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Books > Science & Mathematics > Physics > Thermodynamics & statistical physics > Statistical physics
About half a century ago Landau formulated the central principles of the phe nomenological second-order phase transition theory which is based on the idea of spontaneous symmetry breaking at phase transition. By means of this ap proach it has been possible to treat phase transitions of different nature in altogether distinct systems from a unified viewpoint, to embrace the aforemen tioned transitions by a unified body of mathematics and to show that, in a certain sense, physical systems in the vicinity of second-order phase transitions exhibit universal behavior. For several decades the Landau method has been extensively used to an alyze specific phase transitions in systems and has been providing a basis for interpreting experimental data on the behavior of physical characteristics near the phase transition, including the behavior of these characteristics in systems subject to various external effects such as pressure, electric and magnetic fields, deformation, etc. The symmetry aspects of Landau's theory are perhaps most effective in analyzing phase transitions in crystals because the relevant body of mathemat ics for this symmetry, namely, the crystal space group representation, has been worked out in great detail. Since particular phase transitions in crystals often call for a subtle symmetry analysis, the Landau method has been continually refined and developed over the past ten or fifteen years."
In recent years, due primarily to the proliferation of computers, dynamical systems has again returned to its roots in applications. It is the aim of this book to provide undergraduate and beginning graduate students in mathematics or science and engineering with a modest foundation of knowledge. Equations in dimensions one and two constitute the majority of the text, and in particular it is demonstrated that the basic notion of stability and bifurcations of vector fields are easily explained for scalar autonomous equations. Further, the authors investigate the dynamics of planar autonomous equations where new dynamical behavior, such as periodic and homoclinic orbits appears.
One service mathematics has rc: ndered the 'Et moi, "', si j'avait su comment CD revenir, je n'y serais point alle. ' human race. It has put common SCIIJC back Jules Verne where it belongs. on the topmost shelf next to tbe dusty canister 1abdled 'discarded non- The series is divergent; tberefore we may be sense'. able to do sometbing witb it Eric T. Bell O. Heaviside Mathematics is a tool for thought. A highly necessary tool in a world where both feedback and non linearities abound. Similarly, all kinds of parts of mathematics serve as tools for other parts and for other sciences. Applying a simple rewriting rule to the quote on the right above one finds such statements as: 'One service topology has rendered mathematical physics . . . '; 'One service logic has rendered com puter science . . . '; 'One service category theory has rendered mathematics . . . '. All arguably true_ And all statements obtainable this way form part of the raison d'etre of this series_ This series, Mathematics and Its ApplicatiOns, started in 1977. Now that over one hundred volumes have appeared it seems opportune to reexamine its scope_ At the time I wrote "Growing specialization and diversification have brought a host of monographs and textbooks on increasingly specialized topics. However, the 'tree' of knowledge of mathematics and related fields does not grow only by putting forth new branches."
One of the ultimate goals of materials research is to develop a fun damental and predictive understanding of the physical and metallurgical properties of metals and alloys. Such an understanding can then be used in the design of materials having novel properties or combinations of proper ties designed to meet specific engineering applications. The development of new and useful alloy systems and the elucidation of their properties are the domain of metallurgy. Traditionally, the search for new alloy systems has been conducted largely on a trial and error basis, guided by the skill and intuition of the metallurgist, large volumes of experimental data, the principles of 19th century thermodynamics and ad hoc semi-phenomenological models. Recently, the situation has begun to change. For the first time, it is possible to understand the underlying mechanisms that control the formation of alloys and determine their properties. Today theory can begin to offer guidance in predicting the properties of alloys and in developing new alloy systems. Historically, attempts directed toward understanding phase stability and phase transitions have proceeded along distinct and seemingly diverse lines. Roughly, we can divide these approaches into the following broad categories. 1. Experimental determination of phase diagrams and related properties, 2. Thermodynamic/statistical mechanical approaches based on semi phenomenological models, and 3. Ab initio quantum mechanical methods. Metallurgists have traditionally concentrated their efforts in cate gories 1 and 2, while theoretical physicists have been preoccupied with 2 and 3."
