Nonlinear optical (NLO) phenomena such as frequency conversion have played a key role in the development of photonic technologies. This thesis reports a detailed study of the molecular response of a large variety of push-pull organic compounds using the Second Harmonic Generation technique, which will serve as a starting point for the investigation at the macroscopic scale of azobenzene-based liquid crystalline polymeric films and their blends with highly efficient NLO
chromophores. These materials are designed with the aim of exploiting their photoadressability in order to tailor their nonlinear behaviour. The magnitude and symmetry of their NL response was successfully controlled via light irradiation and thermal treatments. Moreover, as a specific application, the recording of efficient NLO gratings was achieved.

This book gives a representative survey of the state of the art of research on gas-surface interactions. It provides an overview of the current understanding of gas surface dynamics and, in particular, of the reactive and non-reactive processes of atoms and small molecules at surfaces. Leading scientists in the field, both from the theoretical and the experimental sides, write in this book about their most recent advances. Surface science grew as an interdisciplinary research area over the last decades, mostly because of new experimental technologies (ultra-high vacuum, for instance), as well as because of a novel paradigm, the 'surface science' approach. The book describes the second transformation which is now taking place pushed by the availability of powerful quantum-mechanical theoretical methods implemented numerically. In the book, experiment and theory progress hand in hand with an unprecedented degree of accuracy and control. The book presents how modern surface science targets the atomic-level understanding of physical and chemical processes at surfaces, with particular emphasis on dynamical aspects. This book is a reference in the field.

The book deals with the development of continual models of turbulent natural media. Such models serve as a ground for the statement and numerical evaluation of the key problems of the structure and evolution of the numerous astrophysical and geophysical objects. The processes of ordering (self-organization) in an originally chaotic turbulent medium are addressed and treated in detail with the use of irreversible thermodynamics and stochastic dynamics approaches which underlie the respective models. Different examples of ordering set up in the natural environment and outer space are brought and thoroughly discussed, the main focus being given to the protoplanetary discs formation and evolution.

Interesting and new specific results of current theoretical and experimental work in various fields at the frontier of particle scattering and X-ray diffraction are reviewed in this volume. Special emphasis is placed on the study of the microstructure of solids, crystals and liquids, both classically and quantum mechanically. This gives the reader essential insights into the dynamics and properties of these states of matter. The authors address students interested in the physics of quantum solids, crystallography and material science as well as physical chemistry and computational physics.

Micro/nano-mechanical systems are a crucial part of the modern world providing a plethora of sensing and actuation functionalities used in everything from the largest cargo ships to the smallest hand-held electronics; from the most advanced scientific and medical equipment to the simplest household items. Over the past few decades, the processes used to produce these devices have improved, supporting dramatic reductions in size, but there are fundamental limits to this trend that require a new production paradigm. The 2004 discovery of graphene ushered in a new era of condensed matter physics research, that of two-dimensional materials. Being only a few atomic layers thick, this new class of materials exhibit unprecedented mechanical strength and flexibility and can couple to electric, magnetic and optical signals. Additionally, they can be combined to form van der Waals heterostructures in an almost limitless number of ways. They are thus ideal candidates to reduce the size and extend the capabilities of traditional micro/nano-mechanical systems and are poised to redefine the technological sphere. This thesis attempts to develop the framework and protocols required to produce and characterise micro/nano-mechanical devices made from two-dimensional materials. Graphene and its insulating analogue, hexagonal boron nitride, are the most widely studied materials and their heterostructures are used as the test-bed for potential device architectures and capabilities. Interlayer friction, electro-mechanical actuation and surface reconstruction are some of the key phenomena investigated in this work.

This thesis unites the fields of optical atomic clocks and ultracold molecular science, laying the foundation for optical molecular measurements of unprecedented precision. Building upon optical manipulation techniques developed by the atomic clock community, this work delves into attaining surgical control of molecular quantum states. The thesis develops two experimental observables that one can measure with optical-lattice-trapped ultracold molecules: extremely narrow optical spectra, and angular distributions of photofragments that are ejected when the diatomic molecules are dissociated by laser light pulses. The former allows molecular spectroscopy approaching the level of atomic clocks, leading into molecular metrology and tests of fundamental physics. The latter opens the field of ultracold chemistry through observation of quantum effects such as matter-wave interference of photofragments and tunneling through reaction barriers. The thesis also describes a discovery of a new method of thermometry that can be used near absolute zero temperatures for particles lacking cycling transitions, solving a long-standing experimental problem in atomic and molecular physics.

