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Books > Professional & Technical > Mechanical engineering & materials > Materials science > Testing of materials

Sustainable Composites for Aerospace Applications (Paperback): Mohammad Jawaid, Mohamed Thariq Sustainable Composites for Aerospace Applications (Paperback)
Mohammad Jawaid, Mohamed Thariq
R5,512 R5,100 Discovery Miles 51 000 Save R412 (7%) Ships in 12 - 19 working days

Sustainable Composites for Aerospace Applications presents innovative advances in the fabrication, characterization and applications of LDH polymer nanocomposites. It covers fundamental structural and chemical knowledge and explores various properties and characterization techniques, including microscopic, spectroscopic and mechanical behaviors. Users will find a strong focus on the potential applications of LDH polymer nanocomposites, such as in energy, electronics, electromagnetic shielding, biomedical, agricultural, food packaging and water purification functions. This book provides comprehensive coverage of cutting-edge research in the field of LDH polymer nanocomposites and future applications, and is an essential read for all academics, researchers, engineers and students working in this area.

Non-Destructive Evaluation (NDE) of Polymer Matrix Composites (Hardcover, New): V. M. Karbhari Non-Destructive Evaluation (NDE) of Polymer Matrix Composites (Hardcover, New)
V. M. Karbhari
R5,934 Discovery Miles 59 340 Ships in 12 - 19 working days

The increased use of polymer matrix composites in structural applications has led to the growing need for a very high level of quality control and testing of products to ensure and monitor performance over time. Non-destructive evaluation (NDE) of polymer matrix composites explores a range of NDE techniques and the use of these techniques in a variety of application areas.
Part one provides an overview of a range of NDE and NDT techniques including eddy current testing, shearography, ultrasonics, acoustic emission, and dielectrics. Part two highlights the use of NDE techniques for adhesively bonded applications. Part three focuses on NDE techniques for aerospace applications including the evaluation of aerospace composites for impact damage and flaw characterisation. Finally, the use of traditional and emerging NDE techniques in civil and marine applications is explored in part four.
With its distinguished editor and international team of expert contributors, Non-destructive evaluation (NDE) of polymer matrix composites is a technical resource for researchers and engineers using polymer matrix composites, professionals requiring an understanding of non-destructive evaluation techniques, and academics interested in this field.
Explores a range of NDE and NDT techniques and considers future trendsExamines in detail NDE techniques for adhesively bonded applicationsDiscusses NDE techniques in aerospace applications including detecting impact damage, ultrasonic techniques and structural health monitoring

Fatigue in Composites - Science and Technology of the Fatigue Response of Fibre-Reinforced Plastics (Hardcover, illustrated... Fatigue in Composites - Science and Technology of the Fatigue Response of Fibre-Reinforced Plastics (Hardcover, illustrated edition)
Bryan Harris
R6,735 Discovery Miles 67 350 Ships in 12 - 19 working days

This major handbook is the first authoritative survey of current knowledge of fatigue behaviour of composites. It deals in detail with a wide range of problems met by designers in the automotive, marine and structural engineering industries. Compiled from the contributions of some of the best-known researchers in the field, it provides an invaluable, practical and encyclopaedic handbook covering recent developments.
Comprehensively discusses the problems of fatigue in composites met by designers in the aerospace, marine and structural engineering industriesProvides a general introduction on fatigue in composites before reviewing current research on micromechanical aspectsAnalyses various types of composites with respect to fatigue behaviour and testing and provides in-depth coverage of life-prediction models for constant variable stresses

Physical Testing of Textiles (Hardcover, illustrated edition): B.P. Saville Physical Testing of Textiles (Hardcover, illustrated edition)
B.P. Saville
R4,762 Discovery Miles 47 620 Ships in 12 - 19 working days

This book examines the physical testing of textiles in the form of fibre, yarn and fabric, the emphasis throughout eing on standard and reproducible tests. After an introductory explanation of sampling and measurement, the author explores the effects of moisture on textiles, then goes on to discuss fibre dimension, yarn tests for linear density, twist, evenness and hairiness, tensile strength, and dimensional stability and serviceability. Also covered are aspects of comfort and fabric handle, colour fastness and quality assurance. The book's comprehensive coverage of the physical properties of textiles makes it an essential reference for managers in the textiles industry concerned with quality assurance, garment and fabric technologists, and students of textile science and engineering.

