Electrochemistry plays an important role in preserving our cultural heritage. For the first time this has been documented in the present volume. Coverage includes both electrochemical processes such as corrosion and electroanalytical techniques allowing to analyse micro- and nanosamples from works of art or archaeological finds. While this volume is primarily aimed at electrochemists and analytical chemists, it also contains relevant information for conservators, restorers, and archaeologists.

The book drawing on the author's nearly half a century of energetic materials research experience intends to systematically review the global researches on liquid explosives. The book focuses on the study of the conception, explosion mechanism, properties and preparation of liquid explosives. It provides a combination of theoretical knowledge and practical examples in a reader-friendly style. The book is likely to be interest of university researchers and graduate students in the fields of energetic materials, blasting engineering and mining.

This book covers the topic of vibration energy harvesting using piezoelectric materials. Piezoelectric materials are analyzed in the context of their electromechanical coupling, heterogeneity, microgeometry and interrelations between electromechanical properties. Piezoelectric ceramics and composites based on ferroelectrics are advanced materials that are suitable for harvesting mechanical energy from vibrations using inertial energy harvesting which relies on the resistance of a mass to acceleration and kinematic energy harvesting which couples the energy harvester to the relative movement of different parts of a source. In addition to piezoelectric materials, research efforts to develop optimization methods for complex piezoelectric energy harvesters are also reviewed. The book is important for specialists in the field of modern advanced materials and will stimulate new effective piezotechnical applications.

Li-Co-Mn-Ni oxides have been of extreme interest as potential positive electrode materials for next generation Li-ion batteries. Though many promising materials have been discovered and studied extensively, much debate remains in the literature about the structures of these materials. There is no consensus as to whether the lithium-rich layered materials are single-phase or form a layered-layered composite on the few nanometer length-scales. Much of this debate came about because no phase diagrams existed to describe these systems under the synthesis conditions used to make electrode materials. Detailed in this thesis are the complete Li-Co-Mn-O and Li-Mn-Ni-O phase diagrams generated by way of the combinatorial synthesis of mg-scale samples at over five hundred compositions characterized with X-ray diffraction. Selected bulk samples were used to confirm that the findings are relevant to synthesis conditions used commercially. The results help resolve a number of points of confusion and contradiction in the literature. Amongst other important findings, the compositions and synthesis conditions giving rise to layered-layered nano-composites are presented and electrochemical results are used to show how better electrode materials can be achieved by making samples in the single phase-layered regions.

This book covers the topic of eddy current nondestructive evaluation, the most commonly practiced method of electromagnetic nondestructive evaluation (NDE). It emphasizes a clear presentation of the concepts, laws and relationships of electricity and magnetism upon which eddy current inspection methods are founded. The chapters include material on signals obtained using many common eddy current probe types in various testing environments. Introductory mathematical and physical concepts in electromagnetism are introduced in sufficient detail and summarized in the Appendices for easy reference. Worked examples and simple calculations that can be done by hand are distributed throughout the text. These and more complex end-of-chapter examples and assignments are designed to impart a working knowledge of the connection between electromagnetic theory and the practical measurements described. The book is intended to equip readers with sufficient knowledge to optimize routine eddy current NDE inspections, or design new ones. It is useful for graduate engineers and scientists seeking a deeper understanding of electromagnetic methods of NDE than can be found in a guide for practitioners.

Micromanufacturing and Nanotechnology is an emerging technological infrastructure and process that involves manufacturing of products and systems at the micro and nano scale levels. Development of micro and nano scale products and systems are underway due to the reason that they are faster, accurate and less expensive. Moreover, the basic functional units of such systems possesses remarkable mechanical, electronic and chemical properties compared to the macro-scale counterparts. Since this infrastructure has already become the prefered choice for the design and development of next generation products and systems it is now necessary to disseminate the conceptual and practical phenomenological know-how in a broader context. This book incorporates a selection of research and development papers. Its scope is the history and background, underlynig design methodology, application domains and recent developments.

The book summarizes recent international research and experimental developments regarding fatigue crack growth investigations of rubber materials. It shows the progress in fundamental as well as advanced research of fracture investigation of rubber material under fatigue loading conditions, especially from the experimental point of view. However, some chapters will describe the progress in numerical modeling and physical description of fracture mechanics and cavitation phenomena in rubbers. Initiation and propagation of cracks in rubber materials are dominant phenomena which determine the lifetime of these soft rubber materials and, as a consequence, the lifetime of the corresponding final rubber parts in various fields of application. Recently, these phenomena became of great scientific interest due to the development of new experimental methods, concepts and models. Furthermore, crack phenomena have an extraordinary impact on rubber wear and abrasion of automotive tires; and understanding of crack initiation and growth in rubbers will help to support the growthing number of activities and worldwide efforts of reduction of tire wear losses and abrasion based emissions.