The present set of lectures and tutorial reviews deals with various topical aspects related to instabilities of interfacial processes and driven flows from both the theoretical and experimental point of views. New research has been spurred by demands for many applications in material sciences (melting, solidification, electro deposition), biomedical engineering and processing in microgravity environments. This book is intended as both a modern source of reference for researchers in the field as well as an introduction to postgraduate students and non-specialists from related areas.

Fullerene Polymers and Fullerene Polymer Composites is an in-depth experimental and theoretical account of polymers and composites whose unusual properties, such as, photophysical phenomena, electrical transport, phase transitions and magnetic properties, stem from the incorporation of C60 in the material. Each chapter is written by an internationally renowned expert who has published extensively in this sub-field of fullerene materials. Introductory chapters on the fundamental properties of fullerenes (C60, C70) and photophysical phenomena in fullerenes and polymers are also included.

This book reviews the current state-of-the art of single layer silicene up to thicker silicon nanosheets, and their structure, properties and potential applications. Silicene is a newly discovered material that is one atomic layer think. It is a two-dimensional (2D) nanomaterial that is classified as a nanosheet, which has large lateral dimensions up to micrometres, but thicknesses of only nanometres or less. Silicon nanosheets are currently a very 'hot' area of research. The unique properties and morphology of such materials make them ideal for a variety of applications, including electronic devices, batteries and sensors. 2D nanosheets of silicon can be considered as analogues of graphene. As silicon is already the major component of electronic devices, the significance of nanosheets composed of silicon is that they can be more easily integrated into existing electronic devices. Furthermore, if 2D nanostructured Si can be implemented into such devices, then their size could be reduced into the nano-regime, providing unique properties different from bulk Si that is currently employed. The book is written for researchers and graduate students.

A reference and text, Dissipative Phenomena treats the broadly applicable area of nonequilibrium statistical physics and concentrates the modelling and characterization of dissipative phenomena. A variety of examples from diverse disciplines, such as condensed matter physics, materials science, metallurgy, chemical physics, are discussed. Dattagupta employs a broad framework of stochastic processes and master equation techniques to obtain models for a range of experimentally relevant phenomena such as classical and quantum Brownian motion, spin dynamics, kinetics of phase ordering, relaxation in glasses, and dissipative tunnelling. This book will serve as a graduate/research level textbook since it offers considerable utility to experimentalists, computational physicists and theorists.

My intent in writing this book is to present an introduction to the thermo- chanical theory required to conduct research and pursue applications of shock physics in solid materials. Emphasis is on the range of moderate compression that can be produced by high-velocity impact or detonation of chemical exp- sives and in which elastoplastic responses are observed and simple equations of state are applicable. In the interest of simplicity, the presentation is restricted to plane waves producing uniaxial deformation. Although applications often - volve complex multidimensional deformation fields it is necessary to begin with the simpler case. This is also the most important case because it is the usual setting of experimental research. The presentation is also restricted to theories of material response that are simple enough to permit illustrative problems to be solved with minimal recourse to numerical analysis. The discussions are set in the context of established continuum-mechanical principles. I have endeavored to define the quantities encountered with some care and to provide equations in several convenient forms and in a way that lends itself to easy reference. Thermodynamic analysis plays an important role in continuum mechanics, and I have included a presentation of aspects of this subject that are particularly relevant to shock physics. The notation adopted is that conventional in expositions of modern continuum mechanics, insofar as possible, and variables are explained as they are encountered. Those experienced in shock physics may find some of the notation unconventional.

Written by leading experts in the field of band-ferromagnetism, this book is intended to give a status report on our understanding of this complicated and fascinating problem of solid state physics. Modern developments are presented and explained in a tutorial style, emphasizing the decisive ideas and the hot topics of current and future research on band-ferromagnetism. The authors include experimentalists and theoreticians working on different aspects of magnetism and employing a variety of techniques. In particular, they treat the following five central themes: Ground-State Properties, Finite-Temperature Electronic Structure, Models of Band-Ferromagnetism, Low-Dimensional Systems, Understanding Spectroscopies. The book will be of benefit to students and researchers alike.

The book summarizes recent international research and experimental developments regarding fatigue crack growth investigations of rubber materials. It shows the progress in fundamental as well as advanced research of fracture investigation of rubber material under fatigue loading conditions, especially from the experimental point of view. However, some chapters will describe the progress in numerical modeling and physical description of fracture mechanics and cavitation phenomena in rubbers. Initiation and propagation of cracks in rubber materials are dominant phenomena which determine the lifetime of these soft rubber materials and, as a consequence, the lifetime of the corresponding final rubber parts in various fields of application. Recently, these phenomena became of great scientific interest due to the development of new experimental methods, concepts and models. Furthermore, crack phenomena have an extraordinary impact on rubber wear and abrasion of automotive tires; and understanding of crack initiation and growth in rubbers will help to support the growthing number of activities and worldwide efforts of reduction of tire wear losses and abrasion based emissions.

