In this thesis, the author investigates experimentally and numericallythe fracture behavior of an electron beam welded joint made fromtwo butt S355 plates. The 2D Rousselier model, the Gurson-Tvergaard-Needleman (GTN) model and the cohesive zone model (CZM) wereadopted to predict the crack propagation of thick compact tension (CT)specimens. Advantages and disadvantages of the three mentioned modelsare discussed. The cohesive zone model is suggested as it is easy to usefor scientists & engineers because the CZM has less model parametersand can be used to simulate arbitrary crack propagation. The resultsshown in this thesis help to evaluate the fracture behavior of a metallicmaterial. A 3D optical deformation measurement system (ARAMIS) andthe synchrotron radiation-computed laminography (SRCL) techniquereveal for the first time the damage evolution on the surface of the sampleand inside a thin sheet specimen obtained from steel S355. Damageevolution by void initiation, growth and coalescence are visualized in2D and 3D laminographic images. Two fracture types, i.e., a flat crackpropagation originated from void initiation, growth and coalescenceand a shear coalescence mechanism are visualized in 2D and 3D imagesof laminographic data, showing the complexity of real fracture. Inthe dissertation, the 3D Rousselier model is applied for the first timesuccessfully to predict different microcrack shapes before shear cracksarise by defining the finite elements in front of the initial notch withinhomogeneous f0-values. The influence of the distribution of inclusionson the fracture shape is also discussed. For the analyzed material, ahomogeneous distribution of particles in the material provides thehighest resistance to fracture.

This book describes efficient and safe repair operations for pipelines, and develops new methods for the detection and repair of volumetric surface defects in transmission pipelines. It also addresses the physics, mechanics, and applications of advanced materials used for composite repair of corroded pipelines. Presenting results obtained in the European Commission's INNOPIPES FRAMEWORK 7 programme, it develops long-range ultrasonic and phased array technologies for pipeline diagnostics, and explores their interactions with discontinuities and directional properties of ultrasonic antenna array. The book subsequently shares the results of non-destructive testing for different types of materials applications and advanced composite repair systems, and characterizes the mechanical properties by means of fracture methods and non-destructive techniques. In turn, the book assesses the currently available technologies for reinforcement of pipelines, drawing on the experience gai ned by project partners, and evaluates the recovery of the carrying capacity of pipeline sections with local corrosion damage by means of analytical and numerical procedures. It develops an optimization method based on the planning of experiments and surface techniques for advanced composite repair systems, before validating the numerical models developed and experimentally gauging the effectiveness of composite repair with the help of full-scale hydraulic tests.

This books presents a current look at friction stir welding technology from application to characterization and from modeling to R&D. It is a compilation of the recent progress relating to friction stir technologies including derivative technologies, high-temperature applications, industrial applications, dissimilar alloy/materials, lightweight alloys, simulation, and characterization. With contributions from leaders and experts in industry and academia, this will be a comprehensive source for the field of Friction Stir Welding and Processing.

This collection gives broad and up-to-date results in the research and development of materials characterization and processing. Coverage is well-rounded from minerals, metals, and materials characterization and developments in extraction to the fabrication and performance of materials. In addition, topics as varied as structural steels to electronic materials to plant-based composites are explored. The latest research presented in this wide area make this book both timely and relevant to the materials science field as a whole. The book explores scientific processes to characterize materials using modern technologies, and focuses on the interrelationships and interdependence among processing, structure, properties, and performance of materials. Topics covered include ferrous materials, non-ferrous materials, minerals, ceramics, clays, soft materials, method development, processing, corrosion, welding, solidification, composites, extraction, powders, nanomaterials, advanced materials, and several others.

This book discusses the mechanisms of electric conductivity in various ionic liquid systems (protic, aprotic as well as polymerized ionic liquids). It hence covers the electric properties of ionic liquids and their macromolecular counterpanes, some of the most promising materials for the development of safe electrolytes in modern electrochemical energy devices such as batteries, super-capacitors, fuel cells and dye-sensitized solar cells. Chapter contributions by the experts in the field discuss important findings obtained using broadband dielectric spectroscopy (BDS) and other complementary techniques. The book is an excellent introduction for readers who are new to the field of dielectric properties of ionic conductors, and a helpful guide for every scientist who wants to investigate the interplay between molecular structure and dynamics in ionic conductors by means of dielectric spectroscopy.

This collection focuses on all aspects of science and technology related to friction stir welding and processing.