Ion implantation is one of the key processing steps in silicon integrated circuit technology. Some integrated circuits require up to 17 implantation steps and circuits are seldom processed with less than 10 implantation steps. Controlled doping at controlled depths is an essential feature of implantation. Ion beam processing can also be used to improve corrosion resistance, to harden surfaces, to reduce wear and, in general, to improve materials properties. This book presents the physics and materials science of ion implantation and ion beam modification of materials. It covers ion-solid interactions used to predict ion ranges, ion straggling and lattice disorder. Also treated are shallow-junction formation and slicing silicon with hydrogen ion beams. Topics important for materials modification topics, such as ion-beam mixing, stresses, and sputtering, are also described.

This text, the first of its kind, delivers a systematically organized introduction to the theory and practice of yield prediction. The book addresses the economic need for accurate yield prediction, and clarifies the important role it plays in the semiconductor industry.

This book presents research advances in the field of Continuous Media with Microstructure and considers the three complementary pillars of mechanical sciences: theory, research and computational simulation. It focuses on the following problems: thermodynamic and mathematical modeling of materials with extensions of classical constitutive laws, single and multicomponent media including modern multifunctional materials, wave propagation, multiscale and multiphysics processes, phase transformations, and porous, granular and composite materials. The book presents the proceedings of the 2nd Conference on Continuous Media with Microstructure, which was held in 2015 in Lagow, Poland, in memory of Prof. Krzysztof Wilmanski.

This volume of Modern Aspects covers a wide spread of topics presented in an authoritative, informative and instructive manner by some internationally renowned specialists. Professors Politzer and Dr. Murray provide a comprehensive description of the various theoretical treatments of solute-solvent interactions, including ion-solvent interactions. Both continuum and discrete molecular models for the solvent molecules are discussed, including Monte Carlo and molecular dynamics simulations. The advantages and drawbacks of the resulting models and computational approaches are discussed and the impressive progress made in predicting the properties of molecular and ionic solutions is surveyed. The fundamental and applied electrochemistry of the silicon/electrolyte interface is presented in an authoritative review by Dr. Gregory Zhang, with emphasis in the preparation of porous silicon, a material of significant technological interest, via anodic dissolution of monocrystalline Si. The chapter shows eloquently how fundamental electrokinetic principles can be utilized to obtain the desired product morphology. Markov chains theory provides a powerful tool for modeling several important processes in electrochemistry and electrochemical engineering, including electrode kinetics, anodic deposit formation and deposit dissolution processes, electrolyzer and electrochemical reactors performance and even reliability of warning devices and repair of failed cells. The way this can be done using the elegant Markov chains theory is described in lucid manner by Professor Thomas Fahidy in a concise chapter which gives to the reader only the absolutely necessary mathematics and is rich in practical examples.

It is now 10 years since the first edition of Engineering Coatings by Stan Grainger appeared. The success of that edition, and the developments in the area since its publication make this new edition a valuable addition
to the literature on the subject.
This new edition describes the many methods by which surface coatings or surface modification can be carried out to delay surface degradation and prolong the useful life of engineering components. Since surface technology has advanced in many areas, new techniques such as the newer thermal spray processes and laser surfacing are now covered and the book has been expanded to include more coverage on corrosion.
Major changes have also taken place in health and safety legislation, and the sections covering health and safety have been entirely revised as a result. Engineering Coatings with its breadth of coverage and sound basis in
industrial practice is an invaluable guide to methods which have the potential to save money in many industries concerned with wear, corrosion, welding and thermal spraying of engineering components.

This book provides insights into sensor development for structural health monitoring. Current technological advances mean that the field is changing rapidly, making standardization an ongoing challenge. As such, the book gathers several essential contributions in the area of sensor development, including macro-fiber composite sensors for crack detection and optical fiber Bragg gratings for flaw detection. It also discusses the use of the welds in the structure as sensors, and probability estimation of detection for various sensor configurations. In addition, it presents methods based on vibration signal variations to detect small defects in composite components or to monitor large structures. Last but not least, the book includes special structural health monitoring applications in industrial components such as a nuclear boiler support spines and industrial presses as well as in corrosion monitoring of pipes.

