Workshop on Turbulent Spray Combustion held in 2009 in Corsica (France). The focus is on reporting the progress of experimental and numerical techniques in two-phase flows, with emphasis on spray combustion. The motivation for studies in this area is that knowledge of the dominant phenomena and their interactions in such flow systems is essential for the development of predictive models and their use in combustor and gas turbine design. This necessitates the development of accurate experimental methods and numerical modelling techniques. The workshop aimed at providing an opportunity for experts and young researchers to present the state-of-the-art, discuss new developments or techniques and exchange ideas in the areas of experimentations, modelling and simulation of reactive multiphase flows. The first two papers reflect the contents of the invited lectures, given by experts in the field of turbulent spray combustion. The first concerns computational issues, while the second deals with experiments. These lectures initiated very interesting and interactive discussions among the researchers, further pursued in contributed poster presentations. Contributions 3 and 4 focus on some aspects of the impact of the interaction between fuel evaporation and combustion on spray combustion in the context of gas turbines, while the final article deals with the interaction between evaporation and turbulence.

The material in this work is focused on recent developments in research into the stress-strain behavior of geomaterials, with an emphasis on laboratory measurements, soil constitutive modeling and behavior of soil structures (such as reinforced soils, piles and slopes). The latest advancements in the field, such as the rate effect and dynamic behavior of both clay and sand, behavior of modified soils and soil mixtures, and soil liquefaction are addressed.

This book is a new edition of Roederer's classic Dynamics of Geomagnetically Trapped Radiation, updated and considerably expanded. The main objective is to describe the dynamic properties of magnetically trapped particles in planetary radiation belts and plasmas and explain the physical processes involved from the theoretical point of view. The approach is to examine in detail the orbital and adiabatic motion of individual particles in typical configurations of magnetic and electric fields in the magnetosphere and, from there, derive basic features of the particles' collective "macroscopic" behavior in general planetary environments. Emphasis is not on the "what" but on the "why" of particle phenomena in near-earth space, providing a solid and clear understanding of the principal basic physical mechanisms and dynamic processes involved. The book will also serve as an introduction to general space plasma physics, with abundant basic examples to illustrate and explain the physical origin of different types of plasma current systems and their self-organizing character via the magnetic field. The ultimate aim is to help both graduate students and interested scientists to successfully face the theoretical and experimental challenges lying ahead in space physics in view of recent and upcoming satellite missions and an expected wealth of data on radiation belts and plasmas.

Ion Correlations at Electrified Soft Matter Interfaces presents an investigation that combines experiments, theory, and computer simulations to demonstrate that the interdependency between ion correlations and other ion interactions in solution can explain the distribution of ions near an electrified liquid/liquid interface. The properties of this interface are exploited to vary the coupling strength of ion-ion correlations from weak to strong while monitoring their influence on ion distributions at the nanometer scale with X-ray reflectivity and on the macroscopic scale with interfacial tension measurements. This thesis demonstrates that a parameter-free density functional theory that includes ion-ion correlations and ion-solvent interactions is in agreement with the data over the entire range of experimentally tunable correlation coupling strengths. The reported findings represent a significant advance towards understanding the nature and role of ion correlations in charged soft-matter. Ion distributions underlie many scientific phenomena and technological applications, including electrostatic interactions between charged biomolecules and the efficiency of energy storage devices. These distributions are determined by interactions dictated by the chemical properties of the ions and their environment, as well as the long-range nature of the electrostatic force. The presence of strong correlations between ions is responsible for counterintuitive effects such as like-charge attraction.

This book continues the biannual series of conference proceedings, which has become a classical reference resource in traffic and granular research alike, and addresses the latest developments at the intersection of physics, engineering and computational science. These involve complex systems, in which multiple simple agents, be they vehicles or particles, give rise to surprising and fascinating phenomena. The contributions collected in these proceedings cover several research fields, all of which deal with transport. Topics include highway, pedestrian and internet traffic; granular matter; biological transport; transport networks; data acquisition; data analysis and technological applications. Different perspectives, i.e., modeling, simulations, experiments, and phenomenological observations are considered.

