Solid-State NMR Characterization of Heterogeneous Catalysts and Catalytic Reactions provides a comprehensive account of state-of-the-art solid-state NMR techniques and the application of these techniques in heterogeneous catalysts and related catalytic reactions. It includes an introduction to the basic theory of solid-state NMR and various frequently used techniques. Special emphasis is placed on characterizing the framework and pore structure, active site, guest-host interaction, and synthesis mechanisms of heterogeneous catalysts using multinuclear one- and two-dimensional solid-sate NMR spectroscopy. Additionally, various in-situ solid-state NMR techniques and their applications in investigation of the mechanism of industrially important catalytic reactions are also discussed. Both the fundamentals and the latest research results are covered, making the book suitable as a reference guide for both experienced researchers in and newcomers to this field. Feng Deng is a Professor at Wuhan Institute of Physics and Mathematics, Chinese Academy of Sciences.

This thesis extends our understanding of systems of independent electrons by developing a generalization of Bloch's Theorem which is applicable whenever translational symmetry is broken solely due to arbitrary boundary conditions. The thesis begins with a historical overview of topological condensed matter physics, placing the work in context, before introducing the generalized form of Bloch's Theorem. A cornerstone of electronic band structure and transport theory in crystalline matter, Bloch's Theorem is generalized via a reformulation of the diagonalization problem in terms of corner-modified block-Toeplitz matrices and, physically, by allowing the crystal momentum to take complex values. This formulation provides exact expressions for all the energy eigenvalues and eigenstates of the single-particle Hamiltonian. By precisely capturing the interplay between bulk and boundary properties, this affords an exact analysis of several prototypical models relevant to symmetry-protected topological phases of matter, including a characterization of zero-energy localized boundary excitations in both topological insulators and superconductors. Notably, in combination with suitable matrix factorization techniques, the generalized Bloch Hamiltonian is also shown to provide a natural starting point for a unified derivation of bulk-boundary correspondence for all symmetry classes in one dimension.

This monograph treats an extensively developed field in modern mathematical physics - the theory of generalized coherent states and their applications to various physical problems. Coherent states, introduced originally by Schrodinger and von Neumann, were later employed by Glauber for a quantal description of laser light beams. The concept was generalized by the author for an arbitrary Lie group. In the last decade the formalism has been widely applied to various domains of theoretical physics and mathematics. The area of applications of generalized coherent states is very wide, and a comprehensive exposition of the results in the field would be helpful. This monograph is the first attempt toward this aim. My purpose was to compile and expound systematically the vast amount of material dealing with the coherent states and available through numerous journal articles. The book is based on a number of undergraduate and postgraduate courses I delivered at the Moscow Physico-Technical Institute. In its present form it is intended for professional mathematicians and theoretical physicists; it may also be useful for university students of mathematics and physics. In Part I the formalism is elaborated and explained for some of the simplest typical groups. Part II contains more sophisticated material; arbitrary Lie groups and symmetrical spaces are considered. A number of examples from various areas of theoretical and mathematical physics illustrate advantages of this approach, in Part III. It is a pleasure for me to thank Dr. Yu. Danilov for many useful remarks.

This book explores the status of paper-based diagnostic solutions, or Microfluidics 2.0. The contributors explore: how paper-based tests can be widely distributed and utilized by semi-skilled personnel; how close to commercial applications the technology has become, and what is still required to make paper-based diagnostics the game-changer it can be. The technology is examined through the lens of the World Health Organization's ASSURED criteria for low-resource countries (Affordable, Sensitive, Specific, User-friendly, Rapid and robust, Equipment-free, and Deliverable to end-users). Its applications have to include: health technology, environmental technology, food safety, and more. This book is appropriate for researchers in these areas, as well as those interested in microfluidics, and includes chapters dedicated to principles such as theory of flow and surface treatments; components such as biomarkers and detection; and current methods of manufacturing. Discusses how paper-based diagnostics can be used in developing countries by comparing current diagnostic tests with the World Health Organization's ASSURED criteria Examines how paper-based diagnostics could be integrated with other technologies, such as printed electronics, and the Internet of Things. Outlines how semi-skilled personnel across a variety of fields can implement paper-based diagnostics

