International shipping is of great importance for the transport of a great many types of cargo. Substances and products considered dangerous constitute almost 50% of all the payload. It is obvious that stringent regulations are required in order to minimize the risks of accidents. These regulations, which are derived from good practice and which are based on research, have been adopted by a great number of countries. However, emergencies do occur in spite of all precautions. Such emergencies require fast and adequate response in order to confine the consequences for man and his environment to a minimum. Emergency response has political, legal, financial and technical aspects. This makes decision making extremely difficult. The papers carefully prepared and assembled in this book present an up-to-date picture of today's achievements, knowledge and difficulties that are being faced. It was the intention of Oilchem Recovery Denmark and TNO to bring the wide scatter of aspects together in a joined perspective. We also intended to spread the information on latest developments among the many people who are involved in combating calamities and in particular in decision making. Finally, we hope that this conference may help all of us to come to a safer transport of chemicals and a better aquatic environment. We thank all the authors for their magnificent contribution.

Water is the most effective agent in the climate system to modulate energy transfer by radiative processes, through its exchanges of latent heat and within cascades of chemical processes. It is the source of all life on earth, and once convective clouds are formed, it enables large vertical transports of momentum, heat and various atmospheric constituents up to levels above the tropical tropopause. Water triggers very complex processes at the earth's continental surfaces and within the oceans. At last, water in its gaseous phase is the most important greenhouse-gas! Numerical modelling and measurements of the state of the present climate system needs a very thorough understanding of all these processes and their various interactions and forcings. This is a prerequisite for more substantial forecasts of future states in all scales of time, from days to centuries. Therefore, the management of the World Climate Research Programme established in 1988 the new programme GEWEX (Global Energy and Water Cycle Experiment). GEWEX is specifically defined to determine the energy and water transports in the fast components of the climate system with the presently available modelling and measurement means and to provide new capabilities for the future. Research in GEWEX must further develop methods to determine the influence of climatic anomalies on available water resources.

Nowadays, major environmental issues are the object of large public debates de- spite the fact that scientific knowledge is often insufficient to draw unequivocal conclusions. Such is the case in the ongoing debate regarding the specific contri- butions of anthropogenic greenhouse gas emissions and of natural climate changes to global warming. At least 10 to 20 years of additional observations will be re- quired, before we will be able to conclude, with certainty, on this subject. In the mean time, and as directed by their immediate interests, people will continue to promote contradictory opinions. The media are, in part, responsible for perpetuat- ing such debates in that they convey indiscriminately the opinion of highly credi- ble scientists as that of dogmatic researchers, the latter, unfortunately too often expressing working hypotheses as established facts. Naturally, in a similarly mis- informed manner, pressure groups tend to support the researcher whose opinions most closely represent either their particular ideological battles or their economic interests and, hence, in their own way, add further to the confusion and obscurity of the debate. Only a few years ago, mercury (Hg)contamination in hydroelectric reservoirs was the object of such media and social biases. At the time, analytical data used to support the discourse were themselves uncertain and numerous hypotheses, often times fanciful, were proposed and hastily "delivered" to the public.

Aquatic hyphomycetes were discovered 50 years ago by C.T. Ingold. They remained a relatively obscure group until their role as intermediaries between deciduous leaves and stream invertebrates was established some 20 years ago. This book, for the first time, provides a comprehensive summary and critical evaluation of the biology and ecology of these organisms. Aspecial effort was made to evaluate the potential and actual insight that have been or will be derived from work in related disciplines such as the ecology of other fungal groups, stream ecology, or population ecology. The topics treated include the basic life history of the fungi and the potential role of wood, a discussion of how the fungi have adjusted to life in running water, their interactions with invertebrates, the attachment and germination of their spores, what is known about sexual reproduction, how water chemistry may influence their distribution and activity, how they react to human degradation of their environment, and a summary of the research done on the Indian subcontinent. The volume is of special interest to mycologists and stream ecologists and should facilitate the entry of new workers into this exciting area.

This book lies at the intersection of natural sciences, economics, and water en- neering and is in line with the long tradition of environmental economics at the University of Heidelberg. In the 1970s, the Neo-Austrian Capital Theory was developed using the fundamental laws of thermodynamics as a common language between the natural and social sciences. Niemes (1981) integrated the dynamic and irreversibility characteristics of the natural environment into the Neo-Austrian c- ital theory. Faber et al. (1983, 1987, 1995) then extended this interdisciplinary approach further to create a comprehensive, dynamic, environmental resource model. Over the last 3 decades, the theoretical foundations of environmental economics have been modi ed and there have been an impressive variety of applications. This book aims to reduce the gaps between economic theory, natural sciences, and engineering practice. One of the reasons these gaps exist is because economic assumptions are used to construct dynamic environmental and resource models, which are not consistent with the fundamental laws of the natural sciences. Another reason for the gap might be the distance between academic theory and real world situations. Based on an extended thermodynamic approach, the authors explain which economic assumptions are acceptable for constructing a dynamic model that is consistent with the natural sciences. In particular, the special role of water in the production and reproduction activities will be considered as an integral component.