Ultra High Temperature Mechanical Testing (Hardcover): Ultra High Temperature Mechanical Testing (Hardcover)
R3,990 Discovery Miles 39 900 Ships in 12 - 19 working days

The research and development of advanced materials for high-temperature applications requires special test methods, procedures and equipment. This recent book presents in-depth information on the subject prepared by leading high-temperature materials testing specialists from Europe, Japan and the U.S. The 18 illustrated reports cover key topics in the areas of equipment, theory, test design, test specimens, procedures, applications and test results interpretation and utility. A wealth of test data is included for various materials. The primary focus is on ceramic matrix composite materials. Other materials applications include intermetallics, refractories, and monolithic materials. The text includes numerous diagrams, flow charts and photographs which illustrate equipment, procedures and test specimens. The many tables and graphs provide test results and properties data for a variety of high temperature materials.

Nickel and Chromium Plating (Hardcover, 3rd edition): J. Dennis, T.E. Such Nickel and Chromium Plating (Hardcover, 3rd edition)
J. Dennis, T.E. Such
R5,036 Discovery Miles 50 360 Ships in 12 - 19 working days

During the last decade the engineering applications for nickel and chromium coatings have gained in importance. In this third edition the chapter dealing with engineering applications has been updated and expanded to include more information on electroforming and composite coatings, and engineering applications have been emphasized in the additions to the chapter on autocatalytic deposition of nickel. Additions have been made to the sections on pulse plating and use or rotating cathodes, and the section on trivalent chromium has been extended.

The Wear Debris Analysis Handbook (Hardcover): Trevor M. Hunt, Brian J. Roylance The Wear Debris Analysis Handbook (Hardcover)
Trevor M. Hunt, Brian J. Roylance
R1,614 Discovery Miles 16 140 Ships in 12 - 19 working days

An ideal - and affordable - text for engineers and maintenance professionals with an interest in vibration monitoring. This title does not attempt to baffle with the technology, but introduces it at an understandable level, touching on the basic theory and concepts, available equipment and practical issues relevant to the engineer as well as highlighting several case studies with which the reader can relate. Other books in this series focus on corrosion, vibration, thermography, noise, ultrasonics and acoustic emission, level, leakage and flow, oil analysis, load monitoring and a superb Concise Encyclopaedia that includes introductory notes on all of the above techiques as well as others.

Unsaturated Polyester Resins - Fundamentals, Design, Fabrication, and Applications (Paperback): Sabu Thomas, Mahesh Hosur,... Unsaturated Polyester Resins - Fundamentals, Design, Fabrication, and Applications (Paperback)
Sabu Thomas, Mahesh Hosur, Cintil Jose Chirayil
R5,912 Discovery Miles 59 120 Ships in 12 - 19 working days

Unsaturated Polyester Resins: Fundamentals, Design, Fabrication, and Applications explains the preparation, techniques and applications relating to the use of unsaturated polyester resin systems for blends, interpenetrating polymer networks (IPNs), gels, composites and nanocomposites, enabling readers to understand and utilize the improved material properties that UPRs facilitate. Chapters cover unsaturated polyester resins and their interaction at the macro, micro and nano levels, in-depth studies on the properties and analysis of UPR based materials, and the applications of UPR based composites, blends, IPNs and gels across a range of advanced commercial and industrial fields. This is a highly detailed source of information on unsaturated polyester resins, supporting academics, researchers and postgraduate students working with UPRs, polyesters, polymeric or composite materials, polymer chemistry, polymer physics, and materials science, as well as scientists, R&D professionals and engineers in industry.