1. Dynamic Force Microscopy and Spectroscopy using the Frequency-Modulation Technique in Air and Liquids.- 2. Colossal Permittivity in Advanced Functional Heterogeneous Materials: The Relevance of the Local Measurements at Submicron Scale.- 3. Scanning Probe Alloying Nanolithography.- 4. Controlling Wear on Nanoscale.- 5. Structural and Mechanical Mechanisms of Ocular Tissues Probed by AFM.- 6. Modern Atomic Force Microscopy and Its Application to the Study of Genome Architecture.- 7. Near-field Nanolitography.- 8. Photonic Force Microscopy: From Femtonewton Force Sensing to Ultra-Sensitive Spectroscopy.- 9. Simultaneous Topography and Recognition Imaging.- 10. Application of Contact Mode AFM to Manufacturing Processes.- 11. Mechanical Properties of One-dimensional Nanostructures.- 12. Contact Potential Difference Techniques as Probing Tools in Tribology and Surface Mapping.- 13. Force-extension (FX) and Force-clamp (FC) AFM Spectroscopies in Investigating Mechanochemical Reactions and Mechanical properties of Single Biomolecules.- 14. Scanning Probe Microscopy as a Tool Applied to Agriculture.- 15. Spin Charge Pairing Instabilities, Magnetism and Ferroelectricity in Nanoclusters, High-Tc Cuprates, Manganites and Multiferroic Nanomaterials.- 16. Combining Atomic Force Microscopy and Depth Sensing Instruments for the Nanometre Scale Mechanical Characterization of Soft Matter.- 17. Structuring the Surface of Crystallizable Polymers with an AFM Tip.- 18. Polarization-sensitive Tip-enhanced Raman Scattering.- 19. Static and Dynamic Structural Modeling Analysis of Atomic Force Microscope.- 20. Carbon Nanotube Atomic Force Microscopy with Applications to Biology and Electronics.- 21. Multilevel Experimental and Modelling Techniques for Bioartificial Scaffolds and Matrices.- 22. A New AFM Based Lithography Method: ThermoChemical NanoLithography.- 23. Novel Strategies to Probe the Fluid Properties and Revealing its Hidden Elasticity.- 24. Electrostatic Force Microscopy and Kelvin Force Microscopy as a Probe of the Electrostatic and Electronic Properties of Carbon Nanotubes.- 25. Quantized Mechanics of Nanotubes and Bundles.- 26. Experimental Methods for the Calibration of Lateral Forces in Atomic Force Microscopy.

Particulate products make up around 80% of chemical products, from all industry sectors. Examples given in this book include the construction materials, fine ceramics and concrete; the delicacies, chocolate and ice cream; pharmaceutical, powders, medical inhalers and sun screen; liquid and powder paints. Size distribution and the shape of the particles provide for different functionalities in these products. Some functions are general, others specific. General functions are powder flow and require - at the typical particulate concentrations of these products - that the particles cause adequate rheological behavior during processing and/or for product performance. Therefore, this book addresses particle packing as well as its relation to powder flow and rheological behavior. Moreover, general relationships to particle size are discussed for e.g. color and sensorial aspects of particulate products. Product-specific functionalities are often relevant for comparable product groups. Particle size distribution and shape provide, for example, the following functionalities: - dense particle packing in relation to sufficient strength is required in concrete construction, ceramic objects and pharmaceutical tablets - good sensorial properties (mouthfeel) to chocolate and ice cream - effective dissolution, flow and compression properties for pharmaceutical powders - adequate hiding power and effective coloring of paints for protection and the desired esthetical appeal of the objects - adequate protection of our body against sun light by sunscreen - effective particle transport and deposition to desired locations for medical inhalers and powder paints. Adequate particle size distribution, shape and porosity of particulate products have to be achieved in order to reach optimum product performance. This requires adequate management of design and development as well as sufficient knowledge of the underlying principles of physics and chemistry. Moreover, flammability, explosivity and other health hazards from powders, during handling, are taken into account. This is necessary, since great risks may be involved. In all aspects, the most relevant parameters of the size distribution (and particle shape) have to be selected. In this book, experts in the different product fields have contributed to the product chapters. This provides optimum information on what particulate aspects are most relevant for behavior and performance within specified industrial products and how optimum results can be obtained. It differs from other books in the way that the critical aspects of different products are reported, so that similarities and differences can be identified. We trust that this approach will lead to improved optimization in design, development and quality of many particulate products.