Hazard assessment of a compound (xenobiotic) discharged to the aquatic environment requires data on both exposure and effects to various components of the ecosystem. The multitude of ecological gradients in the Baltic Sea is used as a background example for discussing the complexity of the issue and the need for new approaches. Therefore, this book attempts to go beyond the simplistic, standardized short-term laboratory tests traditionally used as a basis for hazard assessment of chemicals, and gives strong emphasis to the interpretation of ecotoxicological data in their real, ecological context, pointing out the need to consider the natural mortality distribution of the population under study, the role of keystone species and of species with broad ecological niches versus those with narrow, specialized niches.

International concern in scientific, industrial, and governmental communi ties over traces of xenobiotics in foods and in both abiotic and biotic envi ronments has justified the present triumvirate of specialized publications in this field: comprehensive reviews, rapidly published research papers and progress reports, and archival documentations. These three international publications are integrated and scheduled to provide the coherency essential for nonduplicative and current progress in a field as dynamic and complex as environmental contamination and toxicology. This series is reserved ex clusively for the diversified literature on "toxic" chemicals in our food, our feeds, our homes, recreational and working surroundings, our domestic animals, our wildlife and ourselves. Tremendous efforts worldwide have been mobilized to evaluate the nature, presence, magnitude, fate, and toxi cology of the chemicals loosed upon the earth. Among the sequelae of this broad new emphasis is an undeniable need for an articulated set of authoritative publications, where one can find the latest important world literature produced by these emerging areas of science together with docu mentation of pertinent ancillary legislation. Research directors and legislative or administrative advisers do not have the time to scan the escalating number of technical publications that may contain articles important to current responsibility. Rather, these individu als need the background provided by detailed reviews and the assurance that the latest information is made available to them, all with minimal literature searching."

Worldwide concern in scientific, industrial, and governmental com munities over traces of toxic chemicals in foodstuffs and in both abiotic and biotic environments has justified the present triumvirate of specialized publications in this field: comprehensive reviews, rapidly published progress reports, and archival documentations. These three publications are integrated and scheduled to provide in international communication the coherency essential for nonduplicative and current progress in a field as dynamic and complex as environmental contamination and toxicology. Until now there has been no journal or other publication series reserved exclusively for the diversified literature on toxic" chemicals in our foods, our feeds, our geographical surroundings, our domestic animals, our wild life, and ourselves. Around the world immense efforts and many talents have been mobilized to technical and other evaluations of natures, locales, magnitudes, . fates, and toxicology of the persisting residues of these chemicals loosed upon the world. Among the sequelae of this broad new emphasis has been an inescapable need for an articulated set of authorita tive publications where one could expect to find the latest important world literature produced by this emerging area of science together with documentation of pertinent ancillary legislation."

Acidification is one of the most serious environmental problems - especially in Sweden, which suffers most from the consequences of acid rain. Besides international negotiations to reduce sulphur emissions - 85% of the acid load on Sweden can be traced to emissions from outside the country itself - the Swedish Government has employed large-scale, operative liming activities to counteract acidification of surface waters. The scientific results show that - although acidification cannot be solved by liming alone - the measures taken resulted in substantial improvements to around 8,000 Swedish lakes and watercourses. The idea is that other countries affected by acidification may also profit from this experience.

Worldwide concern in scientific, industrial, and governmental com munities over traces of toxic chemicals in foodstuffs and in both abiotic and biotic environments has justified the present triumvirate of specialized publications in this field: comprehensive reviews, rapidly published progress reports, and archival documentations. These three publications are integrated and scheduled to provide in international communication the coherency essential for nonduplicative and current progress in a field as dynamic and complex as environmental contamination and toxicology. Until now there has been no journal or other publication series reserved exclusively for the diversified literature on "toxic" chemicals in our foods, our feeds, our geographical surroundings, our domestic animals, our wild life, and ourselves. Around the world immense efforts and many talents have been mobilized to technical and other evaluations of natures, locales, magnitudes, fates, and toxicology of the persisting residues of these chemicals loosed upon the world. Among the sequelae of this broad new emphasis has been an inescapable need for an articulated set of authorita tive publications where one could expect to find the latest important world literature produced by this emerging area of science together with documentation of pertinent ancillary legislation."