Atlas of Material Damage (Hardcover, 2nd edition): George Wypych Atlas of Material Damage (Hardcover, 2nd edition)
George Wypych
R10,085 R6,282 Discovery Miles 62 820 Save R3,803 (38%) Ships in 12 - 19 working days

Atlas of Material Damage, Second Edition provides a systematic analysis of the modes of damage and morphology of damaged material, and compares the experiences of different industries to provide insight into the most frequently encountered failures, reasons for these failures, and potential improvements to prevent future materials failure. Product reliability is a critical aim of materials scientists and engineers. Uninterrupted performance of manufactured products at typical and extreme conditions of use is the major goal of product development and the most important indicator of material quality. This atlas has microscopic pictures, schematic diagrams, and graphs which show how materials fail, how they are produced to not fail, and how they are designed to perform particular functions to make outstanding products. Findings presented by each illustration are fully explained in the text and labeled. Materials increasingly must have optimal structure and specially designed morphology. The book offers numerous examples of how this special morphology can be achieved in electronics, the plastics industry, the pharmaceutical industry, aerospace, automotive applications, medicine, dentistry, and many other fields. This book provides information on defect formation and materials damage; discusses effect of composition, morphological features and structure of different materials on material performance, durability, and resilience; and analyses the cause of material damage and degradation, and the effect of processing conditions on material damage.

Adverse Effects of Engineered Nanomaterials - Exposure, Toxicology, and Impact on Human Health (Hardcover, 2nd edition): Bengt... Adverse Effects of Engineered Nanomaterials - Exposure, Toxicology, and Impact on Human Health (Hardcover, 2nd edition)
Bengt Fadeel, Antonio Pietroiusti, Anna A. Shvedova
R3,441 Discovery Miles 34 410 Ships in 12 - 19 working days

Adverse Effects of Engineered Nanomaterials: Exposure, Toxicology, and Impact on Human Health, Second Edition, provides a systematic evaluation of representative engineered nanomaterials (ENM) of high volume production and their high economic importance. Each class of nanomaterials discussed includes information on what scientists, industry, regulatory agencies, and the general public need to know about nanosafety. Written by leading international experts in nanotoxicology and nanomedicine, this book gives a comprehensive view of the health impact of ENM, focusing on their potential adverse effects in exposed workers, consumers, and patients. All chapters have been updated with new sections on the endocrine system and other organ systems. In addition, other newly added sections include introductory chapters on the physio-chemical characterization of nanomaterials and interactions between nanomaterials and biological systems, as well as a new chapter that explores risk assessment and management of nanomaterials. This book fills an important need in terms of bridging the gap between experimental findings and human exposure to ENM, also detailing the clinical and pathological consequences of such exposure in the human population.

Materials Under Extreme Conditions - Recent Trends and Future Prospects (Hardcover): A.K. Tyagi, S. Banerjee Materials Under Extreme Conditions - Recent Trends and Future Prospects (Hardcover)
A.K. Tyagi, S. Banerjee
R4,752 R4,418 Discovery Miles 44 180 Save R334 (7%) Ships in 12 - 19 working days

Materials Under Extreme Conditions: Recent Trends and Future Prospects analyzes the chemical transformation and decomposition of materials exposed to extreme conditions, such as high temperature, high pressure, hostile chemical environments, high radiation fields, high vacuum, high magnetic and electric fields, wear and abrasion related to chemical bonding, special crystallographic features, and microstructures. The materials covered in this work encompass oxides, non-oxides, alloys and intermetallics, glasses, and carbon-based materials. The book is written for researchers in academia and industry, and technologists in chemical engineering, materials chemistry, chemistry, and condensed matter physics.