Synergetics is the quantitative study of multicomponent systems that exhibit nonlinear dynamics and cooperativity. This book specifically considers basic models of the nonlinear dynamics of molecular systems and discusses relevant applications in biological physics and the polymer sciences. Emphasis is placed on specific solutions to the dynamical equations that correspond to the coherent formation of spatial-temporal structures, such as solitons, kinks and breathers, in particular. The emergence of these patterns in molecular structures provides a variety of information on their structural properties and plays a significant part in energy transfer processes, topological defects, dislocations, and related structure transitions. Real media, in which solitons take the form of solitary waves, are also considered. In this context, the formation of nonlinear waves in a continuous medium described by nonlinear equations is associated with spontaneous breaking of the local symmetry of the homogeneous system, which produces a range of interesting phenomena. A particular feature of this text is its combination of analytic and computational strategies to tackle difficult nonlinear problems at the molecular level of matter.

Smart Hydrogel Functional Materials comprehensively and systematically describes our current understanding of smart or intelligent hydrogel functional materials with environmental stimuli-responsive functions. The contents range from hydrogels (including hydrogel-functionalized membranes) to microgels (including hydrogel-functionalized microcapsules) with various response properties, such as thermo-response, pH-response, pH-/thermo-dual-response, glucose-response, ethanol-response, ion-recognition, molecular-recognition, and so on. Most of the contents in this book represent the fresh achievements of the authors’ group on smart hydrogel functional materials. While all chapters can be read as stand-alone papers, together they clearly describe the design concepts, fabrication strategies and methods, microstructures and performances of smart hydrogel functional materials. Vivid schematics and illustrations throughout the book enhance the accessibility of the theory and technologies involved. This is an ideal reference book for a broad general readership including chemists, materials researchers, chemical engineers, pharmaceutical scientists and biomedical researchers, who are interested in designing and fabricating smart hydrogel functional materials for various application purposes. Dr. Liang-Yin Chu is a professor at the School of Chemical Engineering, Sichuan University, China. He is a Distinguished Young Scholar of the National Natural Science Foundation of China and a Distinguished Professor of the “Chang Jiang Scholars Program” of the Ministry of Education of China.

This book focuses on the exciting topic of nanoscience with liquid crystals: from self-organized nanostructures to applications. The elegant self-organized liquid crystalline nanostructures, the synergetic characteristics of liquid crystals and nanoparticles, liquid crystalline nanomaterials, synthesis of nanomaterials using liquid crystals as templates, nanoconfinement and nanoparticles of liquid crystals are covered and discussed, and the prospect of fabricating functional materials is highlighted. Contributions, collecting the scattered literature of the field from leading and active players, are compiled to make the book a reference book. Readers will find the book useful and of benefit both as summaries for works in this field and as tutorials and explanations of concepts for those just entering the field. Additionally, the book helps to stimulate future developments.

Independent Variables for Optical Surfacing Systems discusses the characterization and application of independent variables of optical surfacing systems and introduces the basic principles of surfacing technologies and common surfacing systems. All the pivotal variables influencing surface quality are analyzed; evaluation methods for surface quality, the removal capability of tool influence functions, and a series of novel optical surfacing systems are introduced. The book also particularly focuses on the multi-path mode and dwell time used for deterministic surfacing. Researchers and graduate students working in optical engineering will benefit from this book; optical engineers in the industry will also find it a valuable reference work. Haobo Cheng is a professor at Beijing Institute of Technology.

Imaging and Manipulating Molecular Orbitals celebrates the 60th anniversary of the first image of a single molecule by E. Müller. This book summarizes the advances in the field from various groups around the world who use a broad range of experimental techniques: scanning probe microscopy (STM and AFM), field emission microscopy, transmission electron microscopy, attosecond tomography and photoemission spectroscopy. The book is aimed at those who are interested in the field of molecular orbital imaging and manipulation. Included in the book are a variety of experimental techniques in combination with theoretical approaches which describe the spatial distribution and energies of the molecular orbitals. The goal is to provide the reader with an up-to-date summary on the latest developments in this field from various points of view.

This book deals with basic aspects of polymer electronics and optoelectronics. There is an enormous world-wide effort both in basic scientific research as well as in industrial development in the area of organic electronics. It is becoming increasingly clear that, if devices based on organic materials are ever going to have a significant relevance beyond being a cheap replacement for inorganic semiconductors, there will be a need to understand interface formation, film growth and functionality. A control of these aspects will allow the realisation of totally new device concepts exploiting the enormous flexibility inherent in organic chemistry. In this book we focus on oligomeric/molecular films as we believe that the control of molecular structures and interfaces provides highly defined systems which allow, on the one hand the study of the basic physics and on the other hand to find the important parameters necessary to improve organic devices.