This second edition of the highly successful dictionary offers more than 300 new or revised terms. A distinguished panel of electrochemists provides up-to-date, broad and authoritative coverage of 3000 terms most used in electrochemistry and energy research as well as related fields, including relevant areas of physics and engineering. Each entry supplies a clear and precise explanation of the term and provides references to the most useful reviews, books and original papers to enable readers to pursue a deeper understanding if so desired. Almost 600 figures and illustrations elaborate the textual definitions. The "Electrochemical Dictionary" also contains biographical entries of people who have substantially contributed to electrochemistry. From reviews of the first edition: 'the creators of the Electrochemical Dictionary have done a laudable job to ensure that each definition included here has been defined in precise terms in a clear and readily accessible style' (The Electric Review) 'It is a must for any scientific library, and a personal purchase can be strongly suggested to anybody interested in electrochemistry' (Journal of Solid State Electrochemistry) 'The text is readable, intelligible and very well written' (Reference Reviews)

This book presents concepts, methods and techniques to examine symptoms of faults and failures of structures, systems and components and to monitor functional performance and structural integrity. The book is organized in five parts. Part A introduces the scope and application of technical diagnostics and gives a comprehensive overview of the physics of failure. Part B presents all relevant methods and techniques for diagnostics and monitoring: from stress, strain, vibration analysis, nondestructive evaluation, thermography and industrial radiology to computed tomography and subsurface microstructural analysis. Part C cores the principles and concepts of technical failure analysis, illustrates case studies, and outlines machinery diagnostics with an emphasis on tribological systems. Part D describes the application of structural health monitoring and performance control to plants and the technical infrastructure, including buildings, bridges, pipelines, electric power stations, offshore wind structures, and railway systems. And finally, Part E is an excursion on diagnostics in arts and culture. The book integrates knowledge of basic sciences and engineering disciplines with contributions from research institutions, academe, and industry, written by internationally known experts from various parts of the world, including Europe, Canada, India, Japan, and USA.

This second edition of a successful and highly-accessed monograph has been extended by more than 100 pages. It includes an enlarged coverage of applications for materials characterization and analysis. Also a more detailed description of strategies for determining free energies of ion transfer between miscible liquids is provided. This is now possible with a "third-phase strategy" which the authors explain from theoretical and practical points of view. The book is still the only one detailing strategies for solid state electroanalysis. It also features the specific potential of the techniques to use immobilized particles (for studies of solid materials) and of immobilized droplets of immiscible liquids for the purpose of studying the three-phase electrochemistry of these liquids. This also includes studies of ion transfer between aqueous and immiscible non-aqueous liquids. The bibliography of all published papers in this field of research has been expanded from 318 to now 444 references in this second edition. Not only are pertinent references provided at the end of each chapter, but the complete list of the cited literature is also offered as a separate chapter for easy reference.

This book highlights a novel and robust platform in the form of in-situ characterization setup for creating X-ray computed tomography (XCT)-based textile material twins. In this hybrid experimental-numerical platform, XCT images of different complex fibrous reinforcements at different levels of compaction are acquired. The images are converted into computational models for resin flow simulations. The capabilities of this hybrid framework are applied to a variety of reinforcements used in liquid composite molding processes such as 2D, 3D fabrics and dry tapes. This book is a milestone in the development of virtual manufacturing protocols using material twins of textiles, providing a step closer to the digitalization of advanced composites used in manufacturing processes for industry 4.0.

This book draws on the latest research to discuss the history and development of high-entropy alloys and ceramics in bulk, film, and fiber form. High-entropy materials have recently been developed using the entropy of mixing and entropy of configuration of materials, and have proven to exhibit unique properties superior to those of conventional materials. The field of high-entropy alloys was born in 2004, and has since been developed for both scientific and engineering applications. Although there is extensive literature, this field is rapidly transforming. This book highlights the cutting edge of high-entropy materials, including their fundamentals and applications. Above all, it reflects two major milestones in their development: the equi-atomic ratio single-phase high-entropy alloys; and the non-equi-atomic ratio dual-phase high-entropy alloys.

This book presents the latest advances in ultrafast science, including both ultrafast optical technology and the study of ultrafast phenomena. It covers picosecond, femtosecond, and attosecond processes relevant to applications in physics, chemistry, biology, and engineering. Ultrafast technology has a profound impact in a wide range of applications, amongst them biomedical imaging, chemical dynamics, frequency standards, material processing, and ultrahigh-speed communications. This book summarizes the results presented at the 19th International Conference on Ultrafast Phenomena and provides an up-to-date view of this important and rapidly advancing field.