Stress Corrosion Cracking - Theory and Practice (Paperback): V. S. Raja, T. Shoji Stress Corrosion Cracking - Theory and Practice (Paperback)
V. S. Raja, T. Shoji
R6,988 R6,447 Discovery Miles 64 470 Save R541 (8%) Ships in 12 - 19 working days

The problem of stress corrosion cracking (SCC), which causes sudden failure of metals and other materials subjected to stress in corrosive environment(s), has a significant impact on a number of sectors including the oil and gas industries and nuclear power production. Stress corrosion cracking reviews the fundamentals of the phenomenon as well as examining stress corrosion behaviour in specific materials and particular industries. The book is divided into four parts. Part one covers the mechanisms of SCC and hydrogen embrittlement, while the focus of part two is on methods of testing for SCC in metals. Chapters in part three each review the phenomenon with reference to a specific material, with a variety of metals, alloys and composites discussed, including steels, titanium alloys and polymer composites. In part four, the effect of SCC in various industries is examined, with chapters covering subjects such as aerospace engineering, nuclear reactors, utilities and pipelines. With its distinguished editors and international team of contributors, Stress corrosion cracking is an essential reference for engineers and designers working with metals, alloys and polymers, and will be an invaluable tool for any industries in which metallic components are exposed to tension, corrosive environments at ambient and high temperatures.

Materials Characterization Using Nondestructive Evaluation (NDE) Methods (Hardcover): Gerhard Huebschen, Iris Altpeter, Ralf... Materials Characterization Using Nondestructive Evaluation (NDE) Methods (Hardcover)
Gerhard Huebschen, Iris Altpeter, Ralf Tschuncky, Hans-Georg Herrmann
R4,743 R4,401 Discovery Miles 44 010 Save R342 (7%) Ships in 12 - 19 working days

Materials Characterization Using Nondestructive Evaluation (NDE) Methods discusses NDT methods and how they are highly desirable for both long-term monitoring and short-term assessment of materials, providing crucial early warning that the fatigue life of a material has elapsed, thus helping to prevent service failures. Materials Characterization Using Nondestructive Evaluation (NDE) Methods gives an overview of established and new NDT techniques for the characterization of materials, with a focus on materials used in the automotive, aerospace, power plants, and infrastructure construction industries. Each chapter focuses on a different NDT technique and indicates the potential of the method by selected examples of applications. Methods covered include scanning and transmission electron microscopy, X-ray microtomography and diffraction, ultrasonic, electromagnetic, microwave, and hybrid techniques. The authors review both the determination of microstructure properties, including phase content and grain size, and the determination of mechanical properties, such as hardness, toughness, yield strength, texture, and residual stress.

A Comprehensive Database of Tests on Axially Loaded Piles Driven in Sand (Paperback): Zhongxuan Yang, Richard Jardine, Wangbo... A Comprehensive Database of Tests on Axially Loaded Piles Driven in Sand (Paperback)
Zhongxuan Yang, Richard Jardine, Wangbo Guo, Fiona Chow
R2,535 R2,390 Discovery Miles 23 900 Save R145 (6%) Ships in 12 - 19 working days

A Comprehensive Database of Tests on Axially Loaded Driven Piles in Sands reviews the critical need to develop better load-test databases for piles driven in sands. The key quality parameters, population of current entries and reporting formats are described before offering preliminary results obtained from comparisons between axial capacities calculated by various predictive approaches and site measurements. This book also shows that the "simplified" and "offshore" ICP and UWA variants proposed by some practitioners are over-conservative and that their use could be discontinued. The new pile capacity and stiffness database offers a broad scope for evaluating potential prediction biases relating to a wide range of soil and pile parameters. Submission of further high quality tests for inclusion in regularly updated versions is encouraged.