This book introduces 'functional networks', a novel neural-based paradigm, and shows that functional network architectures can be efficiently applied to solve many interesting practical problems. Included is an introduction to neural networks, a description of functional networks, examples of applications, and computer programs in Mathematica and Java languages implementing the various algorithms and methodologies. Special emphasis is given to applications in several areas such as: * Box-Jenkins AR(p), MA(q), ARMA(p, q), and ARIMA (p, d, q) models with application to real-life economic problems such as the consumer price index, electric power consumption and international airlines' passenger data. Random time series and chaotic series are considered in relation to the Henon, Lozi, Holmes and Burger maps, as well as the problems of noise reduction and information masking. * Learning differential equations from data and deriving the corresponding equivalent difference and functional equations. Examples of a mass supported by two springs and a viscous damper or dashpot, and a loaded beam, are used to illustrate the concepts.* The problem of obtaining the most general family of implicit, explicit and parametric surfaces as used in Computer Aided Design (CAD). * Applications of functional networks to obtain general nonlinear regression models are given and compared with standard techniques. Functional Networks with Applications: A Neural-Based Paradigm will be of interest to individuals who work in computer science, physics, engineering, applied mathematics, statistics, economics, and other neural networks and data analysis related fiel
The idea for this book was conceived by the authors some time in 1988, and a first outline of the manuscript was drawn up during a summer school on mathematical physics held in Ravello in September 1988, where all three of us were present as lecturers or organizers. The project was in some sense inherited from our friend Marvin Shinbrot, who had planned a book about recent progress for the Boltzmann equation, but, due to his untimely death in 1987, never got to do it. When we drew up the first outline, we could not anticipate how long the actual writing would stretch out. Our ambitions were high: We wanted to cover the modern mathematical theory of the Boltzmann equation, with rigorous proofs, in a complete and readable volume. As the years progressed, we withdrew to some degree from this first ambition- there was just too much material, too scattered, sometimes incomplete, sometimes not rigor ous enough. However, in the writing process itself, the need for the book became ever more apparent. The last twenty years have seen an amazing number of significant results in the field, many of them published in incom plete form, sometimes in obscure places, and sometimes without technical details. We made it our objective to collect these results, classify them, and present them as best we could. The choice of topics remains, of course, subjective.
... "What do you call work?" "Why ain't that work?" Tom resumed his whitewashing, and answered carelessly: "Well. lI1a), he it is, and maybe it aill't. All I know, is, it suits Tom Sawvc/: " "Oil CO/lll , IIOW, Will do not mean to let 011 that you like it?" The brush continued to move. "Likc it? Well, I do not see wlzy I oughtn't to like it. Does a hoy get a chance to whitewash a fence every day?" That put the thing ill a Ilew light. Ben stopped nibhling the apple .... (From Mark Twain's Adventures of Tom Sawyer, Chapter II.) Mathematics can put quantitative phenomena in a new light; in turn applications may provide a vivid support for mathematical concepts. This volume illustrates some aspects of the mathematical treatment of phase transitions, namely, the classical Stefan problem and its generalizations. The in tended reader is a researcher in application-oriented mathematics. An effort has been made to make a part of the book accessible to beginners, as well as physicists and engineers with a mathematical background. Some room has also been devoted to illustrate analytical tools. This volume deals with research I initiated when I was affiliated with the Istituto di Analisi Numerica del C.N.R. in Pavia, and then continued at the Dipartimento di Matematica dell'Universita di Trento. It was typeset by the author in plain TEX."
We present here a selection of the seminars given at the Second International Workshop on Instabilities and Nonequilibrium Structures in Valparaiso, Chile, in December 1987. The Workshop was organized by Facultad de Ciencias Fisicas y Matematicas of Universidad de Chile and by Universidad Tecnica Federico Santa Maria where it took place. This periodic meeting takes place every two years in Chile and aims to contribute to the efforts of Latin America towards the development of scientific research. This development is certainly a necessary condition for progress in our countries and we thank our lecturers for their warm collaboration to fulfill this need. We are also very much indebted to the Chilean Academy of Sciences for sponsoring officially this Workshop. We thank also our sponsors and supporters for their valuable help, and most especially the Scientific Cooperation Program of France, UNESCO, Ministerio de Educaci6n of Chile and Fundaci6n Andes. We are grateful to Professor Michiel Hazewinkel for including this book in his series and to Dr. David Larner of Kluwer for his continuous interest and support to this project.