The study of disorder in solids is one of the key areas in contemporary solid state science. In crystalline solids there are well-developed models for describing the way in which defects control the atomic transport, thermodynamic and spectroscopic properties. In contrast, the conceptual and theoretical framework for describing these properties in amorphous solids is less well developed, partly due to the uncertainties in the structural models used to represent the disordered systems. Moreover, disordered solids include materials of great contemporary technological importance, for example, ceramic superconductors and amorphous semiconductors. The field has developed rapidly in the last few years, driven both by technological needs for improved materials and by the fundamental scientific problems posed by disorder in solids. Progress has been especially rapid in structural studies, using diffraction, EXAFS, NMR and microscopy techniques, in investigation of atomic and charge transport and in the application of theoretical and computational methods. The book provides a unified approach to disorder in solids. The earlier chapters present a survey of the theoretical and structural concepts used in describing defective and amorphous solids and the basic properties of these materials. The next chapters are devoted to a thorough survey of techniques and properties, including structural studies, transport, thermodynamic and spectroscopic properties and theoretical and computational techniques. The final chapters review materials and applications, including fast-ion conductors, sensors, amorphous semiconductors and novel glasses. It therefore presents a unique survey of an important field incontemporary solid state science.

This book contains a modern selection of about 200 solved problems and examples arranged in a didactic way for hands-on experience with course work in a standard advanced undergraduate/first-year graduate class in thermodynamics and statistical physics. The principles of thermodynamics and equilibrium statistical physics are few and simple, but their application often proves more involved than it may seem at first sight. This book is a comprehensive complement to any textbook in the field, emphasizing the analogies between the different systems, and paves the way for an in-depth study of solid state physics, soft matter physics, and field theory.

The present volume contains the written versions of most of the invited talks of the Spring Meeting of the Condensed Matter Physics section of the Deutsche Physikalische Gesellschaft held from March 25 to 29, 2002 in Regensburg, Germany. Also contained are those talks presented as part of the Symposia most of which were organized by several divisions in collaboration and covered a fascinating selection of topics of current interest. Thus this volume reflects the status of condensed matter physics in Germany in the year 2002. In particular, one notes a slight change in paradigms: from quantum dots and wires to spin transport and soft matter systems in the broadest sense. This seems to reflect the present general trend in physics. Nevertheless, a large portion of the invited papers concentrate on nanostructured matter.

This book highlights the power and elegance of algebraic methods of solving problems in quantum mechanics. It shows that symmetries not only provide elegant solutions to problems that can be solved exactly, but also substantially simplify problems that must be solved approximately. Furthermore, the book provides an elementary exposition of quantum electrodynamics and its application to low-energy physics, along with a thorough analysis of the role of relativistic, magnetic, and quantum electrodynamic effects in atomic spectroscopy. Included are essential derivations made clear through detailed, transparent calculations. The book's commitment to deriving advanced results with elementary techniques, as well as its inclusion of exercises will enamor it to advanced undergraduate and graduate students.

"Soft matter" is nowadays used to describe an increasingly important class of - terials that encompasses polymers, liquid crystals, molecular assemblies building hierarchical structures, organic-inorganic hybrids, and the whole area of colloidal science. Common to all is that ?uctuations, and thus the thermal energy k T and B entropy, play an important role. "Soft" then means that these materials are in a state of matter that is neither a simple liquid nor a hard solid of the type studied in hard condensed matter, hence sometimes many types of soft matter are also named "c- plex ?uids. " Soft matter, either of synthetic or biological origin, has been a subject of physical and chemical research since the early ?nding of Staudinger that long chain mo- cules exist. From then on, synthetic chemistry as well as physical characterization underwent an enormous development. One of the outcomes is the abundant pr- ence of polymeric materials in our everyday life. Nowadays, methods developed for synthetic polymers are being more and more applied to biological soft matter. The link between modern biophysics and soft matter physics is quite close in many respects. This also means that the focus of research has moved from simple - mopolymers to more complex structures, such as branched objects, heteropolymers (random copolymers, proteins), polyelectrolytes, amphiphiles and so on.