Advanced materials are the basis of modern science and technology. This proceedings volume presents a broad spectrum of studies of novel materials covering their processing techniques, physics, mechanics, and applications. The book is concentrated on nanostructures, ferroelectric crystals, materials and composites, materials for solar cells and also polymeric composites. Nanotechnology approaches, modern piezoelectric techniques and also latest achievements in materials science, condensed matter physics, mechanics of deformable solids and numerical methods are presented. Great attention is devoted to novel devices with high accuracy, longevity and extended possibilities to work in wide temperature and pressure ranges, aggressive media etc. The characteristics of materials and composites with improved properties opening new possibilities of various physical processes, in particular transmission and receipt of signals under water, are described.

This book presents a comprehensive description of phonons and their interactions in systems with different dimensions and length scales. Internationally-recognized leaders describe theories and measurements of phonon interactions in relation to the design of materials with exotic properties such as metamaterials, nano-mechanical systems, next-generation electronic, photonic, and acoustic devices, energy harvesting, optical information storage, and applications of phonon lasers in a variety of fields.

The emergence of techniques for control of semiconductor properties and geometry has enabled engineers to design structures in which functionality is derived from controlling electron behavior. As manufacturing techniques have greatly expanded the list of available materials and the range of attainable length scales, similar opportunities now exist for designing devices whose functionality is derived from controlling phonon behavior. However, progress in this area is hampered by gaps in our knowledge of phonon transport across and along arbitrary interfaces, the scattering of phonons with crystal defects, interface roughness and mass-mixing, delocalized electrons/collective electronic excitations, and solid acoustic vibrations when these occur in structures with small physical dimensions. This book providesa comprehensive description of phonons and their interactions in systems with different dimensions and length scales. Theories and measurements of phonon interactions are described in relation to the design of materials with exotic properties such as metamaterials, nano-mechanical systems, next-generation electronic, photonic, and acoustic devices, energy harvesting, optical information storage, and applications of phonon lasers in a variety of fields."

This book presents a unified view of the physicochemical origin of the mechanical behaviour of gases, simple solids and liquids, suspensions, polymers, emulsions, foams, and granular materials, along with techniques for measuring that behaviour. Besides molecular materials in all their classical gaseous, solid, or liquid states, we deal daily with a number of other materials made of coarser elements such as polymers, cells, grains, bubbles, and droplets. They take on the familiar appearance of paints, inks, cements, muds, foams, emulsions, toothpastes, gels, etc. These materials exhibit complex structures and sometimes amazing types of mechanical behaviour, often intermediate between those of a simple liquid and a simple solid. From a practical standpoint, the aim is to analyze their internal evolution (aging, restructuring, phase separation, etc.), then to formulate these materials in accordance with the desired properties, and thereby devise new materials. With that aim in mind, it is crucial to understand how these materials deform or flow, depending on the interactions and structures formed by the elements they contain. This book is intended for students as well as more advanced researchers in mechanics, physics, chemistry, and biology. The mathematical formalism is reduced in order to focus on physical explanations.

This book provides the first complete and up-to-date summary of the state of the art in HAXPES and motivates readers to harness its powerful capabilities in their own research. The chapters are written by experts. They include historical work, modern instrumentation, theory and applications. This book spans from physics to chemistry and materials science and engineering. In consideration of the rapid development of the technique, several chapters include highlights illustrating future opportunities as well.

This book demonstrates how the new phenomena in superconductivity on the nanometer scale (FFLO state, triplet superconductivity, Crossed Andreev Reflection, synchronized generation etc.) serve as the basis for the invention and development of novel nanoelectronic devices and systems. It demonstrates how rather complex ideas and theoretical models, like odd-pairing, non-uniform superconducting state, pi-shift etc., adequately describe the processes in real superconducting nanostructues and novel devices based on them. The book is useful for a broad audience of readers, researchers, engineers, PhD-students, lectures and others who would like to gain knowledge in the frontiers of superconductivity at the nanoscale.

The book considers the main growth-related phenomena occurring during epitaxial growth, such as thermal etching, doping, segregation of the main elements and impurities, coexistence of several phases at the crystal surface and segregation-enhanced diffusion.
It is complete with tables, graphs and figures, which allow fast determination of suitable growth parameters for practical applications.