This book contains the lectures and a selection of the seminars gi ven in the Fifth International Workshop on Instabilities and Nonequilibrium Structures which took place in Santiago, Chile, in December 1993. The Workshop was organized by Facultad de Ciencias Fisicas y Matematicas, Universidad de Chile, Instituto de Fisica of Universidad Cat6lica de Valparaiso and Centro de Fisica No Lineal y Sistemas Complejos de Santiago. This volume is the first of a new series of Kluwer on Nonlinear Phenomena and Complex Systems which will be edited by the Centro de Fisica No Lineal y Sistemas Complejos de Santiago. We thank Dr. David Lamer of Kluwer for his encouragements and support for this project. ix LIST OF SPONSORS OF THE WORKSHOP * Academia Chilena de Ciencias * Facultad de Ciencias Fisicas y Mathematicas de la Univ. de Chile * Instituto de Fisica de la Univ. Cat6lica de Valparaiso * Centro de FIsica No Lineal y Sistemas Complejos de Santiago (CFNL) * CONICYT (Chile) * Ministere Francais des Affaires Etrangeres * International Centre for Theoretical Physics (Trieste) * UNESCO * Fundaci6n Andes (Chile) * Departamento Tecnico de Investigaci6n y de Relaciones Internationa- cion ales de la Universidad de Chile * IDIEM (Fac. Cs. FIs. y Mat., Univ. de Chile) * CHILGENER S.A.
In the decades the of the formation of structures past subject spontaneous in far from has into a branch of - systems equilibrium major physics grown search with ties to It has become evident that strong neighboring disciplines. a diverse of can be understood within a common mat- phenomena range matical framework which has been called nonlinear of continuous dynamics This name the close to the field of nonlinear systems. emphasizes relationship of with few of freedom which has evolved into a dynamics systems degrees mature in the recent features mathematically subject past. Many dynamical of continuous be described reduction few can a to a systems actually through of freedom and of the latter of continue to degrees properties type systems of continuous the inspire study systems. The of this book is to demonstrate the numerous goal through examples that exist for the of nonlinear the opportunities study phenomena through tools of mathematical and use of common analyses dynamical interpretations. Instead of overview of the a providing comprehensive rapidly evolving field, the contributors to this book are to communicate to a wide scientific trying audience the of what have learnt about the formation of essence they spon- neous structures in continuous and about the dissipative systems competition between order and chaos that characterizes these It is that systems. hoped the book will be even to those scientists whose not helpful are disciplines the authors.
New developments in laser technology and theoretical modeling has allowed physicists to control chemical reactions using lasers and to attain an understanding of the underlying photochemical reaction mechanism. The book gives an up-to-date presentation of this research area, covering time-resolved spectroscopy and the dynamical behavior of electronically excited states.
In recent years there has been a growth in interest in studying the heart from the perspective of the physical sciences: mechanics, fluid flow, electromechanics. This volume is the result of a workshop held in July 1989 at the Institute for Nonlinear Sciences at the University of California at San Diego that brought together scientists and clinicians with graduate students and postdoctoral fellows who shared an interest in the heart. The chapters were prepared by the invited speakers as didactic reviews of their subjects but also include the structure, mechanical properties, and function of the heart and the myocardium, electrical activity of the heart and myocardium, and mathematical models of heart function.
The essays in this topical volume inquire into one of the most fundamental issues of philosophy and of the cognitive and natural sciences: the riddle of time. The central feature is the tension between the experience and the conceptualization of time, reflecting an apparently unavoidable antinomy of subjective first-person accounts and objective traditional science. Is time based in the physics of inanimate matter, or does it originate in the operation of our minds? Is it essential for the constitution of reality, or is it just an illusion? Issues of time, temporality, and nowness are paradigms for interdisciplinary work in many contemporary fields of research. The authors of this volume discuss profoundly the mutual relationships and inspiring perspectives. They address a general audience.
Statistical mechanics deals with systems in which chaos and randomness reign supreme. The current theory is therefore firmly based on the equations of classical mechanics and the postulates of probability theory. This volume seeks to present a unified account of classical mechanical statistics, rather than a collection of unconnected reviews on recent results. To help achieve this, one element is emphasised which integrates various parts of the prevailing theory into a coherent whole. This is the hierarchy of the BBGKY equations, which enables a relationship to be established between the Gibbs theory, the liquid theory, and the theory of nonequilibrium phenomena. As the main focus is on the complex theoretical subject matter, attention to applications is kept to a minimum. The book is divided into three parts. The first part describes the fundamentals of the theory, embracing chaos in dynamic systems and distribution functions of dynamic systems. Thermodynamic equilibrium, dealing with Gibbs statistical mechanics and the statistical mechanics of liquids, forms the second part. Lastly, the third part concentrates on kinetics, and the theory of nonequilibrium gases and liquids in particular. Audience: This book will be of interest to graduate students and researchers whose work involves thermophysics, theory of surface phenomena, theory of chemical reactions, physical chemistry and biophysics.