Bioepoxy/Clay Nanocomposites - Fabrication Optimisation, Properties and Modelling (Hardcover, 1st ed. 2021): Haipan Salam, Yu... Bioepoxy/Clay Nanocomposites - Fabrication Optimisation, Properties and Modelling (Hardcover, 1st ed. 2021)
Haipan Salam, Yu Dong
R3,383 Discovery Miles 33 830 Ships in 10 - 15 working days

This book highlights current advanced developments in bioepoxy and bioepoxy/clay nanocomposites and an optimisation of material formulation and processing parameters on fabrication of bioepoxy/clay nanocomposites in order to achieve the highest mechanical properties in relation to their morphological structures, thermal properties, as well as biodegradability and water absorption, which is based on the use of Taguchi design of experiments with the consideration of technical and economical point of view. It also elaborates holistic theoretical modelling of tensile properties of such bionanocomposites with respect to the effect of contents of nanoclay fillers and epoxydised soybean oil (ESO).

ZIF-8 Based Materials for Water Decontamination (Hardcover): Awais Ahmad, Muhammad Pervaiz, Umer Younas, Rafael Luque, Mabkhoot... ZIF-8 Based Materials for Water Decontamination (Hardcover)
Awais Ahmad, Muhammad Pervaiz, Umer Younas, Rafael Luque, Mabkhoot Alsaiari, …
R5,099 Discovery Miles 50 990 Ships in 12 - 19 working days

This volume discusses the role of ZIF-8 composites in water decontamination as an adsorbent and photocatalyst. Metal-organic frameworks (MOFs) are advanced porous materials and are promising adsorbents with facile modifications, high specific surface area, controllable porosity, and tailored surface properties. Water pollution is a major concern and has endangered human health. Recently, researchers have designed MOFs for use in remediation.

ZIF-8 Based Materials for Pharmaceutical Waste (Hardcover): Awais Ahmad, Muhammad Pervaiz, Zohaib Saeed, Rafael Luque, Mabkhoot... ZIF-8 Based Materials for Pharmaceutical Waste (Hardcover)
Awais Ahmad, Muhammad Pervaiz, Zohaib Saeed, Rafael Luque, Mabkhoot Alsaiari, …
R5,101 Discovery Miles 51 010 Ships in 12 - 19 working days

This volume discusses the role of MOFs in removal of pharmaceutical pollutants. Metal-organic frameworks (MOFs) are advanced porous materials and are promising adsorbents with facile modifications, high specific surface area, controllable porosity, and tailored surface properties. Pharmaceutical pollution is an issue of concern due to its effects on environment. Recently, researchers have designed MOFs for use in remediation.

Non-Destructive In Situ Strength Assessment of Concrete - Practical Application of the RILEM TC 249-ISC Recommendations... Non-Destructive In Situ Strength Assessment of Concrete - Practical Application of the RILEM TC 249-ISC Recommendations (Hardcover, 1st ed. 2021)
Denys Breysse, Jean Paul Balayssac
R4,166 Discovery Miles 41 660 Ships in 10 - 15 working days

The book presents the work of the RILEM Technical Committee 249-ISC. Addressing the effective application of new recommendations for non-destructive in situ strength assessment of concrete, it provides information about the different steps of the investigation and processing of test results, until the delivery of strength estimates, and includes tables giving the minimum required number of cores in a variety of situations as well as several examples of how the recommendations can be used in practice. The book explores a topic which is of major importance, i.e. the assessment of concrete compressive strength in existing structures. This property (both mean and standard deviation) is a key input in many cases, such as the reinforcement of structures, the safety checking, the extension of service life. As the new RILEM recommendations imply a deep revision (and improvement) of field practice, the book is intended for managers of structures, structural engineers and specialists of NDT that have to answer these issues. More widely, it will benefit engineers and students who are interested in NDT and in the safety analysis of structures.