This book presents a comprehensive and unifying approach to analytical identification of material properties of biological materials. Focusing on depth-sensing indentation testing, pipette aspiration testing, and torsion of soft tissues, it discusses the following important aspects in detail: damping, adhesion, thickness effect, substrate effect, elastic inhomogeneity effect, and biphasic effect. This book is intended for advanced undergraduate and graduate students, researchers in the area of biomechanics as well as for biomedical engineers interested in contact problems and involved in inverse materials parameters prediction analysis.

Ion implantation is one of the key processing steps in silicon integrated circuit technology. Some integrated circuits require up to 17 implantation steps and circuits are seldom processed with less than 10 implantation steps. Controlled doping at controlled depths is an essential feature of implantation. Ion beam processing can also be used to improve corrosion resistance, to harden surfaces, to reduce wear and, in general, to improve materials properties. This book presents the physics and materials science of ion implantation and ion beam modification of materials. It covers ion-solid interactions used to predict ion ranges, ion straggling and lattice disorder. Also treated are shallow-junction formation and slicing silicon with hydrogen ion beams. Topics important for materials modification topics, such as ion-beam mixing, stresses, and sputtering, are also described.

Quasielastic neutron scattering has made many important contributions to the atomistic elucidation of diffusion processes in solids. The aim of this book is to inform researchers in solid state physics, solid state chemistry, and inorganic materials science of the potential of quasielastic neutron scattering. The book has been written for experimentalists and contains in its first part the theoretical background on neutrons, neutron scattering, and solid state diffusion, which is essential for the proper use of quasielastic neutron scattering. This general part should be useful for non-experts in the field of neutron scattering and diffusion as well. The second part of the book addresses the experts in this vivid field of research. It summarizes the scientific applications of quasielastic neutron scattering to special solid state materials systems, as for example to hydrogen in metals or to diffusion in solid state ionic conductors.

This book gives an account of state-of-the-art investigations of properties and processes at solid-liquid interfaces with the same precision as it is standard in ultrahigh vacuum based surface science. Using combinations of in-situ and ex-situ experimental methods fundamental and relevant phenomena such as adsorption and desorption of ions and molecules, restructuring of surfaces, thin film and nanocluster growth, and electrochemical reactions on the micrometer scale are addressed. The overview includes a wide range of experimental techniques and examples of solid-liquid interfaces and aims at stimulating an expansion of this type of important Interface Science.

Experiments since 1911 prove that the distance between nuclear particles constituting atomic bodies is a hundred thousand times larger than the diameters of these particles. Hence the volumes of all atomic bodies including ourselves are space-like empty, a hundred times more empty than the volume of the solar system. Scores of experiments also prove that space contains electrons and positrons bound to each other by energies of a million electron volts per pair, and form a cubic lattice, named the epola.Based on the epola model of space, this book reveals the physical nature of inertia, gravitation, the spreading of electromagnetic and gravitational actions in space with the velocity of light, and derives their laws. The postulates of quantum and relativity theories are also derived and turned into explainable physical laws. Thus physics is restored as the natural science it had been before it was turned into a science of axiomatic statements and calculations.The book will appeal both to serious scientists and students as well as the general reader interested in scientific explanations of the physical world. Since as a natural science physics deals with the simplest and most basic natural phenomena, this book will be as accessible to the general public as biology books.

Lithium niobate, LiNbO , is an oxide ferroelectric with various kinds of pro- 3 nouncedphysicalproperties. Thisversatilityhaspromoteditscareerinscience anddevices. Ithasbeenparticularlyfruitfulintheopticalregime,wheremany e?ects have been found in LiNbO and devices introduced using it as a host. 3 One of the few big drawbacks, namely the low level laser damage threshold based on photorefraction due to extrinsic defects was discovered very early. A relatively new topic, not involved so far in any general description, is a fundamental dependence of the optical properties of LiNbO on intrinsic de- 3 fects. Their importance has been realised out due to the development of varies growthtechniquesintherecentpast. Theprogressinthegrowthandstudiesof LiNbO crystals with di?erent composition, particularly almost stoichiomet- 3 ric ones, has revealed a signi?cant and sometimes decisive role of the intrinsic defects. For example, the photoinduced charge transport, and therefore the photorefractive properties governing the recording of the phase gratings in LiNbO , are strongly controlled by the content of intrinsic defects. The re- 3 cently found impact of intrinsic defects on the coercive ?eld in LiNbO is 3 of fundamental importance for the creation of periodically poled structures (PPLN) aimed at the optical-frequency conversion in the quasi-phase mat- ing (QPM) mode of operation. As a consequence of these results, an idea of the intrinsic defects in LiNbO has been developed during the last decade 3 and involves microscopic studies on defects, photorefraction and ferroelectric switching using spectroscopic and structure methods.