Laser-enabled measurements are valuable tools for the investigation of surfaces and interfaces or for the in situ investigation of interfacial processes including electrode processes. The understanding of the thermodynamics of solid/liquid surfaces is important for surface science and electrochemistry. In the first part of this book, the authors describe a range of techniques for investigating interfacial tension and surface stress, which is important for coatings, thin films, and fuel cells. The techniques covered comprise bending beam (bending plate, bending cantilever, wafer curvature) methods with different detection techniques. Special attention is given to methods using optical detection by laser beam deflection or interferometry. The second part is devoted to the techniques based on the detection of refractive index gradients in the solution. The refractive index changes could be related to concentration gradients (Probe Beam Deflection, PBD) or light-induced thermal gradients (Photothermal Deflection Spectroscopy, PDS). The application of the techniques to surface-confined and solution electrochemical systems is described. Subsequently, a comparison with others techniques able to monitor ion fluxes is performed.

This volume presents a collection of contributions on materials modeling, which were written to celebrate the 65th birthday of Prof. Nobutada Ohno. The book follows Prof. Ohno's scientific topics, starting with creep damage problems and ending with homogenization methods.

This book describes spark plasma sintering (SPS) in depth. It addresses fundamentals and material-specific considerations, techniques, and applications across a broad spectrum of materials. The book highlights methods used to consolidate metallic or ceramic particles in very short times. It highlights the production of complex alloys and metal matrix composites with enhanced mechanical and wear properties. Emphasis is placed on the speed of the sintering processes, uniformity in product microstructure and properties, reduced grain growth, the compaction and sintering of materials in one processing step, various materials processing, and high energy efficiency. Current and potential applications in space science and aeronautics, automation, mechanical engineering, and biomedicine are addressed throughout the book.

This book includes contributions from the Materials Processing Fundamentals Symposium held at the TMS 2018 Annual Meeting & Exhibition in Phoenix, Arizona. Covering the physical and numerical modeling of materials processing, the volume covers a range of metals and minerals. Authors present models and results related the basics of processing such as extraction, joining, separation, and casting. The corresponding fundamentals of mass and heat transport as well as physical and thermodynamics properties are addressed, allowing for a cross-disciplinary vision of the field.

This book provides an overview of polymer nanocomposites and hybrid materials with polyhedral oligomeric silsesquioxanes (POSS). Among inorganic nanoparticles, functionalized POSS are unique nano-building blocks that can be used to create a wide variety of hybrid and composite materials, where precise control of nanostructures and properties is required. This book describes the influence of incorporation of POSS moieties into (organic) polymer matrices on the mechanical, thermal and flammability behavior of composites and hybrid organic-inorganic materials. Importantly, POSS-containing materials can be bio-functionalized by linking e.g. peptides and growth factors through appropriate surface modification in order to enhance the haemo-compatibility of cardiovascular devices made of these materials. This volume includes descriptions of synthesis routes of POSS and POSS-containing polymeric materials (e.g. based on polyolefines, epoxy resins and polyurethanes), presentation of POSS' role as flame retardants and as biocompatible linker, as well as the depiction of decomposition and ageing processes.

This second edition provides comprehensive information on electromagnetic acoustic transducers (EMATs), from the theory and physical principles of EMATs to the construction of systems and their applications to scientific and industrial ultrasonic measurements on materials. The original version has been complemented with selected ideas on ultrasonic measurement that have emerged since the first edition was released. The book is divided into four parts: PART I offers a self-contained description of the basic elements of coupling mechanisms along with the practical designing of EMATs for various purposes. Several implementations to compensate for EMATs' low transfer efficiency are provided, along with useful tips on how to make an EMAT. PART II describes the principle of electromagnetic acoustic resonance (EMAR), which makes the most of EMATs' contactless nature and is the most successful amplification mechanism for precise measurements of velocity and attenuation. PART III applies EMAR to studying physical acoustics. New measurements have emerged with regard to four major subjects: in situ monitoring of dislocation behavior, determination of anisotropic elastic constants, pointwise elasticity mapping (RUM), and acoustic nonlinearity evolution. PART IV deals with a variety of individual issues encountered in industrial applications, for which the EMATs are believed to be the best solutions. This is proven by a number of field applications.