This volume features fundamental research and applications in the field of the design and application of engineering materials, predominantly within the context of mechanical engineering applications. This includes a wide range of materials engineering and technology, including metals, e.g., polymers, composites, and ceramics. Advanced applications would include manufacturing in the new or newer materials, testing methods, multi-scale experimental and computational aspects. This book features fundamental research and applications in the design of engineering materials, predominantly within the context of mechanical engineering applications such as automobile, railway, marine, aerospace, biomedical, pressure vessel technology, and turbine technology. It covers a wide range of materials, including metals, polymers, composites, and ceramics. Advanced applications include the manufacturing of new materials, testing methods, multi-scale experimental and computational aspects. p>

This collection provides researchers and industry professionals with complete guidance on the synthesis, analysis, design, monitoring, and control of metals, materials, and metallurgical processes and phenomena. Along with the fundamentals, it covers modeling of diverse phenomena in processes involving iron, steel, non-ferrous metals, and composites. It also goes on to examine second phase particles in metals, novel sensors for hostile-environment materials processes, online sampling and analysis techniques, and models for real-time process control and quality monitoring systems.

This book provides state-of-the-art computational approaches for accelerating materials discovery, synthesis, and processing using thermodynamics and kinetics. The authors deliver an overview of current practical computational tools for materials design in the field. They describe ways to integrate thermodynamics and kinetics and how the two can supplement each other.

Failure Mechanisms in Semiconductor Devices Second Edition E. Ajith Amerasekera Texas Instruments Inc., Dallas, USA Farid N. Najm University of Illinois at Urbana-Champaign, USA Since the successful first edition of Failure Mechanisms in Semiconductor Devices, semiconductor technology has become increasingly important. The high complexity of today's integrated circuits has engendered a demand for greater component reliability. Reflecting the need for guaranteed performance in consumer applications, this thoroughly updated edition includes more detailed material on reliability modelling and prediction. The book analyses the main failure mechanisms in terms of cause, effects and prevention and explains the mathematics behind reliability analysis. The authors detail methodologies for the identification of failures and describe the approaches for building reliability into semiconductor devices. Their thorough yet accessible text covers the physics of failure mechanisms from the semiconductor die itself to the packaging and interconnections. Incorporating recent advances, this comprehensive survey of semiconductor reliability will be an asset to both engineers and graduate students in the field.

The book presents a series of concise papers by researchers specialized in various fields of continuum and computational mechanics and of material science. The focus is on principles and strategies for multiscale modeling and simulation of complex heterogeneous materials, with periodic or random microstructure, subjected to various types of mechanical, thermal, chemical loadings and environmental effects. A wide overview of complex behavior of materials (plasticity, damage, fracture, growth, etc.) is provided. Among various approaches, attention is given to advanced non-classical continua modeling which, provided by constitutive characterization for the internal and external actions (in particular boundary conditions), is a very powerful frame for the gross mechanical description of complex material behaviors, able to circumvent the restrictions of classical coarse-graining multiscale approaches.

With both nickel and cobalt featuring heavily in modern industry, there is an ongoing and intense interest in ore supplies and processing, applications development, and recycling. This book presents a collection of authoritative papers covering the latest advances in all aspects of nickel and cobalt processing, including fundamentals, technology, operating practices, and related areas of Platinum-Group Metals (PGM) processing. Special emphasis is given to the treatment of sulphide and laterite ores, concentrates, and secondary materials for the production of nickel and cobalt.

A new experimental method - the "Stiffnessometer", is developed to measure elementary properties of a superconductor, including the superconducting stiffness and the critical current. This technique has many advantages over existing methods, such as: the ability to measure these properties while minimally disturbing the system; the ability to measure large penetration depths (comparable to sample size), as necessary when approaching the critical temperature; and the ability to measure critical currents without attaching contacts and heating the sample. The power of this method is demonstrated in a study of the penetration depth of LSCO, where striking evidence is found for two separate critical temperatures for the in-plane and out-of-plane directions. The results in the thesis are novel, important and currently have no theoretical explanation. The stiffnessometer in a tool with great potential to explore new grounds in condensed matter physics.

This volume introduces a comprehensive theory of deformation and fracture to engineers and applied scientists. Here "comprehensive" means that the theory can describe all stages of deformation from elastic to plastic and plastic to fracturing stage on the same basis (equations). The comprehensive approach is possible because the theory is based on a fundamental physical principle called the local symmetry, or gauge invariance, as opposed to phenomenology. Professor Yoshida explains the gist of local symmetry (gauge invariance) intuitively so that engineers and applied physicists can digest it easily, rather than describing physical or mathematical details of the principle. The author also describes applications of the theory to practical engineering, such as nondestructive testing in particular, with the use of an optical interferometric technique called ESPI (Electronic Speckle-Pattern Interferometry).The book is not a manual of applications. Instead, it provides information on how to apply physical concepts to engineering applications.