Essentials of Water Systems Design in the Oil, Gas and Chemical Processing Industries provides valuable insight for decision makers by outlining key technical considerations and requirements of four critical systems in industrial processing plants-water treatment systems, raw water and plant water systems, cooling water distribution and return systems, and fire water distribution and storage facilities. The authors identify the key technical issues and minimum requirements related to the process design and selection of various water supply systems used in the oil, gas, and chemical processing industries. This book is an ideal, multidisciplinary work for mechanical engineers, environmental scientists, and oil and gas process engineers.

In this book major construction projects are reviewed. The aim is to present case studies or topics which would stimulate discussion within the areas of environmental policy, economy, ethics or science. By carefully balancing the needs and interests of all involved stakeholders and by observing basic ethical principles, it is possible to resolve the conflicts and to proceed towards constructive cooperation with commonly accepted environmental objectives. The book further contains the key conclusions and recommendations resulting from the "First International Symposium on Large-Scale Constructions in Coastal Environments" held on the island of Norderney from 21-25 April 1997.

ROBERT A. GOLDSTEIN Electric Power Research Institute. Environmental Assessment Department. P.O. Box 10412. Palo Alto. CA 94303. U.S.A. CARL W. CHEN Systech Engineering. Inc .. 3744 Mt. Diablo Boulevard. Suite 101. Lafayette. CA 94549. U.S.A. and STEVEN A. GHERINI Tetra Tech. Inc .. 3746 Mt. Diablo Boulevard. Suite 300. Lafayette. CA 94549. U.S.A. (Received November I, 1984; revised May 14, 1985) Abstract. An integrated, interdisciplinary, intensive study of three forested watersheds in the Adirondack Park region of New York State was started in 1977 to quantify the relationship between the deposition of atmospheric acids and surface water acidity. A general mechanistic theory of lake-watershed acidification that takes into account the production and consumption of acidity by watershed processes, as well as atmospheric inputs of acidity, was developed. This theory is formulated as a mathematical simulation model. Model and data analyses establish the importance of using an integrated ecosystem perspective to assess the vulnerability of surface waters to acidification by acidic deposition. The acid-base status of surface waters is determined by the interaction of many factors: soil, hydrologic, vegetation, geologic, climatic, atmospheric. The absolute and relative contribution of any given factor can be highly variable, both geographically and temporally; hence, lake sensitivity to changes in the quality and quantity of atmospheric deposition is also highly variable.

This book focuses on innovative treatment technologies for the elimination of emerging contaminants in wastewater and drinking water treatment processes. The book also discusses sources and occurrence of emerging contaminants in municipal and industrial waste, giving an overview of state-of-the-art analytical methods for their identification. Further important aspects covered include the acute and chronic effects and overall impact of emerging contaminants on the environment.

There have been many significant microbiological, biochemical and technological advances made in the understanding and implementation of anaerobic digestion processes with respect to industrial and domestic wastewater treatment. Elucida tion of the mechanisms of anaerobic degradation has permitted a greater control over the biological parameters of waste conversion and the technical advances achieved have reduced the time and land area requirements and increased the cost-effectiveness and efficiency of the various processes presently in use. By product recovery in the form of utilisable methane gas has become increasingly feasible, while the development of new and superior anaerobic reactor designs with increased tolerance to toxic and shock loadings of concentrated effiuents has established a potential for treating many extremely recalcitrant industrial wastestreams. The major anaerobic bioreactor systems and their applications and limitations are examined here, together with microbiological and biochemical aspects of anaerobic wastewater treatment processes. London, June 1986 S. M. Stronach T. Rudd J. N. Lester v Table of Contents 1 The Biochemistry of Anaerobic Digestion 1 1. 1 Kinetics of Substrate Utilisation and Bacterial Growth 3 1. 1. 1 COD Fluxes and Mean Carbon Oxidation State 3 1. 1. 2 Bacterial Growth and Biokinetics 4 1. 1. 2. 1 Growth and Single Substrate Kinetics 4 1. 1. 2. 2 Multisubstrate Systems . 8 1. 2 Kinetics and Biochemistry of Hydrolysis 8 1. 3 Kinetics and Biochemistry of Fermentation and J1-0xidation . 11 1."