The volume that you have before you is the result of a growing realization that fluctuations in nonequilibrium systems playa much more important role than was 1 first believed. It has become clear that in nonequilibrium systems noise plays an active, one might even say a creative, role in processes involving self-organization, pattern formation, and coherence, as well as in biological information processing, energy transduction, and functionality. Now is not the time for a comprehensive summary of these new ideas, and I am certainly not the person to attempt such a thing. Rather, this short introductory essay (and the book as a whole) is an attempt to describe where we are at present and how the viewpoint that has evolved in the last decade or so differs from those of past decades. Fluctuations arise either because of the coupling of a particular system to an ex ternal unknown or "unknowable" system or because the particular description we are using is only a coarse-grained description which on some level is an approxima tion. We describe the unpredictable and random deviations from our deterministic equations of motion as noise or fluctuations. A nonequilibrium system is one in which there is a net flow of energy. There are, as I see it, four basic levels of sophistication, or paradigms, con cerning fluctuations in nature. At the lowest level of sophistication, there is an implicit assumption that noise is negligible: the deterministic paradigm."
"Granular Gases" are diluted many-particle systems in which the mean free path of the particles is much larger than the typical particle size, and where particle collisions occur dissipatively. The dissipation of kinetic energy can lead to effects such as the formation of clusters, anomalous diffusion and characteristic shock waves to name but a few. The book is organized as follows: Part I comprises the rigorous theoretical results for the dilute limit. The detailed properties of binary collisions are described in Part II. Part III contains experimental investigations of granular gases. Large-scale behaviour as found in astrophysical systems is discussed in Part IV. Part V, finally, deals with possible generalizations for dense granular systems.
This book presents a rational scheme of analysis for the periodic and quasi-periodic solution of a broad class of problems within technical and celestial mechanics. It develops steps for the determination of sufficiently general averaged equations of motion, which have a clear physical interpretation and are valid for a broad class of weak-interaction problems in mechanics. The criteria of stability regarding stationary solutions of these equations are derived explicitly and correspond to the extremum of a special "potential" function. Much consideration is given to applications in vibrational technology, electrical engineering and quantum mechanics, and a number of results are presented that are immediately useful in engineering practice. The book is intended for mechanical engineers, physicists, as well as applied mathematicians specializing in the field of ordinary differential equations.
Fractal analysis research is expanding into a variety of engineering domains. The strong potential of this work is now beginning to be seen in important applications in real industrial situations. Recent research progress has already led to new developments in domains such as signal processing and chemical engineering, and the major advances in fractal theory that underlie such developments are detailed here. New domains of applications are also presented, among them environmental science and rough surface analysis. Sections include multifractal analysis, iterated function systems, random processes, network traffic analysis, fractals and waves, image compression, and applications in physics. Fractals in Engineering emphasizes the connection between fractal analysis research and applications to industry. It is an important volume that illustrates the scientific and industrial value of this exciting field.
Oaxaca, Mexico, was the place chosen by a large international group of scientists to meet and discuss on the recent advances on the understanding of the physical prop- ties of low dimensional systems; one of the most active fields of research in condensed matter in the last years. The International Symposium on the Physics of Low Dim- sions took place in January 16-20, 2000. The group of scientists converging into the historical city of Oaxaca, in the state of the same name, had come from Argentina, Chile, Venezuela, several places in Mexico, Canada, U. S. A. , England, France, Italy, Germany, Russia, and Switzerland. The presentations at the workshop provided sta- of-art reviews of many of the most important problems, currently under study. Equally important to all the participants in the workshop was the fact that we had come to honor a friend, Hans Christoph Siegmann, on his sixty-fifth birthday. This Festschrift recognizes the intellectual leadership of Professor Siegmann in the field and as a sincere homage to his qualities as an exceptional friend, college and mentor. Those who have had the privilege to work closely with Hans Christoph have been deeply impressed by his remarkable analytic mind as well as by his out of range kindness and generosity. Hans Christoph has contributed to the understanding of the difficult and very important problem of the magnetic properties of finite systems: surfaces, thin films, heterostructures.