The field of stress analysis has gained its momentum from the widespread applications in industry and technology and has now become an important part of materials science. Various destructive as well as nondestructive methods have been developed for the determination of stresses. This timely book provides a comprehensive review of the nondestructive techniques for strain evaluation written by experts in their respective fields.

The main part of the book deals with X-ray stress analysis (XSA), focussing on measurement and evaluation methods which can help to solve the problems of today, the numerous applications of metallic, polymeric and ceramic materials as well as of thin-film-substrate composites and of advanced microcomponents. Furthermore it contains data, results, hints and recommendations that are valuable to laboratories for the certification and accreditation of their stress analysis.

Stress analysis is an active field in which many questions remain unsettled. Accordingly, unsolved problems and conflicting results are discussed as well. The assessment of the experimentally determined residual and structural stress states on the static and dynamic behavior of materials and components is handled in a separate chapter.

Students and engineers of materials science and scientists working in laboratories and industries will find this book invaluable.

Due to their high stiffness and strength and their good processing properties short fibre reinforced thermoplastics are well-established construction materials. Up to now, simulation of engineering parts consisting of short fibre reinforced thermoplastics has often been based on macroscopic phenomenological models, but deformations, damage and failure of composite materials strongly depend on their microstructure. The typical modes of failure of short fibre thermoplastics enriched with glass fibres are matrix failure, rupture of fibres and delamination, and pure macroscopic consideration is not sufficient to predict those effects. The typical predictive phenomenological models are complex and only available for very special failures. A quantitative prediction on how failure will change depending on the content and orientation of the fibres is generally not possible, and the direct involvement of the above effects in a numerical simulation requires multi-scale modelling. One the one hand, this makes it possible to take into account the properties of the matrix material and the fibre material, the microstructure of the composite in terms of fibre content, fibre orientation and shape as well as the properties of the interface between fibres and matrix. On the other hand, the multi-scale approach links these local properties to the global behaviour and forms the basis for the dimensioning and design of engineering components. Furthermore, multi-scale numerical simulations are required to allow efficient solution of the models when investigating three-dimensional problems of dimensioning engineering parts. Bringing together mathematical modelling, materials mechanics, numerical methods and experimental engineering, this book provides a unique overview of multi-scale modelling approaches, multi-scale simulations and experimental investigations of short fibre reinforced thermoplastics. The first chapters focus on two principal subjects: the mathematical and mechanical models governing composite properties and damage description. The subsequent chapters present numerical algorithms based on the Finite Element Method and the Boundary Element Method, both of which make explicit use of the composite's microstructure. Further, the results of the numerical simulations are shown and compared to experimental results. Lastly, the book investigates deformation and failure of composite materials experimentally, explaining the applied methods and presenting the results for different volume fractions of fibres. This book is a valuable resource for applied mathematics, theoretical and experimental mechanical engineers as well as engineers in industry dealing with modelling and simulation of short fibre reinforced composites.

This monograph addresses the foundations of mechanothermodynamics and analyzes two of its key principles-damage of everything that exists has no conceivable limits, and effective energy (entropy) flows caused by loads of a different nature do not have a cumulative property; they interact dialectically. The authors examine a generalized model of energy and entropy states of a mechanothermodynamical medium, which generally is a continuum (liquid, gaseous) containing distributed solid deformable, and, therefore, damageable bodies, as a problem of information states of movable and damageable systems and express a solution in the first approximation. The book goes on to analyze some directions of further research in its conclusion. It is ideal for scientists, engineers, post graduate and master students of mechanics, mathematics and physics.

This book highlights fundamental research on the design and application of engineering materials, and predominantly mechanical engineering applications. This area includes a wide range of technologies and materials, including metals, polymers, composites, and ceramics. Advanced applications include manufacturing cutting-edge materials, testing methods, and multi-scale experimental and computational aspects. The book introduces readers to a wealth of engineering applications in transport, civil, packaging and power generation.