Polychlorinated biphenyls (PCBs) have been produced commercially since be fore 1930. They proved to be highly versatile mixtures and their uses continued to expand during the early 1970's even after the unanticipated world-wide en vironmental contamination had been discovered (Jensen et aI. , 1969; Koeman et aI. , 1969). Over 600,000 metric-tons were produced and/or used in the U. S. during this time and it is estimated that worldwide production totaled about 1,200,000 metric-tons (Table 1). With low acute toxicities (Fishbein, 1974), these mixtures were considered gen erally biologically inactive even though industrial exposure had demonstrated he patic and dermatological effects (Fishbein, 1974; Hansen, 1987). Thus, use and disposal were not carefully monitored and it is estimated that one-third of the world-wide production of PCBs has been released into the global environment (Table 1). Table 1. Estimated production and disposition of PCBs b U. s. a Worldwide 6 6 Production/use 610 X 10 kg 1200 X 10 kg Mobil environmental reservoir 82 400 Static reservoirs In service 340 Dumps 130 Total static 470 800 a NAS, 1979 b Tatsukawa and Tanaba, 1984 2 Environmental Distribution Many countries now impose strict controls on the use and release of PCBs. Re lease into the environment has declined dramatically in the last decade, but con tinued release from reservoirs (Table 1) into burdened ecosystems (Table 2) ap pears inevitable for several more decades (Barros et aI. , 1984).

The identification of inputs and outputs is the first and probably most important step in testing and analyzing complex systems. Following accepted natural laws such as the conservation of mass and the principle of electroneutrality, the input/output analysis of the system, be it steady or in connection with perturbations will reveal the status dynamic, will identify whether changes are reversible or irreversible and whether changing the input will cause a hysteresis response. Moreover, measurements ofinput and output fluxes can indicate the storage capacity ofa system, its resilience to buffer or amplify variations of the external input, and it can identify structural changes. Therefore, to a certain extent, the input/output analysis can facilitate predictions about the ecosystem stability. The measurement of fluxes and the determination of inputs and outputs of eco systems are, in many aspects, analogous to measurements done by engineers when testing an electronic apparatus. The first step is the measurement ofthe input/output properties of the instrument as a whole, or ofvarious circuit boards, and the compari. son ofthese with the expected variations of the original design. Varying input and out. put can give valuable information about the stability and the regulatory properties of the device. Nevertheless, only the circuit as an entity has specific properties which cannot be anticipated if the individual components are investigated regardless oftheir position. Also, the instrument as a whole will have different input/output properties than its subcircuits."

The world population in 1930 was 2 billion. It reached 3 billion in 1960, stands at 4. 6 billion today, and is expected to reach 6 billion by the end of the century. The food and fiber needs of such a rapidly increasing population are enormous. One of the most basic resources, perhaps the most basic of all, for meeting these needs is the soil. There is an urgent need to improve and protect this resource on which the future of mankind directly depends. We must not only learn how to use the soil to furnish our immediate needs, but also ensure that the ability of the soil to sustain food production in the future is unimpaired. This is indeed a mammoth task; a 1977 United Nations survey reported that almost one-fifth of the world's is now being steadily degraded. The diversity of soil makes it cropland necessary for research to be conducted in many locations. There are basic principles, however, that are universal. This, Advances in Soil Sciences, presents clear and concise reviews in all areas of soil science for everyone interested in this basic resource and man's influence on it. The purpose of the series is to provide a forum for leading scientists to analyze and summarize the available scientific information on a subject, assessing its importance and identifying additional research needs. But most importantly, the contributors will develop principles that have practical applications to both developing and developed agricultures.

This seventh symposium in the series of biennial Gothenburg Symposia, taking place in Edingburgh 1996 continues to bring together research scientists, designing and operating engineers and funding and supervising administrators. It also has enlarged the scope of its platform by bringing together concerned specialists from Western countries and Central and Eastern Europe and furthermore attempts to bridge the gap between developing and industrialized countries. The traditionally presented topics, such as treatment of potable water and wastwater predominantly by chemical means are of utmost importance for those that need immediate action at reasonable costs. It is particularly noteworthy that an increasing number of contributions address these problems of the emerging need for environmental protection. And more and more presentations are delivered by experts from Central and Eastern Europe and from developing countries. Again the proceedings of this seventh symposium indicate and demonstrate new developments that advance the field of water and wastewater treatment. Be sides the ever present topics there is now a whole section on automation and control, a highly significant topic for water technology that so far has not received too much attention in symposia of this kind addressing theoreticians and prac titioners at the same time."