X-Ray Fluorescence Spectrometry and Related Techniques (Hardcover): Eva Margui, Rene Van Grieken X-Ray Fluorescence Spectrometry and Related Techniques (Hardcover)
Eva Margui, Rene Van Grieken
R3,590 Discovery Miles 35 900 Ships in 12 - 19 working days

X-ray fluorescence spectrometry (XRF) is a well-established analytical technique for qualitative and quantitative elemental analysis of a wide variety of materials. It is known for its rapid speed and ease of use. All levels of professionals in materials science, analytic chemistry, and physics will benefit from the review of basic and newly developed technologies presented in this book. Highlights include: A basic introduction to XRF, including background on X-ray physics. Coverage of qualitative and quantitative analysis using XRF. Coverage of the design of low-power micro-focus tubes and novel X-ray optics and detectors. Benchtop and portable instrumentation that offer extreme simplicity of operation in a low-cost design. Extensive bibliographic references. Buyers Guide.

Characterization of Minerals, Metals, and Materials 2021 (Hardcover, 1st ed. 2021): Jian Li, Mingming Zhang, Bowen Li, Sergio... Characterization of Minerals, Metals, and Materials 2021 (Hardcover, 1st ed. 2021)
Jian Li, Mingming Zhang, Bowen Li, Sergio Neves Monteiro, Shadia Ikhmayies, …
R6,449 Discovery Miles 64 490 Ships in 10 - 15 working days

The collection focuses on the advancements of characterization of minerals, metals, and materials and the applications of characterization results on the processing of these materials. Advanced characterization methods, techniques, and new instruments are emphasized. Areas of interest include, but are not limited to: * Novel methods and techniques for characterizing materials across a spectrum of systems and processes. * Characterization of mechanical, thermal, electrical, optical, dielectric, magnetic, physical, and other properties of materials. * Characterization of structural, morphological, and topographical natures of materials at micro- and nano- scales. * Characterization of extraction and processing including process development and analysis. * Advances in instrument developments for microstructure analysis and performance evaluation of materials, such as computer tomography (CT), X-ray and neutron diffraction, electron microscopy (SEM, FIB, TEM), and spectroscopy (EDS, WDS, EBSD) techniques. * 2D and 3D modelling for materials characterization. The book explores scientific processes to characterize materials using modern technologies, and focuses on the interrelationships and interdependence among processing, structure, properties, and performance of materials.

Porous Materials - Theory and Its Application for Environmental Remediation (Hardcover, 1st ed. 2021): Juan Carlos... Porous Materials - Theory and Its Application for Environmental Remediation (Hardcover, 1st ed. 2021)
Juan Carlos Moreno-Pirajan, Liliana Giraldo-Gutierrez, Fernando Gomez-Granados
R5,142 Discovery Miles 51 420 Ships in 10 - 15 working days

This book is written in honor of Prof. Francisco Rodriguez-Reinoso, who has made significant contributions in the area of porous materials such as active carbons and graphenes. It details the preparation of porous materials, including carbonaceous, zeolitic, and siliceous materials, MOFs, aerogels, and xerogels, describing the characterization techniques and the interpretation of the results, and highlighting common errors that can occur during the process. This book subsequently presents the use of modeling based on thermodynamics to describe the materials. Lastly, it illustrates a number of current environmental protection applications in the context of both water and air.

Physics and Chemistry of Te and HgTe-based Ternary Semiconductor Melts (Hardcover, 1st ed. 2021): Ching-Hua Su Physics and Chemistry of Te and HgTe-based Ternary Semiconductor Melts (Hardcover, 1st ed. 2021)
Ching-Hua Su
R4,233 Discovery Miles 42 330 Ships in 12 - 19 working days