This book presents a systematic approach in performing reliability assessment of solder joints using Finite Element (FE) simulation. Essential requirements for FE modelling of an electronic package or a single reflowed solder joint subjected to reliability test conditions are elaborated. These cover assumptions considered for a simplified physical model, FE model geometry development, constitutive models for solder joints and aspects of FE model validation. Fundamentals of the mechanics of solder material are adequately reviewed in relation to FE formulations. Concept of damage is introduced along with deliberation of cohesive zone model and continuum damage model for simulation of solder/IMC interface and bulk solder joint failure, respectively. Applications of the deliberated methodology to selected problems in assessing reliability of solder joints are demonstrated. These industry-defined research-based problems include solder reflow cooling, temperature cycling and mechanical fatigue of a BGA package, JEDEC board-level drop test and mechanisms of solder joint fatigue. Emphasis is placed on accurate quantitative assessment of solder joint reliability through basic understanding of the mechanics of materials as interpreted from results of FE simulations. The FE simulation methodology is readily applicable to numerous other problems in mechanics of materials and structures.

This book highlights the symmetry properties of acoustic fields and describes the gauge invariance approach, which can be used to reveal those properties. Symmetry is the key theoretical framework of metamaterials, as has been demonstrated by the successful fabrication of acoustical metamaterials. The book first provides the necessary theoretical background, which includes the covariant derivative, the vector potential, and invariance in coordinate transformation. This is followed by descriptions of global gauge invariance (isotropy), and of local gauge invariance (anisotropy). Sections on time reversal symmetry, reflection invariance, and invariance of finite amplitude waves round out the coverage.

This book presents a collection of contributions on the advanced mechanics of materials and mechanics of structures approaches, written in honor of Professor Kienzler. It covers various topics related to constitutive models for advanced materials, recent developments in mechanics of configuration forces, as well as new approaches to the efficient modeling and analysis of engineering structures.

Digital Hardware Testing presents realistic transistor-level fault models and testing methods for all types of circuits. The discussion details design-for-testability and built-in self-test methods, with coverage of boundary scan and emerging technologies such as partial scan, cross check, and circular self-test-path.

This book summarizes research advances in micromechanics modeling of ductile fractures made in the past two decades. The ultimate goal of this book is to reach manufacturing frontline designers and materials engineers by providing a user-oriented, theoretical background of micromechanics modeling. Accordingly, the book is organized in a unique way, first presenting a vigorous damage percolation model developed by the authors over the last ten years. This model overcomes almost all difficulties of the existing models and can be used to completely accommodate ductile damage developments within a single-measure microstructure frame. Related void damage criteria including nucleation, growth and coalescence are then discussed in detail: how they are improved, when and where they are used in the model, and how the model performs in comparison with the existing models. Sample forming simulations are provided to illustrate the model s performance.

The series Advances in Polymer Science presents critical reviews of the present and future trends in polymer and biopolymer science. It covers all areas of research in polymer and biopolymer science including chemistry, physical chemistry, physics, material science. The thematic volumes are addressed to scientists, whether at universities or in industry, who wish to keep abreast of the important advances in the covered topics. Advances in Polymer Science enjoys a longstanding tradition and good reputation in its community. Each volume is dedicated to a current topic, and each review critically surveys one aspect of that topic, to place it within the context of the volume. The volumes typically summarize the significant developments of the last 5 to 10 years and discuss them critically, presenting selected examples, explaining and illustrating the important principles, and bringing together many important references of primary literature. On that basis, future research directions in the area can be discussed. Advances in Polymer Science volumes thus are important references for every polymer scientist, as well as for other scientists interested in polymer science - as an introduction to a neighboring field, or as a compilation of detailed information for the specialist. Review articles for the individual volumes are invited by the volume editors. Single contributions can be specially commissioned. Readership: Polymer scientists, or scientists in related fields interested in polymer and biopolymer science, at universities or in industry, graduate students

This thesis presents a combination of material synthesis and characterization with process modeling. In it, the CO2 adsorption properties of hydrotalcites are enhanced through the production of novel supported hybrids (carbon nanotubes and graphene oxide) and the promotion with alkali metals. Hydrogen is regarded as a sustainable energy carrier, since the end users produce no carbon emissions. However, given that most of the hydrogen produced worldwide comes from fossil fuels, its potential as a carbon-free alternative depends on the ability to capture the carbon dioxide released during manufacture. Sorption-enhanced hydrogen production, in which CO2 is removed as it is formed, can make a major contribution to achieving this. The challenge is to find solid adsorbents with sufficient CO2 capacity that can work in the right temperature window over repeated adsorption-desorption cycles. The book presents a highly detailed characterization of the materials, together with an accurate measurement of their adsorption properties under dry conditions and in the presence of steam. It demonstrates that even small quantities of graphene oxide provide superior thermal stability to hydrotalcites due to their compatible layered structure, making them well suited as volume-efficient adsorbents for CO2. Lastly, it identifies suitable catalysts for the overall sorption-enhanced water gas shift process.