Features Presents an interdisciplinary approach, applicable to a wide range of researchers in waste treatment companies, authorities, and energy and environmental policymakers. Authored by authorities in the field. Up to date with the latest developments and technologies.

This volume is based on the talks and lectures given by the participants of the 3-month seminar program "Topology in Condensed Matter," which was held in the MPIPKS Dresden, 8 May-31 July 2002 under the scienti?c direction of Professors M. Kleman, S. Novikov, and myself. The aim of this program was to discuss recent applications of topology to several areas in condensed matter physics and related ?elds like biology. The last 30 years of the development of modern physics a?rmed two important ideas. The ?rst is the e?cient applications of topology in physics. One should mention applications in condensed matter, such as classi?cation of defects and textures in liquid crystals and super?uid liquids, the role of entangibility in polymer physics and DNA structures. The second tendency is also very prevalent. Some important discoveries in particle physics and condensed m- ter led to new and unpredictable questions in pure mathematics. We refer to the invention of monopoles and instantons in quantum ?eld theory, q- sicrystals ?uid membranes of high genus, fullerenes (C ,C , etc. ), and so on 60 90 in condensed matter. The number of such applications in the last years has increased substantially. The papers presented in this volume and the next one "Topology in - ology" re?ect the spectrum of topics discussed. Besides original papers, a mini-course in topology for physicists and biologists was organized. These lectures will be published in the second volume.

- written by world leading experts in the field - contains many worked-out examples, taken from daily life fire related practical problems - covers the entire range from basics up to state-of-the-art computer simulations of fire and smoke related fluid mechanics aspects, including the effect of water - provides extensive treatment of the interaction of water sprays with a fire-driven flow - contains a chapter on CFD (Computational Fluid Dynamics), the increasingly popular calculation method in the field of fire safety science

In this thesis Johanna Bruckner reports the discovery of the lyotropic counterpart of the thermotropic SmC* phase, which has become famous as the only spontaneously polarized, ferroelectric fluid in nature. By means of polarizing optical microscopy, X-ray diffraction and electro-optic experiments she firmly establishes aspects of the structure of the novel lyotropic liquid crystalline phase and elucidates its fascinating properties, among them a pronounced polar electro-optic effect, analogous to the ferroelectric switching of its thermotropic counterpart. The helical ground state of the mesophase raises the fundamental question of how chiral interactions are "communicated" across layers of more or less disordered and achiral solvent molecules which are located between adjacent bi-layers of the chiral amphiphile molecules. This thesis bridges an important gap between thermotropic and lyotropic liquid crystals and pioneers a new field of liquid crystal research.

This book introduces the fascinating world of self-assembly in mesoporous ordered silica films. Beginning from a single droplet, it guides the reader, in a step-by-step learning process, how to obtain and control ordered porous mesophases in thin films by varying only the precursor chemistry and the process. It explains, in great detail, how order control is achieved through chemical design and post-deposition processing, the latter of which is a unique property in materials science. The book places a special focus on silica, whose particularly complex chemistry enables order control over a range of different length scales. This book is suitable for students and researchers in the fields of sol-gel or colloidal chemistry and interested in the topics of self-assembly and mesoporous phases.

Physicists are pondering on the possibility of simulating black holes in the laboratory by means of various "analog models". These analog models, typically based on condensed matter physics, can be used to help us understand general relativity (Einstein's gravity); conversely, abstract techniques developed in general relativity can sometimes be used to help us understand certain aspects of condensed matter physics. This book contains 13 chapters - written by experts in general relativity, particle physics, and condensed matter physics - that explore various aspects of this two-way traffic.