This book reviews the experimental measurements of density, thermal conductivity, viscosity, and electrical conductivity on the binary, pseudo-binary melts of the most advanced IR-detector material systems of HgCdTe and HgZnTe as well as the theoretical analyses of these results. The time-dependent measurements on the relaxation behavior of the thermophysical properties during rapid cooling of the melts were also performed to elucidate the characteristics of the structural fluctuation and transition of the melts. The author shows his research results which extend understanding of the solidification process in order to interpret and improve the experimental results of crystal growth and enhances the fundamental knowledge of heterophase fluctuations phenomena in the melts so as to improve the melt growth processes of all the semiconductor systems. An in-depth study on the thermophysical properties and their time-dependent structural dynamic processes taking place in the vicinity of the solid-liquid phase transition of the narrow homogeneity range HgTe-based ternary semiconductors as well as the structural analysis of the alloy homogenization process in the melt is needed to understand and to improve the crystal growth processes. This book is intended for graduate students and professionals in materials science as well as engineers preparing and developing optical devices with semiconductors. The theory of heterophase fluctuations of liquids is applicable to any many-body systems including condensed-matter physics and field theory.

X-Ray CT - Hardware and Software Techniques (Hardcover, 1st ed. 2021): Hiroyuki Toda X-Ray CT - Hardware and Software Techniques (Hardcover, 1st ed. 2021)
Hiroyuki Toda
R4,618 Discovery Miles 46 180 Ships in 12 - 19 working days

This book provides easy-to-understand explanations to systematically and comprehensively describe the X-ray CT technologies, techniques, and skills used for industrial and scientific purposes. Included are many references along with photographs, figures, and equations prepared by the author. These features all facilitate the reader's gaining a deeper understanding of the topics being discussed. The book presents expertise not only on fundamentals but also about hardware, software, and analytical methods for the benefit of technical users. The book targets engineers, researchers, and students who are involved in research, development, design, and quality assurance in industry and academia.

Biocomposite Materials - Design and Mechanical Properties Characterization (Hardcover, 1st ed. 2021): Mohamed Thariq Hameed... Biocomposite Materials - Design and Mechanical Properties Characterization (Hardcover, 1st ed. 2021)
Mohamed Thariq Hameed Sultan, Mohd Shukry Abdul Majid, Mohd Ridzuan Mohd Jamir, Azwan Iskandar Azmi, Naheed Saba
R3,222 Discovery Miles 32 220 Ships in 12 - 19 working days

The book highlights the recent research developments in biocomposite design, mechanical performance and utility. It discusses innovative experimental approaches along with mechanical designs and manufacturing aspects of various fibrous polymer matrix composites and presents examples of the synthesis and development of biocomposites and their applications. It is useful for researchers developing biocomposite materials for biomedical and environmental applications.

Study of New Ternary Rare-Earth Intermetallic Germanides with Polar Covalent Bonding - Beyond the Zintl Picture (Hardcover, 1st... Study of New Ternary Rare-Earth Intermetallic Germanides with Polar Covalent Bonding - Beyond the Zintl Picture (Hardcover, 1st ed. 2020)
Riccardo Freccero
R2,889 Discovery Miles 28 890 Ships in 10 - 15 working days

The thesis focuses on the syntheses, structural characterizations and chemical bonding analyses for several ternary R-M-Ge (R = rare earth metal; M = another metal) intermetallics. The challenges in understanding the main interactions governing the chemistry of these compounds, which lead to our inability to predict their formation, structure and properties, are what provided the motivation for this study. In particular, the R2MGe6 (M = Li, Mg, Al, Cu, Zn, Pd, Ag), R4MGe10-x (M = Li, Mg), R2Pd3Ge5, Lu5Pd4Ge8, Lu3Pd4Ge4 and Yb2PdGe3 phases were synthesized and structurally characterized. Much effort was put into the stabilization of metastable phases, employing the innovative metal flux method, and into the accurate structure solution of twinned crystals. Cutting-edge position-space chemical bonding techniques were combined with new methodologies conceived to correctly describe the Ge-M, Ge-La and also La-M polar-covalent interactions for the La2MGe6 (M = Li, Mg, Al, Cu, Zn, Pd, Ag) series. The present results constitute a step forward in our comprehension of ternary germanide chemistry as well as providing a good playground for further investigations.

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