This series is dedicated to serving the growing community of scholars and practitioners concerned with the principles and applications of environ mental management. Each volume is a thorough treatment of a specific topic of importance for proper management practices. A fundamental ob jective of these books is to help the reader discern and implement man's stewardship of our environment and the world's renewable resources. For we must strive to understand the relationship between man and nature, act to bring harmony to it, and nurture an environment that is both stable and productive. These objectives have often eluded us because the pursuit of other in dividual and societal goals has diverted us from a course of living in balance with the environment. At times, therefore, the environmental manager may have to exert restrictive control, which is usually best applied to man, not nature. Attempts to alter or harness nature have often failed or backfired, as exemplified by the results of imprudent use of herbicides, fertilizers, water, and other agents. Each book in this series will shed light on the fundamental and applied aspects of environmental management. It is hoped that each will help solve a practical and serious environmental problem."

The Ecosystems Research Center (ERC) was established at Cornell U ni versity in October 1980 by the Environmental Protection Agency (EPA) with the goals of: 1. Identifying fundamental principles and concepts of ecosystems sci ence and the determination of their importance in understanding and pre dicting the responses of ecosystems to stress, the description of the basic mechanisms that operate within ecosystems, and an examination of the stability of ecosystem structure and function in the face of stress. 2. Testing the applicability of those theoretical concepts to problems of concern to the EPA through a consideration of retrospective and other case studies. In line with these goals, the Hudson River ecosystem provided the basis for the first major retrospective study undertaken by the ERC. The goal of the project was to develop recommendations concerning how ecosystem monitoring can and should be carried out in support of EPA's regulatory responsibilities. Our hope was and is that the experience gained from this study will be broadly applicable to a range of manage ment problems involving estuarine ecosystems, and will lead to more effective regulation."

Global attention in scientific, industrial, and governmental communities to traces of toxic chemicals in foodstuffs and in both abiotic and biotic environ ments has justified the present triumvirate of specialized publications in this field: comprehensive reviews, rapidly published progress reports, and archival documentations. These three publications are integrated and scheduled to pro vide in international communication the coherency essential for nonduplicative and current progress in a field as dynamic and complex as environmental con tamination and toxicology. Until now there has been no journal or other publica tion series reserved exclusively for the diversified literature on "toxic" chemicals in our foods, our feeds, our geographical surroundings, our domestic animals, our wildlife, and ourselves. Around the world immense efforts and many talents have been mobilized to technical and other evaluations of natures, locales, magnitudes, fates, and toxicology of the persisting residues of these chemicals loosed upon the world. Among the sequelae of this broad new emphasis has been an inescapable need for an articulated set of authoritative publications where one could expect to find the latest important world literature produced by this emerging area of science together with documentation of pertinent ancil lary legislation."

This series is dedicated to serving the growing community of scholars and practitioners concerned with the principles and applications of environmental management. Each volume is a thorough treatment of a specific topic of importance for proper management practices. A fundamental objective of these books is to help the reader discern and implement man's stewardship of our environment and the world's renewable resources. For we must strive to understand the relationship between man and nature, act to bring harmony to it, and nurture an environment that is both stable and productive. These objectives have often eluded us because the pursuit of other individual and societal goals has diverted us from a course of living in balance with the environment. At times, therefore, the environmental manager may have to exert restrictive control, which is usually best applied to man, not nature. Attempts to alter or harness nature have often failed or backfired, as exemplified by the results of imprudent use of herbicides, fertilizers, water, and other agents. Each book in this series will shed light on the fundamental and applied aspects of environmental management. It is hoped that each will help solve a practical and serious environmental problem.

Coweeta is one of the oldest continuously operating laboratories of its type in the world. For the first time, a complete review and summary of more than 50 years study of the hydrological and ecological responses of baseline and managed Southern Appalachian hardwood forests at Coweeta is now supplied by this volume. The long-term research approach represents a continuum of theory, experimentation and application using watersheds as landscape units of investigation. Thus, the information encompasses a wide range of interpretations and interests. In addition to in-depth analyses of terrestrial and stream processes, the breadth of coverage includes historical perspectives and relevance of ecosystem science to management needs. In a broader sense, the Coweeta research effort is considered from a perspective of national and international forest hydrology and ecology programs.

Regional Approaches to Water Pollution in the Environment integrates knowledge and experience on pollution problems related to industrial, agricultural and municipal activities and former military sites, with special emphasis on the Black Triangle: the region situated at the borders between North Bohemia, Polish Lower Silesia and South Saxony. Here, some five million inhabitants live in an area of brown coal basins having the highest emissions of sulphuric and nitrogen emission in the whole of Europe. The large-scale damage in this region is due to obsolete technology and insufficient equipment for monitoring emissions. Health effects are severe, and controlling the pollution can only be done at high cost. There is thus a need to exchange knowledge and experience on methods for evaluating the expected effects of measures and purification techniques to remedy ground and surface water pollution.