The research in this book represents the culmination of a drive to build the first discharge gas laser unencumbered by the effects of diffraction. This breakthrough has been achieved through careful implementation of a discharge within a hollow-core optical fibre, and by developing measurement and analysis techniques to demonstrate laser action in an experimental optical cavity. Gas lasers were amongst the earliest laser types to be demonstrated and commercialised, but it was recognised that noble gas lasers were limited by the minimum bore diameter of the laser tube, which is set by diffraction. The advent, in 2011, of hollow optical fibres with optical and physical properties suitable for gas discharge lasers opened up the opportunity to break this diffraction limit. Using a mixture of helium and xenon gas, lasing in the mid-infrared range was achieved using a 100m core flexible hollow optical fibre which, at 1m long, is several hundred times the diffraction-limited Rayleigh length.

Features * Fully updated with the latest results from the spacecraft Hinode, Stereo, Solar Dynamics Observatory (SDO), Interface Region Imaging Spectrograph (IRIS), and Parker Solar Probe * Presents step-by-step explanations for calculating numerical models of the photosphere, convection zone, and radiative interior with exercises and simulation problems to test learning * Describes the structure of polytropic spheres and the acoustic power in the Sun and the process of thermal conduction in different physical conditions

This book discusses various aspects of graphene fictionalization strategies from inorganic oxides and organic moieties including preparation, design, and characterization of functionalization material and its applications. Including illustrations and tables summarizing the latest research on manufacturing, design, characterization and applications of graphene functionalization, it describes graphene functionalization using different techniques and materials and highlights the latest technologies in the field of manufacturing and design. This book is a valuable reference resource for lecturers, students, researchers and industrialists working in the field of material science, especially polymer composites.

Cold atmospheric plasma (CAP) generators have been actively developed as a new device for medical treatment. The applications of plasma treatment include 1) disinfection, sterilization, and decontamination, which inactivates or kills bacteria, fungi, viruses and spores; 2) bleeding control, which coagulates blood swiftly; 3) wound healing, which shortens the healing period and benefits the regeneration of the epithelization of tissue to avoid scar formation; etc.Biomedical applications of CAPs are explored via either in-vitro assays, or in-vivo tests using pigs as animal models; tests include sterilization of oral pathogens and biofilm, decontamination of biological warfare agent, blood clotting and rapid control of active life-threatening hemorrhage, and post-operative observation of wound healing after plasma treatment. The conventional approaches in each application are first introduced, then the advantages of plasma treatments are discussed and demonstrated by the test results. The mechanisms of CAPs' biocidal effect, blood clotting effect, and wound healing effect are presented and discussed.

This volume contains the third and fourth Poincare Seminar, both held in 2003. The third one is devoted to Bose-Einstein Condensation: it covers the physics of superfluid liquid helium as well as the recently discovered atomic Bose-Einstein condensates. Major experimental results are presented, together with relevant theoretical approaches and remaining open questions. The fourth one is devoted to Entropy, giving a comprehensive account of the history and various realizations of this concept, from thermodynamics to black holes, and includes theoretical and experimental discussions of the corresponding fluctuations for mesoscopic systems near equilibrium."

Liquid-crystalline phases are now known to be formed by an ever growing range of quite diverse materials, these include those of low molecular weight as well as the novel liquid-crystalline polymers, such phases can also be induced by the addition of a solvent to amphiphilic systems leading to lyotropic liquid crystals. Irrespective of the structure of the constituent molecules these numerous liquid-cl)'Stailine phases are characterised by their long range orientational order. In addition certain phases exhibit elements of long range positional order. Our understanding, both experimental and theoretical, at the molecular level of the static behaviour of these fascinating and important materials is now well advanced. In contrast the influence of the long range order; both orientational and positional, on the molecular dynamics in liquid Cl)'Stais is less well understood. In an attempt to address this situation a NATO Advanced Study Institute devoted to liquid ctystal dynamics was held at n Ciocco, Barga, Italy in September 1989. This brought together experimentalists and theoreticians concerned with the various dynamical processes occurring in all liquid crystals. The skills of the participants was impressively wide ranging; they spanned the experimental techniques used in the study of molecular dynamics, the nature of the systems investigated and the theoretical models employed to understand the results. While much was learnt it was also recognised that much more needed to be done in order to advance our understanding of molecular dynamics in liquid Cl)'Stais.