A central study in Probability Theory is the behavior of fluctuation phenomena of partial sums of different types of random variable. One of the most useful concepts for this purpose is that of the random walk which has applications in many areas, particularly in statistical physics and statistical chemistry. Originally published in 1991, "Intersections of Random Walks" focuses on and explores a number of problems dealing primarily with the nonintersection of random walks and the self-avoiding walk. Many of these problems arise in studying statistical physics and other critical phenomena. Topics include: discrete harmonic measure, including an introduction to diffusion limited aggregation (DLA); the probability that independent random walks do not intersect; and properties of walks without self-intersections. The presentsoftcover reprint includes corrections andaddenda fromthe1996 printing, andmakesthis classic monographavailable to a wider audience. With a self-contained introduction to the properties of simple random walks, and an emphasis on rigorous results, the book will be useful to researchers in probability and statistical physics and to graduate students interested in basic properties of random walks."
Supersymmetry was created by the physicists in the 1970's to give a unified treatment of fermions and bosons, the basic constituents of matter. Since then its mathematical structure has been recognized as that of a new development in geometry, and mathematicians have busied themselves with exploring this aspect. This volume collects recent advances in this field, both from a physical and a mathematical point of view, with an accent on a rigorous treatment of the various questions raised.
Jerry Marsden, one of the world's pre-eminent mechanicians and applied mathematicians, celebrated his 60th birthday in August 2002. The event was marked by a workshop on "Geometry, Mechanics, and Dynamics"at the Fields Institute for Research in the Mathematical Sciences, of which he wasthefoundingDirector. Ratherthanmerelyproduceaconventionalp- ceedings, with relatively brief accounts of research and technical advances presented at the meeting, we wished to acknowledge Jerry's in?uence as a teacher, a propagator of new ideas, and a mentor of young talent. Con- quently, starting in 1999, we sought to collect articles that might be used as entry points by students interested in ?elds that have been shaped by Jerry's work. At the same time we hoped to give experts engrossed in their own technical niches an indication of the wonderful breadth and depth of their subjects as a whole. This book is an outcome of the e?orts of those who accepted our in- tations to contribute. It presents both survey and research articles in the several ?elds that represent the main themes of Jerry's work, including elasticity and analysis, ?uid mechanics, dynamical systems theory, g- metric mechanics, geometric control theory, and relativity and quantum mechanics. The common thread running through this broad tapestry is the use of geometric methods that serve to unify diverse disciplines and bring a widevarietyofscientistsandmathematicianstogether, speakingalanguage which enhances dialogue and encourages cross-fertilization.
Over the years enormous effort was invested in proving ergodicity, but for a number of reasons, con?dence in the fruitfulness of this approach has waned. - Y. Ben-Menahem and I. Pitowsky [1] Abstract The basic motivation behind the present text is threefold: To give a new explanation for the emergence of thermodynamics, to investigate the interplay between quantum mechanics and thermodynamics, and to explore possible ext- sions of the common validity range of thermodynamics. Originally, thermodynamics has been a purely phenomenological science. Early s- entists (Galileo, Santorio, Celsius, Fahrenheit) tried to give de?nitions for quantities which were intuitively obvious to the observer, like pressure or temperature, and studied their interconnections. The idea that these phenomena might be linked to other ?elds of physics, like classical mechanics, e.g., was not common in those days. Such a connection was basically introduced when Joule calculated the heat equ- alent in 1840 showing that heat was a form of energy, just like kinetic or potential energy in the theory of mechanics. At the end of the 19th century, when the atomic theory became popular, researchers began to think of a gas as a huge amount of bouncing balls inside a box.
Schafer gives a concise overview of the static equilibrium properties of polymer solutions. In the first part diagrammatic perturbation theory is derived from scratch. The second part illustrates the basic ideas of the renormalization group (RG). The crucial role of dilation invariance is stressed. The more efficient method of dimensional regularization and minimal subtractions is worked out in part three. The fourth part contains a unified evaluation of the theory to the one loop level. All the important experimental quantities are discussed in detail, and the results are compared extensively to experiment. Empirical methods of data analysis are critically discussed. The final (fifth) part is devoted to extensions of theory. The first three parts of this book may serve as the basis of a course. Parts four and five are hoped to be useful for detailed quantitative evaluations of experiments. |
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