Surface Structure Modification and Hardening of Al-SI Alloys explores the hardening of material surfaces using concentrated energy flows resulting in the nanostructuring of surface layers. The authors demonstrate how these methods achieve a reduction in plastic deformation of the surface and a more uniform distribution of elastic stresses near the surface during operational use, significantly reducing part failure. It presents results from research and scientific and technological enterprises involved with the modification of light alloy surfaces for use in the automobile and aerospace industries. Additional key features include: Addresses theoretical and experimental research computer simulations of structural phase transformations at the nanolevel to create new materials Details and compares electroexplosion alloying, electron beam processing and electron-plasma alloying of an Al-Si Alloy Explains multiphase plasma jet treatment to obtain high-quality coatings with good and high functional properties This reference is a valuable resource for specialists in the field of physical material science, condensed state physics, metal science and thermal treatment and will be of interest to undergraduate and post-graduate students in these fields.

Scientists have long been looking for alternative methods for the cleaning of historical and cultural museum objects as conventional methods often fail to completely remove surface films, leaving contamination and surface residues behind. Low-temperature plasmas have recently been found to provide a new, efficient and durable approach that maintains the safety of both the materials and personnel. This book is the first to introduce the emerging use of low-temperature plasmas in the cleaning and decontamination of cultural heritage items. It provides a comprehensive exploration of the new possibilities of cleaning objects with plasma, before providing a practice guide to the individual cleaning methods and an overview of the technologies and conditions used in the different cleaning regimes. It is an ideal reference for researchers in plasma physics, in addition to professionals working in the field of historical and cultural conservation. Features: Provides a thorough overview of the cleaning potential of emerging plasma technologies in accessible language for professional restorers and conservators without a scientific background Includes the latest case studies from the field, which have not been published elsewhere yet Authored by a team of experts in the field About the Authors: Dr. Radko Tino is an Associate Professor at the Slovak University of Technology in Bratislava, Slovakia. Dr. Katarina Vizarova is an Associate Professor at the Slovak University of Technology in Bratislava, Slovakia. Dr. Frantisek Krcma is an Associate Professor at Brno University of Technology, Czech Republic. Dr. Milena Rehakova is an Associate Professor at the Slovak University of Technology in Bratislava, Slovakia. Dr. Viera Jancovicova is an Associate Professor at the Slovak University of Technology in Bratislava, Slovakia. Dr. Zdenka Kozakova is an Associate Professor at Brno University of Technology, Czech Republic.

Microcavities are semiconductor, metal, or dielectric structures providing optical confinement in one, two or three dimensions. At the end of the 20th century, microcavities have attracted attention due to the discovery of a strong exciton-light coupling regime allowing for the formation of superposition light-matter quasiparticles: exciton-polaritons. In the following century several remarkable effects have been discovered in microcavities, including the Bose-Einstein condensation of exciton-polaritons, polariton lasing, superfluidity, optical spin Hall and spin Meissner effects, amongst other discoveries. Currently, polariton devices exploiting the bosonic stimulation effects at room temperature are being developed by laboratories across the world. This book addresses the physics of microcavities: from classical to quantum optics, from a Boltzmann gas to a superfluid. It provides the theoretical background needed for understanding the complex phenomena in coupled light-matter systems, and it presents a broad overview of experimental progress in the physics of microcavities.